Ethanal reacts with alkali to give 3-hydroxybutanal. the reaction isa)...
Aldol reaction is an important organic reaction of aldehydes and ketones. This reaction is shown by aldehydes and Ketones having alpha-hydrogen atom in the compound. Such a-hydrogen atom containing aldehydes and ketones will undergo self condensation in presence dilute alkalies like dil.NaOH (dilute Sodium hydroxide), dil.Ba(OH)2(dilute Barium hydroxide) forming alpha, β-hydroxyaldehyde (an aldol) or β-hydroxyketone (a Ketol) .The Aldol or the Ketol thus formed in the reaction upon heating eliminates a molecule of water (i.e. it undergoes dehydration) forming alpha, β-unsaturated Aldehydes or Ketones respectively. This reaction now is called Aldol condensation reaction.
View all questions of this test
Ethanal reacts with alkali to give 3-hydroxybutanal. the reaction isa)...
Aldol condensation is the correct answer.
Explanation:
Aldol condensation is a reaction between two carbonyl compounds, such as aldehydes or ketones, to form a β-hydroxy carbonyl compound. In this reaction, a molecule of water is eliminated, and a new carbon-carbon bond is formed.
In the given reaction, ethanal (also known as acetaldehyde) reacts with an alkali to give 3-hydroxybutanal. Let's break down the reaction step by step:
Step 1: Formation of enolate ion
Ethanal (CH3CHO) reacts with an alkali (such as sodium hydroxide, NaOH) to form an enolate ion. The alkali acts as a base and abstracts a proton from the α-carbon of ethanal, resulting in the formation of an enolate ion. The enolate ion has a negative charge on the oxygen and a double bond between the carbon and oxygen.
CH3CHO + NaOH → CH3CH(OH)Na
Step 2: Attack of enolate ion on another molecule of ethanal
The enolate ion now acts as a nucleophile and attacks another molecule of ethanal. The nucleophilic carbon of the enolate ion attacks the carbonyl carbon of the second ethanal molecule, resulting in the formation of a new carbon-carbon bond.
CH3CH(OH)Na + CH3CHO → CH3CH(OH)CH(OH)CH3
Step 3: Elimination of water molecule
In the final step, a water molecule is eliminated from the β-hydroxy carbonyl compound formed in the previous step. This elimination of water leads to the formation of 3-hydroxybutanal.
CH3CH(OH)CH(OH)CH3 → CH3CH(OH)CH2CHO + H2O
Therefore, the given reaction between ethanal and alkali to give 3-hydroxybutanal is an example of aldol condensation.
Ethanal reacts with alkali to give 3-hydroxybutanal. the reaction isa)...
The answer can be guessed from the product as it is possible through aldol condensation
To make sure you are not studying endlessly, EduRev has designed JEE study material, with Structured Courses, Videos, & Test Series. Plus get personalized analysis, doubt solving and improvement plans to achieve a great score in JEE.