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Alkyl halides react with dialkyl copper reagents to give  
[AIEEE-2005]
  • a)
    alkyl copper halides
  • b)
    alkenes
  • c)
    alkenyl halides
  • d)
    alkanes
Correct answer is option 'D'. Can you explain this answer?
Verified Answer
Alkyl halides react with dialkyl copper reagents to give[AIEEE-2005]a)...
Answer
In Corey House synthesis of alkane, alkyl halide reacts with lithium dialkyl cuprate.
R2CuLi + R’X → R-R’ + RCu + LiX
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Alkyl halides react with dialkyl copper reagents to give[AIEEE-2005]a)...
The correct answer is option D
Alkyl halides react with dialkyl copper reagents to give alkanes. The reaction is called Corey House synthesis.
R2​CuLi+R′X→R−R′+RCu + LiX
For example, ethyl iodide reacts with lithium diethyl cuprate to form butane.
(C2​H5​)2​CuLi+C2​H5​−I→C2​H5​−C2​H5​+C2​H5​Cu + LiI
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Alkyl halides react with dialkyl copper reagents to give[AIEEE-2005]a)alkyl copper halidesb)alkenesc)alkenyl halidesd)alkanesCorrect answer is option 'D'. Can you explain this answer?
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