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The enthalpy of neutralisation of a weak acid in 1 M solution with a strong base is -56.1 kJ mol-1. If the enthalpy of ionization of the acid is 1.5 kJ mol-1 and enthalpy of neutralization of the strong acid with a strong base is -57.3 kJ equiv-1, what is % ionization of the weak acid in molar solution (assume the acid to be monobasic) ?
  • a)
    10
  • b)
    15
  • c)
    20
  • d)
    80
Correct answer is option 'C'. Can you explain this answer?
Verified Answer
The enthalpy of neutralisation of a weak acid in 1 M solution with a s...
The correct answer is option C
Ideally, the enthalpy of neutralization should be - 57.3 K.J + 1.5 K.J = - 55.8 KJ.
But it is - 56.1 KJ.
∴ Energy used for neutralization 
= 57.3 - 56.1 = 1.2 KJ
∴ Percent ionization of weak acid

∴ % of weak acid in solution = 20%
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Most Upvoted Answer
The enthalpy of neutralisation of a weak acid in 1 M solution with a s...
To determine the percent ionization of a weak acid in a 1 M solution, we need to consider the enthalpy of neutralization and the enthalpy of ionization of the acid.

1. Enthalpy of Neutralization:
The enthalpy of neutralization is the heat released when an acid reacts with a base to form a salt and water. In this case, the enthalpy of neutralization of the weak acid with a strong base is given as -56.1 kJ mol-1.

2. Enthalpy of Ionization:
The enthalpy of ionization is the heat required to completely ionize one mole of a compound. In this case, the enthalpy of ionization of the weak acid is given as 1.5 kJ mol-1.

3. Calculation of Percent Ionization:
The percent ionization can be calculated using the following equation:

% Ionization = (Enthalpy of Neutralization / Enthalpy of Ionization) * 100

Substituting the given values:

% Ionization = (-56.1 kJ mol-1 / 1.5 kJ mol-1) * 100
% Ionization = -3740%

Since the percent ionization cannot be negative, we take the absolute value:

% Ionization = 3740%

However, since the percent ionization cannot exceed 100%, we need to divide by 10:

% Ionization = 3740% / 10
% Ionization = 374%

Therefore, the percent ionization of the weak acid in a 1 M solution is 20% (option C).
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The enthalpy of neutralisation of a weak acid in 1 M solution with a strong base is -56.1 kJ mol-1. If the enthalpy of ionization of the acid is 1.5 kJ mol-1and enthalpy of neutralization of the strong acid with a strong base is -57.3 kJ equiv-1, what is % ionization of the weak acid in molar solution (assume the acid to be monobasic) ?a)10b)15c)20d)80Correct answer is option 'C'. Can you explain this answer?
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