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Which of the following statements most accurately describes the stereochemistry between the various cyclohexanes?
  • a)
    Cis-1,2-dichlorocyclohexane and trans-1,2-dichlorocyclohexane rotate plane-polarized light in opposite directions, and together in equal proportions form a racemic mixture.
  • b)
    Only cis-1,4-dichlorocyclohexane is achiral due to a plane of symmetry, and cis-1,4-dichlorocyclohexane is diastereomeric to trans-1,4-dichlorocyclohexane.
  • c)
    The conformational isomers of trans-1,2-dichlorocyclohexane are enantiomers, which are not interconvertible, but resolvable.
  • d)
    The diaxial and diequatorial forms of trans-1,3-dichlorohexane can be separated by their differing physical properties.
Correct answer is option 'C'. Can you explain this answer?
Most Upvoted Answer
Which of the following statements most accurately describes the stereo...
  • Let’s look at trans-1,3-dichlorohexane. The chlorines cannot be positioned diaxial or diequatorial, but can only be axial and equatorial or vice versa. Additionally, if they were diastereomers or structural isomers, then they could be separated by physical means.
  • Consider whether only cis-1,4-dichlorocylohexane is achiral. 1,1-dichlorocycloalkane and trans-1,4-dichlorocycloalkane are both achiral due to a plane of symmetry, for instance, but cis-1,4-dichlorocyclohexane is indeed diastereometric to trans-1,4-dichlorocyclohexane.
  • If cis-1,2 and trans-1,2-dichlorocycloalkane rotate plane-polarized light in opposite directions and together they form a racemic mixture, that would make them enantiomers. In fact, they are diastereomers.
  • Isomers are interconvertible only if there is a small energy barrier separating the two, such as the conformational isomers of butane. Two isomers are resolvable if no interconversion takes place.
  • Since the two chlorines can be either be positioned diaxial or diequatorial, the enantiomer with diequatorial chlorines would be more stable, hence the isomers are not interconvertible and resolvable:
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Which of the following statements most accurately describes the stereochemistry between the various cyclohexanes?a)Cis-1,2-dichlorocyclohexane and trans-1,2-dichlorocyclohexane rotate plane-polarized light in opposite directions, and together in equal proportions form a racemic mixture.b)Only cis-1,4-dichlorocyclohexane is achiral due to a plane of symmetry, and cis-1,4-dichlorocyclohexane is diastereomeric to trans-1,4-dichlorocyclohexane.c)The conformational isomers of trans-1,2-dichlorocyclohexane are enantiomers, which are not interconvertible, but resolvable.d)The diaxial and diequatorial forms of trans-1,3-dichlorohexane can be separated by their differing physical properties.Correct answer is option 'C'. Can you explain this answer?
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Which of the following statements most accurately describes the stereochemistry between the various cyclohexanes?a)Cis-1,2-dichlorocyclohexane and trans-1,2-dichlorocyclohexane rotate plane-polarized light in opposite directions, and together in equal proportions form a racemic mixture.b)Only cis-1,4-dichlorocyclohexane is achiral due to a plane of symmetry, and cis-1,4-dichlorocyclohexane is diastereomeric to trans-1,4-dichlorocyclohexane.c)The conformational isomers of trans-1,2-dichlorocyclohexane are enantiomers, which are not interconvertible, but resolvable.d)The diaxial and diequatorial forms of trans-1,3-dichlorohexane can be separated by their differing physical properties.Correct answer is option 'C'. Can you explain this answer? for MCAT 2024 is part of MCAT preparation. The Question and answers have been prepared according to the MCAT exam syllabus. Information about Which of the following statements most accurately describes the stereochemistry between the various cyclohexanes?a)Cis-1,2-dichlorocyclohexane and trans-1,2-dichlorocyclohexane rotate plane-polarized light in opposite directions, and together in equal proportions form a racemic mixture.b)Only cis-1,4-dichlorocyclohexane is achiral due to a plane of symmetry, and cis-1,4-dichlorocyclohexane is diastereomeric to trans-1,4-dichlorocyclohexane.c)The conformational isomers of trans-1,2-dichlorocyclohexane are enantiomers, which are not interconvertible, but resolvable.d)The diaxial and diequatorial forms of trans-1,3-dichlorohexane can be separated by their differing physical properties.Correct answer is option 'C'. Can you explain this answer? covers all topics & solutions for MCAT 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for Which of the following statements most accurately describes the stereochemistry between the various cyclohexanes?a)Cis-1,2-dichlorocyclohexane and trans-1,2-dichlorocyclohexane rotate plane-polarized light in opposite directions, and together in equal proportions form a racemic mixture.b)Only cis-1,4-dichlorocyclohexane is achiral due to a plane of symmetry, and cis-1,4-dichlorocyclohexane is diastereomeric to trans-1,4-dichlorocyclohexane.c)The conformational isomers of trans-1,2-dichlorocyclohexane are enantiomers, which are not interconvertible, but resolvable.d)The diaxial and diequatorial forms of trans-1,3-dichlorohexane can be separated by their differing physical properties.Correct answer is option 'C'. Can you explain this answer?.
