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When primary amine is heated with CS2 in presence of excess of mercuric chloride, it produce isothiocyanate. This reaction is known as
  • a)
    Hoffmann bromide reaction 
  • b)
    Carbylamine reaction
  • c)
    Hoffmann mustard oil reaction
  • d)
    Hinsberg's reaction
Correct answer is option 'C'. Can you explain this answer?
Most Upvoted Answer
When primary amine is heated with CS2 in presence of excess of mercuri...
Explanation:

Carbylamine Reaction:
- When a primary amine is heated with CS2 in the presence of excess mercuric chloride, it produces an isothiocyanate.
- This reaction is known as the Carbylamine reaction or Hoffmann mustard oil reaction.
- The primary amine reacts with CS2 to form a dithiocarbamate intermediate, which then reacts with mercuric chloride to give the isothiocyanate product.

Significance:
- The Carbylamine reaction is a useful method for the synthesis of isothiocyanates, which are important intermediates in organic synthesis.
- Isothiocyanates have various applications in medicinal chemistry, agriculture, and materials science.

Key Points:
- Reactants: Primary amine, CS2, excess mercuric chloride
- Product: Isothiocyanate
- Conditions: Heating and presence of excess mercuric chloride
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Community Answer
When primary amine is heated with CS2 in presence of excess of mercuri...
Primary amine on heating with CS2 is presence of excess of HgCI2 produce ethyl isothiocyanate which has smell of mustard oil. Therefore, it is known as Hoffmann’s mustard oil reaction.
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When primary amine is heated with CS2 in presence of excess of mercuric chloride, it produce isothiocyanate. This reaction is known asa)Hoffmann bromide reactionb)Carbylamine reactionc)Hoffmann mustard oil reactiond)Hinsbergs reactionCorrect answer is option 'C'. Can you explain this answer?
Question Description
When primary amine is heated with CS2 in presence of excess of mercuric chloride, it produce isothiocyanate. This reaction is known asa)Hoffmann bromide reactionb)Carbylamine reactionc)Hoffmann mustard oil reactiond)Hinsbergs reactionCorrect answer is option 'C'. Can you explain this answer? for JEE 2025 is part of JEE preparation. The Question and answers have been prepared according to the JEE exam syllabus. Information about When primary amine is heated with CS2 in presence of excess of mercuric chloride, it produce isothiocyanate. This reaction is known asa)Hoffmann bromide reactionb)Carbylamine reactionc)Hoffmann mustard oil reactiond)Hinsbergs reactionCorrect answer is option 'C'. Can you explain this answer? covers all topics & solutions for JEE 2025 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for When primary amine is heated with CS2 in presence of excess of mercuric chloride, it produce isothiocyanate. This reaction is known asa)Hoffmann bromide reactionb)Carbylamine reactionc)Hoffmann mustard oil reactiond)Hinsbergs reactionCorrect answer is option 'C'. Can you explain this answer?.
Solutions for When primary amine is heated with CS2 in presence of excess of mercuric chloride, it produce isothiocyanate. This reaction is known asa)Hoffmann bromide reactionb)Carbylamine reactionc)Hoffmann mustard oil reactiond)Hinsbergs reactionCorrect answer is option 'C'. Can you explain this answer? in English & in Hindi are available as part of our courses for JEE. Download more important topics, notes, lectures and mock test series for JEE Exam by signing up for free.
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