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Alkyl halides react with dialkyl copper reagents to give
[AIEEE-2005]
- a)alkyl copper halides
- b)alkenes
- c)alkenyl halides
- d)alkanes
Correct answer is option 'D'. Can you explain this answer?
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Alkyl halides react with dialkyl copper reagents to give[AIEEE-2005]a)...
Answer
In Corey House synthesis of alkane, alkyl halide reacts with lithium dialkyl cuprate.
R2CuLi + R’X → R-R’ + RCu + LiX
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Alkyl halides react with dialkyl copper reagents to give[AIEEE-2005]a)...
The correct answer is option D
Alkyl halides react with dialkyl copper reagents to give alkanes. The reaction is called Corey House synthesis.
R2CuLi+R′X→R−R′+RCu + LiX
For example, ethyl iodide reacts with lithium diethyl cuprate to form butane.
(C2H5)2CuLi+C2H5−I→C2H5−C2H5+C2H5Cu + LiI
Alkyl halides react with dialkyl copper reagents to give alkanes. The reaction is called Corey House synthesis.
R2CuLi+R′X→R−R′+RCu + LiX
For example, ethyl iodide reacts with lithium diethyl cuprate to form butane.
(C2H5)2CuLi+C2H5−I→C2H5−C2H5+C2H5Cu + LiI
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Alkyl halides react with dialkyl copper reagents to give[AIEEE-2005]a)alkyl copper halidesb)alkenesc)alkenyl halidesd)alkanesCorrect answer is option 'D'. Can you explain this answer?
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