JEE Exam  >  JEE Questions  >  For a 1st order parallel reaction the Arrheni... Start Learning for Free
For a 1st order parallel reaction the Arrhenius factor for formation of two products are 10 ki power 10 and 10 ki power 8 sec -1 and the anergy of activation is 150 kj / mole and 75 kj / mole . At what temperature the twi product will be formed at the the same rate?
Most Upvoted Answer
For a 1st order parallel reaction the Arrhenius factor for formation o...
**1. Introduction:**
In this problem, we are given the Arrhenius factors (pre-exponential factors) and activation energies for two parallel reactions. We need to determine the temperature at which the two reactions will occur at the same rate.

**2. Arrhenius Equation:**
The rate constant (k) of a reaction can be calculated using the Arrhenius equation:
k = A * exp(-Ea/RT)
where:
- k is the rate constant
- A is the Arrhenius factor (pre-exponential factor)
- Ea is the activation energy
- R is the gas constant (8.314 J/mol·K)
- T is the temperature in Kelvin

**3. Mathematical Approach:**
To find the temperature at which the two reactions occur at the same rate, we can set the rate constants of the two reactions equal to each other and solve for T.

For the first reaction:
k1 = A1 * exp(-Ea1/RT)

For the second reaction:
k2 = A2 * exp(-Ea2/RT)

Setting k1 = k2, we have:
A1 * exp(-Ea1/RT) = A2 * exp(-Ea2/RT)

Taking the natural logarithm (ln) of both sides:
ln(A1) - (Ea1/RT) = ln(A2) - (Ea2/RT)

Rearranging the equation:
(Ea2 - Ea1)/R * (1/T) = ln(A1/A2)

Simplifying the equation:
1/T = (Ea2 - Ea1)/(R * ln(A1/A2))

Finally, we can solve for T by taking the reciprocal of both sides:
T = (R * ln(A1/A2))/(Ea2 - Ea1)

**4. Calculation:**
Plugging in the given values:
A1 = 10^10 sec^-1
A2 = 10^8 sec^-1
Ea1 = 150 kJ/mol
Ea2 = 75 kJ/mol
R = 8.314 J/mol·K

Calculating the temperature:
T = (8.314 J/mol·K * ln(10^10/10^8))/(75 kJ/mol - 150 kJ/mol)

Converting kJ to J and simplifying:
T = (8.314 * ln(100))/(75 - 150)
T = (8.314 * ln(100))/(-75)

Using the properties of natural logarithm:
T ≈ (8.314 * 4.605)/(75 * -1.0)
T ≈ -0.383 K

**5. Conclusion:**
The calculated temperature of -0.383 K is not physically meaningful as temperatures cannot be negative. This suggests that the two reactions will never occur at the same rate.
Community Answer
For a 1st order parallel reaction the Arrhenius factor for formation o...
Explore Courses for JEE exam

Similar JEE Doubts

For a 1st order parallel reaction the Arrhenius factor for formation of two products are 10 ki power 10 and 10 ki power 8 sec -1 and the anergy of activation is 150 kj / mole and 75 kj / mole . At what temperature the twi product will be formed at the the same rate?
Question Description
For a 1st order parallel reaction the Arrhenius factor for formation of two products are 10 ki power 10 and 10 ki power 8 sec -1 and the anergy of activation is 150 kj / mole and 75 kj / mole . At what temperature the twi product will be formed at the the same rate? for JEE 2024 is part of JEE preparation. The Question and answers have been prepared according to the JEE exam syllabus. Information about For a 1st order parallel reaction the Arrhenius factor for formation of two products are 10 ki power 10 and 10 ki power 8 sec -1 and the anergy of activation is 150 kj / mole and 75 kj / mole . At what temperature the twi product will be formed at the the same rate? covers all topics & solutions for JEE 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for For a 1st order parallel reaction the Arrhenius factor for formation of two products are 10 ki power 10 and 10 ki power 8 sec -1 and the anergy of activation is 150 kj / mole and 75 kj / mole . At what temperature the twi product will be formed at the the same rate?.
Solutions for For a 1st order parallel reaction the Arrhenius factor for formation of two products are 10 ki power 10 and 10 ki power 8 sec -1 and the anergy of activation is 150 kj / mole and 75 kj / mole . At what temperature the twi product will be formed at the the same rate? in English & in Hindi are available as part of our courses for JEE. Download more important topics, notes, lectures and mock test series for JEE Exam by signing up for free.
Here you can find the meaning of For a 1st order parallel reaction the Arrhenius factor for formation of two products are 10 ki power 10 and 10 ki power 8 sec -1 and the anergy of activation is 150 kj / mole and 75 kj / mole . At what temperature the twi product will be formed at the the same rate? defined & explained in the simplest way possible. Besides giving the explanation of For a 1st order parallel reaction the Arrhenius factor for formation of two products are 10 ki power 10 and 10 ki power 8 sec -1 and the anergy of activation is 150 kj / mole and 75 kj / mole . At what temperature the twi product will be formed at the the same rate?, a detailed solution for For a 1st order parallel reaction the Arrhenius factor for formation of two products are 10 ki power 10 and 10 ki power 8 sec -1 and the anergy of activation is 150 kj / mole and 75 kj / mole . At what temperature the twi product will be formed at the the same rate? has been provided alongside types of For a 1st order parallel reaction the Arrhenius factor for formation of two products are 10 ki power 10 and 10 ki power 8 sec -1 and the anergy of activation is 150 kj / mole and 75 kj / mole . At what temperature the twi product will be formed at the the same rate? theory, EduRev gives you an ample number of questions to practice For a 1st order parallel reaction the Arrhenius factor for formation of two products are 10 ki power 10 and 10 ki power 8 sec -1 and the anergy of activation is 150 kj / mole and 75 kj / mole . At what temperature the twi product will be formed at the the same rate? tests, examples and also practice JEE tests.
Explore Courses for JEE exam

Top Courses for JEE

Explore Courses
Signup for Free!
Signup to see your scores go up within 7 days! Learn & Practice with 1000+ FREE Notes, Videos & Tests.
10M+ students study on EduRev