All Courses
Explore Courses UPSC Exam UPSC Test Series Free Notes EduRev Infinity Get the App Login Join for Free
Sign in Open App
Class 12 Exam  >  Class 12 Questions  >  Why do BiF5 is stable than BiCl5 athough they... Start Learning for Free
SaveJoin the Discussion on the App
Why do BiF5 is stable than BiCl5 athough they both are that is fluorine and chlorine are halogen?
Clear all your Class 12 doubts with EduRev
Most Upvoted Answer
Why do BiF5 is stable than BiCl5 athough they both are that is fluorin...
Firstly correct your question, replace stage by stable. Now BiF5 is stable because Bi atom can accommodate small sized 5 fluorine atom around it. Whereas it cannot accommodate 5 large Cl atoms around it. Hence you can say bond energy of the formation of BiCl5 is very low that it cannot be formed.
Community Answer
Why do BiF5 is stable than BiCl5 athough they both are that is fluorin...
Why BiF5 is more stable than BiCl5?


Introduction

Bismuth (Bi) is a chemical element that belongs to the group 15 of the periodic table. It has a unique feature of forming stable compounds with both halogens, fluorine, and chlorine. BiF5 and BiCl5 are two such compounds that are formed by bismuth with halogens. However, BiF5 is more stable than BiCl5. In this article, we will discuss the reasons behind the stability of BiF5 over BiCl5.

Electronegativity Difference

Fluorine (F) is the most electronegative element on the periodic table, while chlorine (Cl) is less electronegative. The electronegativity difference between Bi and F is greater than that between Bi and Cl. This leads to a higher ionic character in BiF5 than BiCl5. The higher the ionic character of a compound, the stronger the bond between the two atoms, making it more stable.

Bond Length

The bond length between Bi and F in BiF5 is shorter than that between Bi and Cl in BiCl5. This is due to the smaller size of F compared to Cl. The shorter bond length leads to stronger bonds, making the compound more stable.

Solubility

BiF5 is more soluble in water than BiCl5. This is due to the higher polarity of BiF5 resulting from the greater electronegativity difference between Bi and F. The higher solubility of BiF5 makes it more stable as it is less likely to precipitate out of solution.

Conclusion

In conclusion, BiF5 is more stable than BiCl5 due to the greater electronegativity difference between Bi and F, resulting in a higher ionic character, shorter bond length, and higher solubility. These factors contribute to the stability of BiF5 over BiCl5.
Explore Courses for Class 12 exam

Similar Class 12 Doubts

When two different halogens react with each other, the compounds formed are called interhalogen compounds.The general formula of these compounds is given by XX, , and .Here, X = halogen of large size and more electropositive.X =halogen of smaller size and more electronegative,e.g. CIF, ClF3, IF5, IF7, etc.All are covalent and diamagnetic.They are either volatile liquids or solids except CIF, BrF, CIF3, IF5 and IF7.Interhalogen compounds are more reactive than halogens (except fluorin e). The reason is X—X bond in interhalogens is weaker than X—X bond in halogens (except F— F bon d).Hydrolysis of interhalogens Interhalogen compounds undergo hydrolysis giving halide ion derived from the smaller halogen and a hypohalite (when XX), halite (when ), halate (when ) and perhalate (when ) n ion derived from the larger halogen.XX+ H2O→ HX + HOXQ.BrCI on hydrolysis produce

Why do BiF5 is stable than BiCl5 athough they both are that is fluorine and chlorine are halogen?
Question Description
Why do BiF5 is stable than BiCl5 athough they both are that is fluorine and chlorine are halogen? for Class 12 2024 is part of Class 12 preparation. The Question and answers have been prepared according to the Class 12 exam syllabus. Information about Why do BiF5 is stable than BiCl5 athough they both are that is fluorine and chlorine are halogen? covers all topics & solutions for Class 12 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for Why do BiF5 is stable than BiCl5 athough they both are that is fluorine and chlorine are halogen?.
Solutions for Why do BiF5 is stable than BiCl5 athough they both are that is fluorine and chlorine are halogen? in English & in Hindi are available as part of our courses for Class 12. Download more important topics, notes, lectures and mock test series for Class 12 Exam by signing up for free.
Here you can find the meaning of Why do BiF5 is stable than BiCl5 athough they both are that is fluorine and chlorine are halogen? defined & explained in the simplest way possible. Besides giving the explanation of Why do BiF5 is stable than BiCl5 athough they both are that is fluorine and chlorine are halogen?, a detailed solution for Why do BiF5 is stable than BiCl5 athough they both are that is fluorine and chlorine are halogen? has been provided alongside types of Why do BiF5 is stable than BiCl5 athough they both are that is fluorine and chlorine are halogen? theory, EduRev gives you an ample number of questions to practice Why do BiF5 is stable than BiCl5 athough they both are that is fluorine and chlorine are halogen? tests, examples and also practice Class 12 tests.
Explore Courses for Class 12 exam
Signup for Free!
Signup to see your scores go up within 7 days! Learn & Practice with 1000+ FREE Notes, Videos & Tests.
10M+ students study on EduRev
Get App
© EduRev
Education Revolution
Follow Us
Signup to see your scores go up
within 7 days!
Takes less than 10 seconds to signup