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Select the set of compounds with oxidation-reduction duality.
  • a)
    Cl2, H3PO4, HCHO, HNO2
  • b)
    Cl2, H3PO3, C6H5CHO, H2O2
  • c)
    Br2, H3PO2, CH3CHO, H3PO4
  • d)
    CrO2Cl2, KMnO4, SO3, CO2
Correct answer is option 'B'. Can you explain this answer?
Most Upvoted Answer
Select the set of compounds with oxidation-reduction duality.a)Cl2, H3...
Com pounds having oxidising and reducing nature in given reaction are said to have oxidation-reduction duality. Such compounds are said to undergo disproportionation reaction.



(This is called Cannizzaro reaction.)

Note Such compounds have O.N. of the affected atoms intermediate of oxidation part and reduction part
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Select the set of compounds with oxidation-reduction duality.a)Cl2, H3...
Oxidation-reduction duality refers to the ability of a compound to act as an oxidizing agent or a reducing agent depending on the reaction conditions. In other words, it can either gain or lose electrons in a redox reaction.

The set of compounds with oxidation-reduction duality is:

b) Cl2, H3PO3, C6H5CHO, H2O2

Explanation:

- Cl2 (chlorine) can act as both an oxidizing agent and a reducing agent, depending on the reaction conditions. For example, in the reaction with FeCl2, it acts as an oxidizing agent, whereas in the reaction with NaI, it acts as a reducing agent.
- H3PO3 (phosphorous acid) can also act as both an oxidizing agent and a reducing agent. For example, in the reaction with HCl, it acts as a reducing agent, whereas in the reaction with H2O2, it acts as an oxidizing agent.
- C6H5CHO (benzaldehyde) can undergo oxidation to form benzoic acid, which is a stronger acid and a better oxidizing agent. It can also undergo reduction to form benzyl alcohol, which is a weaker acid and a better reducing agent.
- H2O2 (hydrogen peroxide) is a strong oxidizing agent and can undergo reduction to form water. It can also act as a reducing agent in the presence of certain catalysts.

Therefore, option B is the correct answer as it contains a set of compounds that have oxidation-reduction duality.
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