20% weight by weight of NaOH solution (density=1.2 gm/cc.calculate mol...
Molality means no. of moles of solute per 1000 g or per kg of solvent.Molar mass of NaOH = 23+1+16 = 40 g/mol. So, 4% NaOH aq. means 40 g or 1 mole NaOH in 1000 ml (=1000 g or 1kg) water. Molatity = 1 mol solute / 1kg solvent =1 mol/kg.Volume of solution = mass of solution (40+1000 = 1040 g) /density of 1.2 g per cc = 866.7 cc, which has 1 mole solute in it. Therefore no. of moles of solute per 1000 cc or 1 litre solution = 1000 x1 / 866.7 = 1.153 mole per litre.Mole fraction of NaOH = No. of moles of NaOH / Total moles = 1.0 / (1.0 + 1000 g /18 g per mole) = 1.0 /(1 + 55.55) = 0.017 (it is unitless). Mole fraction of water = 55.55 /56.55 = 0.982. Also, the sum of mole fractions is always 1.00. Rememer, molality is a mass/ /maa unit. So, it the best unit because it is temperature independent whereas molarity is mass /volume unit which is dependent on temp.
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20% weight by weight of NaOH solution (density=1.2 gm/cc.calculate mol...
Calculating Molarity of a NaOH Solution
To calculate the molarity of a NaOH solution, we need to know the weight of NaOH and the volume of the solution. In this case, we are given the weight of NaOH as 20% weight by weight and the density of the solution as 1.2 gm/cc.
Step 1: Convert Weight Percentage to Grams
First, we need to convert the weight percentage of NaOH to grams. Since the solution is 20% weight by weight, it means that 20 grams of NaOH is present in every 100 grams of the solution.
Step 2: Calculate the Weight of NaOH
To calculate the weight of NaOH, we can assume a convenient volume for the solution, such as 100 ml. Since the density of the solution is 1.2 gm/cc, the weight of the solution can be calculated as follows:
Weight of the solution = Volume of the solution x Density of the solution
Weight of the solution = 100 ml x 1.2 gm/cc = 120 grams
Therefore, the weight of NaOH in the solution is:
Weight of NaOH = Weight of the solution x Weight percentage of NaOH
Weight of NaOH = 120 grams x 20% = 24 grams
Step 3: Calculate the Molarity
To calculate the molarity, we need to know the molar mass of NaOH, which is 22.99 g/mol for Na, 16.00 g/mol for O, and 1.01 g/mol for H.
Molar mass of NaOH = 22.99 g/mol + 16.00 g/mol + 1.01 g/mol = 40.00 g/mol
Molarity (M) = Number of moles of solute / Volume of solution in liters
Number of moles of NaOH = Weight of NaOH / Molar mass of NaOH
Volume of solution = Weight of the solution / Density of the solution
Using the given values, we can calculate the molarity as follows:
Number of moles of NaOH = 24 grams / 40.00 g/mol = 0.6 moles
Volume of solution = 120 grams / 1.2 gm/cc = 100 ml / 1000 = 0.1 liters
Molarity (M) = 0.6 moles / 0.1 liters = 6 M
Therefore, the molarity of the NaOH solution is 6 M.
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