Solutions for Which of the following statements most accurately describes the stereochemistry between the various cyclohexanes?a)Cis-1,2-dichlorocyclohexane and trans-1,2-dichlorocyclohexane rotate plane-polarized light in opposite directions, and together in equal proportions form a racemic mixture.b)Only cis-1,4-dichlorocyclohexane is achiral due to a plane of symmetry, and cis-1,4-dichlorocyclohexane is diastereomeric to trans-1,4-dichlorocyclohexane.c)The conformational isomers of trans-1,2-dichlorocyclohexane are enantiomers, which are not interconvertible, but resolvable.d)The diaxial and diequatorial forms of trans-1,3-dichlorohexane can be separated by their differing physical properties.Correct answer is option 'C'. Can you explain this answer? in English & in Hindi are available as part of our courses for MCAT. Download more important topics, notes, lectures and mock test series for MCAT Exam by signing up for free.
Here you can find the meaning of Which of the following statements most accurately describes the stereochemistry between the various cyclohexanes?a)Cis-1,2-dichlorocyclohexane and trans-1,2-dichlorocyclohexane rotate plane-polarized light in opposite directions, and together in equal proportions form a racemic mixture.b)Only cis-1,4-dichlorocyclohexane is achiral due to a plane of symmetry, and cis-1,4-dichlorocyclohexane is diastereomeric to trans-1,4-dichlorocyclohexane.c)The conformational isomers of trans-1,2-dichlorocyclohexane are enantiomers, which are not interconvertible, but resolvable.d)The diaxial and diequatorial forms of trans-1,3-dichlorohexane can be separated by their differing physical properties.Correct answer is option 'C'. Can you explain this answer? defined & explained in the simplest way possible. Besides giving the explanation of Which of the following statements most accurately describes the stereochemistry between the various cyclohexanes?a)Cis-1,2-dichlorocyclohexane and trans-1,2-dichlorocyclohexane rotate plane-polarized light in opposite directions, and together in equal proportions form a racemic mixture.b)Only cis-1,4-dichlorocyclohexane is achiral due to a plane of symmetry, and cis-1,4-dichlorocyclohexane is diastereomeric to trans-1,4-dichlorocyclohexane.c)The conformational isomers of trans-1,2-dichlorocyclohexane are enantiomers, which are not interconvertible, but resolvable.d)The diaxial and diequatorial forms of trans-1,3-dichlorohexane can be separated by their differing physical properties.Correct answer is option 'C'. Can you explain this answer?, a detailed solution for Which of the following statements most accurately describes the stereochemistry between the various cyclohexanes?a)Cis-1,2-dichlorocyclohexane and trans-1,2-dichlorocyclohexane rotate plane-polarized light in opposite directions, and together in equal proportions form a racemic mixture.b)Only cis-1,4-dichlorocyclohexane is achiral due to a plane of symmetry, and cis-1,4-dichlorocyclohexane is diastereomeric to trans-1,4-dichlorocyclohexane.c)The conformational isomers of trans-1,2-dichlorocyclohexane are enantiomers, which are not interconvertible, but resolvable.d)The diaxial and diequatorial forms of trans-1,3-dichlorohexane can be separated by their differing physical properties.Correct answer is option 'C'. Can you explain this answer? has been provided alongside types of Which of the following statements most accurately describes the stereochemistry between the various cyclohexanes?a)Cis-1,2-dichlorocyclohexane and trans-1,2-dichlorocyclohexane rotate plane-polarized light in opposite directions, and together in equal proportions form a racemic mixture.b)Only cis-1,4-dichlorocyclohexane is achiral due to a plane of symmetry, and cis-1,4-dichlorocyclohexane is diastereomeric to trans-1,4-dichlorocyclohexane.c)The conformational isomers of trans-1,2-dichlorocyclohexane are enantiomers, which are not interconvertible, but resolvable.d)The diaxial and diequatorial forms of trans-1,3-dichlorohexane can be separated by their differing physical properties.Correct answer is option 'C'. Can you explain this answer? theory, EduRev gives you an ample number of questions to practice Which of the following statements most accurately describes the stereochemistry between the various cyclohexanes?a)Cis-1,2-dichlorocyclohexane and trans-1,2-dichlorocyclohexane rotate plane-polarized light in opposite directions, and together in equal proportions form a racemic mixture.b)Only cis-1,4-dichlorocyclohexane is achiral due to a plane of symmetry, and cis-1,4-dichlorocyclohexane is diastereomeric to trans-1,4-dichlorocyclohexane.c)The conformational isomers of trans-1,2-dichlorocyclohexane are enantiomers, which are not interconvertible, but resolvable.d)The diaxial and diequatorial forms of trans-1,3-dichlorohexane can be separated by their differing physical properties.Correct answer is option 'C'. Can you explain this answer? tests, examples and also practice MCAT tests.
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