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During the phase transition, at constant temperature, of a solid from one form to another, the change in molar volume, ΔVm = 1.0 cm3 mol-1 is independent of pressure. The change in molar Gibbs free energy, in units of J mol-1, when the pressure is increased from 1 bar to 3 bars is
  • a)
    4 × 10-1
  • b)
    3 × 10-1
  • c)
    2 × 10-1
  • d)
    1 × 10-1
Correct answer is option 'C'. Can you explain this answer?
Most Upvoted Answer
During the phase transition, at constant temperature, of a solid from ...
  • Given, During the phase transition, at constant temperature, of a solid from one form to another, the change in molar volume, ΔVm = 1.0 cm3 mol-1 is independent of pressure.
  • When the pressure is increased from 1 bar to 3 bars is, from equation (2) we get
μ = Vmdp
μ = 1.0 cm3 mol-1 × (3 bar - 1 bar)
= 1.0 × 2 cm3. mol-1. bar
= 2 × 10-3 lit. atm. mol-1 (1cm3 = 10-3 lit and 1 atm = 1 bar)
= 2 × 10-3 × 102 J mol-1 (1 lit.atm = 100 J)
= 2 × 10-1J mol-1 
Hence, The change in molar Gibbs free energy, in units of J mol-1, when the pressure is increased from 1 bar to 3 bars is 2 × 10-1J mol-1 .
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During the phase transition, at constant temperature, of a solid from one form to another, the change in molar volume, ΔVm= 1.0 cm3mol-1is independent of pressure. The change in molar Gibbs free energy, in units of J mol-1, when the pressure is increased from 1 bar to 3 bars isa)4× 10-1b)3 × 10-1c)2 × 10-1d)1 × 10-1Correct answer is option 'C'. Can you explain this answer?
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