Calculate W and ∆E for the conversion of 1 mole of water into 1 mole o...
**Calculation of work (W):**
The work done during the conversion of water into steam can be calculated using the equation:
W = P∆V
Where:
W = work done
P = pressure
∆V = change in volume
In this case, we are given that the pressure is 1 atm. To calculate the change in volume, we need to consider the difference in volume between 1 mole of water and 1 mole of steam.
The molar volume of water at 373K and 1 atm pressure is approximately 18 cm³/mol. The molar volume of steam at the same temperature and pressure is approximately 30.5 cm³/mol.
Therefore, the change in volume (∆V) is:
∆V = (30.5 - 18) cm³/mol = 12.5 cm³/mol
Now we can calculate the work done (W):
W = (1 atm) * (12.5 cm³/mol) = 12.5 atm·cm³/mol
**Calculation of ∆E (Change in Energy):**
The change in energy (∆E) during the conversion of water into steam can be calculated using the equation:
∆E = q + W
Where:
∆E = change in energy
q = heat transferred
W = work done
In this case, we are given that the latent heat of vaporization of water is 9720 cal/mol. The heat transferred (q) can be calculated by multiplying the latent heat by the number of moles of water:
q = (9720 cal/mol) * (1 mol) = 9720 cal
Now we can calculate the change in energy (∆E):
∆E = (9720 cal) + (12.5 atm·cm³/mol)
Since atm·cm³ is not a standard unit for energy, we need to convert it to cal. 1 atm·cm³ is equivalent to 101.325 J. And 1 J is equivalent to 0.24 cal.
Therefore:
∆E = (9720 cal) + (12.5 atm·cm³/mol) * (101.325 J) * (0.24 cal/J)
∆E = (9720 cal) + (303.66 cal)
∆E ≈ 10023.66 cal
Therefore, the change in energy (∆E) during the conversion of 1 mole of water into 1 mole of steam at a temperature of 373K and a pressure of 1 atm is approximately 10023.66 cal.
Calculate W and ∆E for the conversion of 1 mole of water into 1 mole o...
Q= W+ ∆E
∆E =0 because during phase change of liquid into vapour temp. remains constant.
so Q=W
Q=m×L mass of one mole water will be equal to it's molecular wt. that is 18g.
also L=9720 cal/mol
1 mol=18g
for 18g L is 9720 so for 1g it would be 9720/18=540 cal/g
so now Q=18×540=9720 cal.
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