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Acidic ferric chloride solution on treatment with excess of potassium ferrocyanide give a Prussian blue coloured colloidal species, It is:
  • a)
    HFe[Fe(CN)6]
  • b)
    K5Fe[Fe(CN)6]2
  • c)
    Fe4 [Fe(CN)6]3
  • d)
    KFe[Fe(CN)6]
Correct answer is option 'D'. Can you explain this answer?
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Acidic ferric chloride solution on treatment with excess of potassium ...
Explanation:
When an acidic ferric chloride solution is treated with an excess of potassium ferrocyanide, it results in the formation of a Prussian blue colored colloidal species. This reaction can be represented by the following equation:

FeCl3 + 6K4[Fe(CN)6] → KFe[Fe(CN)6] + 6KCl

The correct answer is option 'D', which represents KFe[Fe(CN)6] as the colloidal species formed.

Explanation in detail:

1. Formation of Ferric Chloride:
When ferric chloride (FeCl3) is dissolved in water, it dissociates into Fe3+ ions and Cl- ions. This forms an acidic solution due to the presence of H+ ions from the dissociation of water.

FeCl3 → Fe3+ + 3Cl-

2. Formation of Potassium Ferrocyanide:
Potassium ferrocyanide (K4[Fe(CN)6]) is a yellow crystalline solid that dissociates in water to form K+ ions and the ferrocyanide ion ([Fe(CN)6]4-).

K4[Fe(CN)6] → 4K+ + [Fe(CN)6]4-

3. Reaction between Ferric Chloride and Potassium Ferrocyanide:
When an acidic ferric chloride solution is treated with an excess of potassium ferrocyanide, a redox reaction occurs. The Fe3+ ions from ferric chloride are reduced to Fe2+ ions, while the ferrocyanide ions are oxidized to ferricyanide ions.

Fe3+ + [Fe(CN)6]4- → Fe2+ + [Fe(CN)6]3-

This reaction results in the formation of a Prussian blue colored precipitate, which is the colloidal species. The Prussian blue compound has the chemical formula KFe[Fe(CN)6].

4. Explanation of the Correct Answer:
Option 'D' represents KFe[Fe(CN)6], which is the correct answer. The other options (a, b, and c) do not represent the correct chemical formula for the Prussian blue colloidal species formed in the reaction.
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Acidic ferric chloride solution on treatment with excess of potassium ferrocyanide give a Prussian blue coloured colloidal species, It is:a)HFe[Fe(CN)6]b)K5Fe[Fe(CN)6]2c)Fe4[Fe(CN)6]3d)KFe[Fe(CN)6]Correct answer is option 'D'. Can you explain this answer?
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Acidic ferric chloride solution on treatment with excess of potassium ferrocyanide give a Prussian blue coloured colloidal species, It is:a)HFe[Fe(CN)6]b)K5Fe[Fe(CN)6]2c)Fe4[Fe(CN)6]3d)KFe[Fe(CN)6]Correct answer is option 'D'. Can you explain this answer? for JEE 2024 is part of JEE preparation. The Question and answers have been prepared according to the JEE exam syllabus. Information about Acidic ferric chloride solution on treatment with excess of potassium ferrocyanide give a Prussian blue coloured colloidal species, It is:a)HFe[Fe(CN)6]b)K5Fe[Fe(CN)6]2c)Fe4[Fe(CN)6]3d)KFe[Fe(CN)6]Correct answer is option 'D'. Can you explain this answer? covers all topics & solutions for JEE 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for Acidic ferric chloride solution on treatment with excess of potassium ferrocyanide give a Prussian blue coloured colloidal species, It is:a)HFe[Fe(CN)6]b)K5Fe[Fe(CN)6]2c)Fe4[Fe(CN)6]3d)KFe[Fe(CN)6]Correct answer is option 'D'. Can you explain this answer?.
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