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CH4 is subjected to photochemical reaction and changes to CH3CI, CH2CI2, CHCI3 and CCI4.
Q. One of the intermediates of the photochemical reaction is
  • a)
    methyl free radical with one unpaired electron, paramagnetic and sp2-hybridised carbon
  • b)
    methyl carbocation with no lone pair sp2- hybridised carbon
  • c)
    methyl carbanion with one lone pair sp3- hybridised carbon
  • d)
    methyl free radical with one unpaired electron, paramagnetic sp3-hybridised carbon
Correct answer is option 'A'. Can you explain this answer?
Verified Answer
CH4 is subjected to photochemical reaction and changes to CH3CI, CH2CI...

 has one unpaired electron in unhybridised p-orbital.
Thus, sp2-hybridised paramagnetic.
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Most Upvoted Answer
CH4 is subjected to photochemical reaction and changes to CH3CI, CH2CI...
Explanation:

Photochemical Reaction of CH4:
- When CH4 is subjected to a photochemical reaction, it undergoes a series of reactions leading to the formation of CH3Cl, CH2Cl2, CHCl3, and CCl4.

Formation of Methyl Free Radical:
- One of the intermediates in this reaction is a methyl free radical (CH3•).
- A methyl free radical is a species with one unpaired electron, making it paramagnetic.
- The carbon in the methyl free radical is sp2-hybridized, allowing for the presence of the unpaired electron.

Explanation of Options:
- Option a) states that the intermediate is a methyl free radical with one unpaired electron, paramagnetic, and sp2-hybridized carbon, which aligns with the characteristics of a methyl free radical formed during the photochemical reaction of CH4.
- Option b) describes a methyl carbocation, which is a positively charged species with no lone pair and sp2-hybridized carbon, which is not consistent with the intermediate formed in this reaction.
- Option c) mentions a methyl carbanion, which is a negatively charged species with one lone pair and sp3-hybridized carbon, which is not the intermediate formed in this reaction.
- Option d) describes a methyl free radical with sp3-hybridized carbon, which is incorrect as the methyl free radical formed in this reaction is sp2-hybridized.
Therefore, the correct answer is option 'A', as it accurately describes the characteristics of the intermediate formed during the photochemical reaction of CH4.
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CH4 is subjected to photochemical reaction and changes to CH3CI, CH2CI2, CHCI3 and CCI4.Q.One of the intermediates of the photochemical reaction isa)methyl free radical with one unpaired electron, paramagnetic and sp2-hybridised carbonb)methyl carbocation with no lone pair sp2- hybridised carbonc)methyl carbanion with one lone pair sp3- hybridised carbond)methyl free radical with one unpaired electron, paramagnetic sp3-hybridised carbonCorrect answer is option 'A'. Can you explain this answer?
Question Description
CH4 is subjected to photochemical reaction and changes to CH3CI, CH2CI2, CHCI3 and CCI4.Q.One of the intermediates of the photochemical reaction isa)methyl free radical with one unpaired electron, paramagnetic and sp2-hybridised carbonb)methyl carbocation with no lone pair sp2- hybridised carbonc)methyl carbanion with one lone pair sp3- hybridised carbond)methyl free radical with one unpaired electron, paramagnetic sp3-hybridised carbonCorrect answer is option 'A'. Can you explain this answer? for Class 11 2024 is part of Class 11 preparation. The Question and answers have been prepared according to the Class 11 exam syllabus. Information about CH4 is subjected to photochemical reaction and changes to CH3CI, CH2CI2, CHCI3 and CCI4.Q.One of the intermediates of the photochemical reaction isa)methyl free radical with one unpaired electron, paramagnetic and sp2-hybridised carbonb)methyl carbocation with no lone pair sp2- hybridised carbonc)methyl carbanion with one lone pair sp3- hybridised carbond)methyl free radical with one unpaired electron, paramagnetic sp3-hybridised carbonCorrect answer is option 'A'. Can you explain this answer? covers all topics & solutions for Class 11 2024 Exam. Find important definitions, questions, meanings, examples, exercises and tests below for CH4 is subjected to photochemical reaction and changes to CH3CI, CH2CI2, CHCI3 and CCI4.Q.One of the intermediates of the photochemical reaction isa)methyl free radical with one unpaired electron, paramagnetic and sp2-hybridised carbonb)methyl carbocation with no lone pair sp2- hybridised carbonc)methyl carbanion with one lone pair sp3- hybridised carbond)methyl free radical with one unpaired electron, paramagnetic sp3-hybridised carbonCorrect answer is option 'A'. Can you explain this answer?.
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