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The energy required to break one mole of Cl - Cl bonds in Cl2 is 242 kJ mol-1. The longest wavelength of light capable of breaking a single Cl - Cl bond is(c = 3 x 108 ms-1 and NA = 6.02 x 1023 mol-1)                                                                                                                                                                       [AIEEE 2010]
  • a)
    594 nm
  • b)
    640 nm
  • c)
    700 nm
  • d)
    494 nm
Correct answer is option 'D'. Can you explain this answer?
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The energy required to break one mole of Cl - Cl bonds in Cl2 is 242 k...
Given: Energy required to break one mole of Cl-Cl bonds in Cl2 = 242 kJ mol-1

We need to find the longest wavelength of light capable of breaking a single Cl-Cl bond.

To solve this problem, we can use the following equation:

E = hc/λ

Where E is the energy of a photon, h is Planck's constant, c is the speed of light, and λ is the wavelength of light.

We know that the energy required to break one mole of Cl-Cl bonds is 242 kJ mol-1. We can convert this to energy per bond by dividing by Avogadro's number:

Energy per bond = 242 kJ mol-1 / (6.02 x 10^23 mol-1) = 4.02 x 10^-19 J

Now, we can use this energy per bond in the equation above to find the longest wavelength of light capable of breaking a single bond:

4.02 x 10^-19 J = (6.626 x 10^-34 J s)(3 x 10^8 m/s) / λ

Solving for λ, we get:

λ = (6.626 x 10^-34 J s)(3 x 10^8 m/s) / 4.02 x 10^-19 J

λ = 4.94 x 10^-7 m

Converting this to nanometers, we get:

λ = 494 nm

Therefore, the longest wavelength of light capable of breaking a single Cl-Cl bond is 494 nm, which is option D.
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The energy required to break one mole of Cl - Cl bonds in Cl2 is 242 kJ mol-1. The longest wavelength of light capable of breaking a single Cl - Cl bond is(c = 3 x 108ms-1and NA = 6.02 x 1023mol-1) [AIEEE 2010]a)594 nmb)640 nmc)700 nmd)494 nmCorrect answer is option 'D'. Can you explain this answer?
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