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Which of the following samples of reducing agents is /are chemically equivalent to 25 ml of 0.2 N KMnO4 to be reduced to Mn2+ and water.
  • a)
    25 ml of 0.2 M FeSO4 to be oxidized to Fe3+
  • b)
    50 ml of 0.1 M H3AsO3 to be oxidized to H3As04
  • c)
    25 ml of 0.1 M H202 to be oxidized to H+ and 02
  • d)
    25 ml of 0.1 M SnCl2 to be oxidized to S04+
Correct answer is option 'A,D'. Can you explain this answer?
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Which of the following samples of reducing agents is /are chemically e...
Understanding Reducing Agents
To determine which reducing agents are chemically equivalent to 25 ml of 0.2 N KMnO4, we need to understand the concept of normality and the stoichiometry involved in redox reactions.

Normalized KMnO4 Reaction
- KMnO4 is a strong oxidizing agent and in acidic medium, it reduces to Mn²⁺.
- The equivalent factor for KMnO4 in this reaction is 5 because 1 mole of KMnO4 can accept 5 moles of electrons.

Calculating Equivalents
- For 25 ml of 0.2 N KMnO4:
- Equivalents = Normality × Volume (L) = 0.2 N × 0.025 L = 0.005 equivalents
Now, let's analyze each option:

Option A: 25 ml of 0.2 M FeSO4
- Oxidation: Fe²⁺ → Fe³⁺
- 1 mole of Fe²⁺ gives 1 mole of electrons, thus:
- Equivalents = Molarity × Volume (L) = 0.2 M × 0.025 L = 0.005 equivalents
- This matches the equivalents from KMnO4.

Option B: 50 ml of 0.1 M H3AsO3
- Oxidation: H3AsO3 → H3AsO4
- 1 mole of H3AsO3 gives 2 moles of electrons.
- Equivalents = 0.1 M × 0.050 L = 0.005 equivalents, but since it gives 2 electrons, it would actually provide 0.010 equivalents, making it unsuitable.

Option C: 25 ml of 0.1 M H2O2
- Oxidation: H2O2 → H⁺ + O₂
- 1 mole of H2O2 gives 2 moles of electrons.
- Equivalents = 0.1 M × 0.025 L = 0.0025 equivalents, insufficient to match.

Option D: 25 ml of 0.1 M SnCl2
- Oxidation: Sn²⁺ → Sn⁴⁺
- 1 mole of Sn²⁺ gives 2 moles of electrons.
- Equivalents = 0.1 M × 0.025 L = 0.0025 equivalents, but since it provides 2 electrons, it gives 0.005 equivalents, matching the requirement.

Conclusion
Thus, the chemically equivalent reducing agents to 25 ml of 0.2 N KMnO4 are:
- **Option A: FeSO4**
- **Option D: SnCl2**
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Volumetric analysis is based on the principle of equivalence a that minloces lead in the ratio of their equivalents. At the equivalence point of the reaction, involving the reactahts A and B : Number of gram equivalents of A = Number of gram equivalents of B..If VA ml of solution A having normality NA react just completely with VB ml of solution B having normalityNB thenEquation(1), called normality equation is very useful in numerical of volumetric analysis. Equivalent masses of different substances :Basically the equivalent mass of a substance is defined as the pads by seam ctituhich combine with or displace 1.0078 parts (1part) by mass of hydrogen, 8 parts by mansetaisiosaid 35.5 parts by mass of chlorine.Mass of a substance expressed in gram equal to its equivalent man is gam equivalent mass. Equivalent mass of a substance is not constant but depends upon the maw i malice the substance participates.Equivalent mass of an acid in acid-base reaction is its mass in grannehidicodoinisooleaf replaceable Fi ions (= 1.0078 g1g).0n the other hand, equivalent mass of a bagels istolonellfacontairis 1 mole of replaceable 0H ions. 1 g equivalent mass each of an acid and base an ionclinegins saint and 1 mole of water= 18 g). Equivalent mass of an oxidising agent is its mass which gains 1 mole at ellecismitcan be obtained by dividing the molecular mass or formula mass by the total decrease in aididditaiiilberef one or more elements per molecule.0n the other hand, equivalent mass of a reducing agent is the mass of the substance which loses 1 mole of electorns. It can be calculated by dividing the molecular or formula mass of the subtance by the total increase in oxidation number of one or more elements per molecular or formula mass.Q.Which of the following solutions, when mixed with 100 ml of 0.05 M NaOH, will give a neutral solution?

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Which of the following samples of reducing agents is /are chemically equivalent to 25 ml of 0.2 N KMnO4 to be reduced to Mn2+ and water.a)25 ml of 0.2 M FeSO4 to be oxidized to Fe3+b)50 ml of 0.1 M H3AsO3 to be oxidized to H3As04c)25 ml of 0.1 M H202 to be oxidized to H+ and 02d)25 ml of 0.1 M SnCl2 to be oxidized to S04+Correct answer is option 'A,D'. Can you explain this answer?
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Which of the following samples of reducing agents is /are chemically equivalent to 25 ml of 0.2 N KMnO4 to be reduced to Mn2+ and water.a)25 ml of 0.2 M FeSO4 to be oxidized to Fe3+b)50 ml of 0.1 M H3AsO3 to be oxidized to H3As04c)25 ml of 0.1 M H202 to be oxidized to H+ and 02d)25 ml of 0.1 M SnCl2 to be oxidized to S04+Correct answer is option 'A,D'. Can you explain this answer? for JEE 2024 is part of JEE preparation. The Question and answers have been prepared according to the JEE exam syllabus. Information about Which of the following samples of reducing agents is /are chemically equivalent to 25 ml of 0.2 N KMnO4 to be reduced to Mn2+ and water.a)25 ml of 0.2 M FeSO4 to be oxidized to Fe3+b)50 ml of 0.1 M H3AsO3 to be oxidized to H3As04c)25 ml of 0.1 M H202 to be oxidized to H+ and 02d)25 ml of 0.1 M SnCl2 to be oxidized to S04+Correct answer is option 'A,D'. Can you explain this answer? covers all topics & solutions for JEE 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for Which of the following samples of reducing agents is /are chemically equivalent to 25 ml of 0.2 N KMnO4 to be reduced to Mn2+ and water.a)25 ml of 0.2 M FeSO4 to be oxidized to Fe3+b)50 ml of 0.1 M H3AsO3 to be oxidized to H3As04c)25 ml of 0.1 M H202 to be oxidized to H+ and 02d)25 ml of 0.1 M SnCl2 to be oxidized to S04+Correct answer is option 'A,D'. Can you explain this answer?.
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