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Reaction involving gold have been of particular interest to a chemist. Consider the following reactions.
Au(OH)3 + 4 HCl → HAuCl4 + 3H2O,         ΔH = -28 kcal
Au(OH)3 + 4 HBr → HAuBr4 + 3 H2O,       ΔH = -36.8 kcal
In an experiment there was an absorption of 0.44 kcal when one mole of HAuBr4 was mixed with 4 moles of HCl. What is the percentage conversion of HAuBr4 into HAuCl4 ?
  • a)
     0.5 %
  • b)
    0.6 %
  • c)
    5 %
  • d)
    50 %
Correct answer is option 'C'. Can you explain this answer?
Verified Answer
Reaction involving gold have been of particular interest to a chemist....
Au(OH)3 + 4HCl → HAuCl4+ 3H2O…(1) ∆H₁=-28kcal
Au(OH)3 + 4HBr → HAuBr4 + 3H2O ...(2) ∆H₂= -36.8kcal
To convert HAuBr4 to HAuCl4, the net reaction is
HAuBr4 + 4HCl→ HAuCl4 + 4HBr ...∆H=?
For the above reaction: 
∆H =∆H₁ - ∆H₂
      = -28 - (-36.8) = 8.8 kcal
Thus to convert one mole of HAuBr4 to HAuCl4 we require 8.8 kcal energy but since the energy absorbed is 0.44 kcal.
hence %conversion =[(0.44)/(8.8)] x 100
                                = 5%
Hence the percentage conversion is 5%.

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Most Upvoted Answer
Reaction involving gold have been of particular interest to a chemist....
The reaction between Au(OH)3 and 4 HCl would result in the formation of gold chloride (AuCl3) and water (H2O). This reaction can be represented by the following balanced chemical equation:

Au(OH)3 + 4 HCl → AuCl3 + 3 H2O

In this reaction, the gold hydroxide (Au(OH)3) reacts with hydrochloric acid (HCl) to form gold chloride (AuCl3) and water (H2O). This type of reaction is called a displacement reaction, where the chloride ions from the hydrochloric acid displace the hydroxide ions from the gold hydroxide, resulting in the formation of gold chloride.

This reaction is of interest to chemists because gold chloride is an important compound in various applications, such as in gold plating, catalysts, and in the synthesis of other gold compounds. Additionally, studying the reactions of gold compounds helps to understand the reactivity and behavior of gold in different chemical environments.
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Reaction involving gold have been of particular interest to a chemist. Consider the following reactions.Au(OH)3+ 4 HCl →HAuCl4+ 3H2O,ΔH = -28 kcalAu(OH)3+ 4 HBr →HAuBr4+ 3 H2O, ΔH = -36.8 kcalIn an experiment there was an absorption of 0.44 kcal when one mole of HAuBr4was mixed with 4 moles of HCl. What is the percentage conversion of HAuBr4into HAuCl4?a)0.5 %b)0.6 %c)5 %d)50 %Correct answer is option 'C'. Can you explain this answer?
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