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Following reaction, CIF3 + AsF5 → (CIF2+ ) (AsF6-)
Q. 
Select the correct statement(s).
  • a)
    CIF3 changes its structure from pyramidal to angular in CIF+2
  • b)
    AsF5 changes to structure from angular bipyramidal to octahedral in (AsF6)-
  • c)
    Both (a) and (b) are correct
  • d)
    None of the above is correct
Correct answer is option 'B'. Can you explain this answer?
Verified Answer
Following reaction, CIF3 + AsF5 → (CIF2+ ) (AsF6-)Q.Select the c...
 sp3d -hybridised Cl-atom - (T-shaped s tructure)
  sp3 -hybridised. Cl-atom (Bent)
 sp3d -hybridised As-atom (Trigonal bipyramidai).
 sp3d2 -hybridised As-atom (Octahedral).
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Most Upvoted Answer
Following reaction, CIF3 + AsF5 → (CIF2+ ) (AsF6-)Q.Select the c...
Statement: AsF5 changes its structure from angular bipyramidal to octahedral in (AsF6)-

Explanation:
- The molecular structure of AsF5 is angular bipyramidal, where the central atom (As) is surrounded by five fluorine atoms in a trigonal bipyramidal arrangement.
- On reacting with CIF3, AsF5 forms CIF2, which is a complex of CIF3 with AsF5.
- The central atom in CIF2 is still As, but it is now surrounded by four fluorine atoms from CIF3 and one fluorine atom from AsF5.
- In the complex (AsF6)-, the structure of AsF5 changes from angular bipyramidal to octahedral.
- The (AsF6)- ion consists of the central atom (As) surrounded by six fluorine atoms in an octahedral arrangement.
- This change in structure occurs due to the formation of additional bonds between the central atom (As) and the fluorine atoms from CIF3, resulting in the formation of an octahedral structure.
- Therefore, statement (b) is correct.

Conclusion:
The correct statement is:
(b) AsF5 changes its structure from angular bipyramidal to octahedral in (AsF6)-
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Following reaction, CIF3 + AsF5 → (CIF2+ ) (AsF6-)Q.Select the correct statement(s).a)CIF3 changes its structure from pyramidal to angular in CIF+2b)AsF5changes to structure from angular bipyramidal to octahedral in (AsF6)-c)Both (a) and (b) are correctd)None of the above is correctCorrect answer is option 'B'. Can you explain this answer?
Question Description
Following reaction, CIF3 + AsF5 → (CIF2+ ) (AsF6-)Q.Select the correct statement(s).a)CIF3 changes its structure from pyramidal to angular in CIF+2b)AsF5changes to structure from angular bipyramidal to octahedral in (AsF6)-c)Both (a) and (b) are correctd)None of the above is correctCorrect answer is option 'B'. Can you explain this answer? for Class 11 2024 is part of Class 11 preparation. The Question and answers have been prepared according to the Class 11 exam syllabus. Information about Following reaction, CIF3 + AsF5 → (CIF2+ ) (AsF6-)Q.Select the correct statement(s).a)CIF3 changes its structure from pyramidal to angular in CIF+2b)AsF5changes to structure from angular bipyramidal to octahedral in (AsF6)-c)Both (a) and (b) are correctd)None of the above is correctCorrect answer is option 'B'. Can you explain this answer? covers all topics & solutions for Class 11 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for Following reaction, CIF3 + AsF5 → (CIF2+ ) (AsF6-)Q.Select the correct statement(s).a)CIF3 changes its structure from pyramidal to angular in CIF+2b)AsF5changes to structure from angular bipyramidal to octahedral in (AsF6)-c)Both (a) and (b) are correctd)None of the above is correctCorrect answer is option 'B'. Can you explain this answer?.
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