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 Which of the following statements are correct in case of the carbonyl bond between carbon and oxygen?
  • a)
    Carbon is the nucleophilic centre and Oxygen is the electrophilic centre.
  • b)
    Oxygen is the nucleophilic centre and Carbon is the electrophilic centre.
  • c)
    Carbon and Oxygen double bond is polarised.
  • d)
    Both ‘b’ and ‘c’ are correct
Correct answer is option 'C'. Can you explain this answer?
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Which of the following statements are correct in case of the carbonyl ...
The double bonds in alkenes and double bonds in carbonyl groups are VERY different in terms of reactivity. The C=C is less reactive due to C=O electronegativity attributed to the oxygen and its two lone pairs of electrons.  One pair of the oxygen lone pairs are located in 2s while the other pair are in 2p orbital where its axis is directed perpendicular to the direction of the pi orbitals.  The Carbonyl groups properties are directly tied to its electronic structure as well as geometric positioning.  For example, the electronegativity of oxygen also polarizes the pi bond allowing the single bonded substituent connected to become electron withdrawing.
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Which of the following statements are correct in case of the carbonyl ...
Carbonyl Bond in Organic Chemistry

Carbonyl compounds are organic compounds that contain a carbonyl group, which is a functional group composed of a carbon atom double-bonded to an oxygen atom (C=O). The carbonyl group is one of the most important functional groups in organic chemistry, and it is found in a wide range of compounds, including aldehydes, ketones, carboxylic acids, esters, and amides. The carbonyl bond between carbon and oxygen is a polar covalent bond, which means that the electrons in the bond are not shared equally between the two atoms.

Nucleophilic and Electrophilic Centres

In organic chemistry, a nucleophile is a chemical species that has an unshared pair of electrons and is attracted to positively charged or electron-deficient atoms (electrophiles). An electrophile is a chemical species that has a partial or full positive charge and is attracted to negatively charged or electron-rich atoms (nucleophiles).

In the case of the carbonyl bond between carbon and oxygen, the carbon atom is electron-deficient and is therefore the electrophilic centre, while the oxygen atom is electron-rich and is the nucleophilic centre. This means that the oxygen atom can attack the carbon atom, forming a new bond and breaking the original carbon-oxygen bond.

Polarisation of the Carbonyl Bond

The carbonyl bond between carbon and oxygen is a polar covalent bond, meaning that the electrons in the bond are not shared equally between the two atoms. The oxygen atom is more electronegative than the carbon atom, which means that it attracts the electrons in the bond more strongly than the carbon atom. This results in a partial negative charge on the oxygen atom and a partial positive charge on the carbon atom.

The polarisation of the carbonyl bond has important implications for the reactivity of carbonyl compounds. The partial positive charge on the carbon atom makes it an electrophilic centre, which means that it can be attacked by nucleophiles. The partial negative charge on the oxygen atom makes it a nucleophilic centre, which means that it can attack electrophiles.

Conclusion

In conclusion, the carbonyl bond between carbon and oxygen is a polar covalent bond, with the carbon atom being the electrophilic centre and the oxygen atom being the nucleophilic centre. The polarisation of the bond has important implications for the reactivity of carbonyl compounds and their reactions with nucleophiles and electrophiles.
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Which of the following statements are correct in case of the carbonyl ...
As oxygen is more electronegative than carbon it is nucleophilic centre sinceC=O negative charge comes on Oxygen and due to electronegativity difference the bond is polarized
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Read the passage given below and answer the following questions:Reductive alkylation is the term applied to the process of introducing alkyl groups into ammonia or a primary or secondary amine by means of an aldehyde or ketone in the presence of a reducing agent. The present discussion is limited to those reductive alkylations in which the reducing agent is hydrogen and a catalyst or "nascent" hydrogen, usually from a metalacid combination; most of these reductive alkylations have been carried out with hydrogen and a catalyst. The principal variation excluded is that in which the reducing agent is formic acid or one of its derivatives; this modification is known as the Leuckart reaction. The process of reductive alkylation of ammonia consists in the addition of ammonia to a carbonyl compound and reduction of the addition compound or its dehydration product. The reaction usually is carried out in ethanol solution when the reduction is to be effected catalytically:Since the primary amine is formed in the presence of the aldehyde it may react in the same way as ammonia, yielding an additional compound, a Schiff's base (RCH= NCH2R) and finally, a secondary amine. Similarly, the primary amine may react with the imine, forming an addition product which also is reduced to a secondary amine Finally, the secondary amine may react with either the aldehyde or the imine to give products which are reduced to tertiary amines.Similar reactions may occur when the carbonyl compound employed is a ketone.Q. The reaction of ammonia and its derivatives with aldehydes is called

Which of the following statements are correct in case of the carbonyl bond between carbon and oxygen?a)Carbon is the nucleophilic centre and Oxygen is the electrophilic centre.b)Oxygen is the nucleophilic centre and Carbon is the electrophilic centre.c)Carbon and Oxygen double bond is polarised.d)Both ‘b’ and ‘c’ are correctCorrect answer is option 'C'. Can you explain this answer?
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Which of the following statements are correct in case of the carbonyl bond between carbon and oxygen?a)Carbon is the nucleophilic centre and Oxygen is the electrophilic centre.b)Oxygen is the nucleophilic centre and Carbon is the electrophilic centre.c)Carbon and Oxygen double bond is polarised.d)Both ‘b’ and ‘c’ are correctCorrect answer is option 'C'. Can you explain this answer? for Class 12 2024 is part of Class 12 preparation. The Question and answers have been prepared according to the Class 12 exam syllabus. Information about Which of the following statements are correct in case of the carbonyl bond between carbon and oxygen?a)Carbon is the nucleophilic centre and Oxygen is the electrophilic centre.b)Oxygen is the nucleophilic centre and Carbon is the electrophilic centre.c)Carbon and Oxygen double bond is polarised.d)Both ‘b’ and ‘c’ are correctCorrect answer is option 'C'. Can you explain this answer? covers all topics & solutions for Class 12 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for Which of the following statements are correct in case of the carbonyl bond between carbon and oxygen?a)Carbon is the nucleophilic centre and Oxygen is the electrophilic centre.b)Oxygen is the nucleophilic centre and Carbon is the electrophilic centre.c)Carbon and Oxygen double bond is polarised.d)Both ‘b’ and ‘c’ are correctCorrect answer is option 'C'. Can you explain this answer?.
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