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The chemical reaction in which reactants require high amount of activation energy are generally
  • a)
    Slow
  • b)
    Spontaneous
  • c)
    Instantaneous
  • d)
    Fast
Correct answer is option 'A'. Can you explain this answer?
Verified Answer
The chemical reaction in which reactants require high amount of activa...
If activation energy is high rate of reaction will decrease and reaction will be slow.
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The chemical reaction in which reactants require high amount of activa...
Introduction:
Chemical reactions involve the breaking and formation of chemical bonds between atoms. In order for a reaction to occur, the reactant molecules must overcome a certain energy barrier called activation energy. The activation energy is the minimum energy required to initiate a chemical reaction.

Explanation:
The chemical reactions in which reactants require a high amount of activation energy are generally slow. This is because a higher activation energy means that the reactant molecules need more energy to reach the transition state, where the bonds are in the process of breaking and forming.

Factors affecting reaction rate:
The rate of a chemical reaction is determined by several factors, including the concentration of reactants, temperature, surface area, and the presence of a catalyst. However, the activation energy plays a crucial role in determining the speed of the reaction.

Activation energy and reaction rate:
The activation energy can be thought of as a barrier that reactant molecules must overcome in order to react. The higher the activation energy, the slower the reaction will be. This is because a higher activation energy requires more energy to be supplied to the reactant molecules, which can be achieved through an increase in temperature.

Reaction profiles:
A reaction profile is a graphical representation that shows the energy changes that occur during a chemical reaction. The reactants are shown on the left side, and the products are shown on the right side. The energy of the reactants is represented by the starting point of the reaction profile, and the energy of the products is represented by the ending point.

Reaction profiles for slow and fast reactions:
For a slow reaction, the reactants require a high activation energy to reach the transition state, as shown by a steep uphill slope on the reaction profile. The reaction proceeds slowly, as the reactant molecules need to collide with enough energy to overcome the activation energy barrier.

In contrast, for a fast reaction, the reactants require a low activation energy to reach the transition state, as shown by a shallow uphill slope on the reaction profile. The reaction proceeds quickly, as the reactant molecules can easily overcome the activation energy barrier.

Conclusion:
In conclusion, the chemical reactions in which reactants require a high amount of activation energy are generally slow. The activation energy acts as a barrier that the reactant molecules must overcome in order to react. The higher the activation energy, the slower the reaction will be. It is important to note that other factors such as concentration, temperature, surface area, and the presence of a catalyst also influence the reaction rate.
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Read the passage given below and answer the following questions:Nucleophilic substitution reaction of haloalkane can be conducted according to both SN1 and SN2 mechanisms. However, which mechanism it is based on is related to such factors as the structure of haloalkane, and properties of leaving group, nucleophilic reagent and solvent. Influences of halogen: No matter which mechanism the nucleophilic substitution reaction is based on, the leaving group always leave the central carbon atom with electron pair. This is just the opposite of the situation that nucleophilic reagent attacks the central carbon atom with electron pair. Therefore, the weaker the alkalinity of leaving group is , the more stable the anion formed is and it will be more easier for the leaving group to leave the central carbon atom; that is to say, the reactant is more easier to be substituted. The alkalinity order of halogen ion is I− < Br− < Cl− < F− and the order of their leaving tendency should be I− > Br− > Cl− > F−. Therefore, in four halides with the same alkyl and different halogens, the order of substitution reaction rate is RI > RBr > RCl > RF. In addition, if the leaving group is very easy to leave, many carbocation intermediates are generated in the reaction and the reaction is based on SN1 mechanism. If the leaving group is not easy to leave, the reaction is based on SN2 mechanism. Influences of solvent polarity: In SN1 reaction, the polarity of the system increases from the reactant to the transition state, because polar solvent has a greater stabilizing effect on the transition state than the reactant, thereby reduce activation energy and accelerate the reaction. In SN2 reaction, the polarity of the system generally does not change from the reactant to the transition state and only charge dispersion occurs. At this time, polar solvent has a great stabilizing effect on Nu than the transition state, thereby increasing activation energy and slow down the reaction rate. For example, the decomposition rate (SN1) of tertiary chlorobutane in 25° water (dielectric constant 79) is 300000 times faster than in ethanol (dielectric constant 24). The reaction rate (SN2) of 2-bromopropane and NaOH in ethanol containing 40% water is twice slower than in absolute ethanol. In a word, the level of solvent polarity has influence on both SN1 and SN2 reactions, but with different results. Generally speaking, weak polar solvent is favorable for SN2 reaction, while strong polar solvent is favorable for SN1 reaction, because only under the action of polar solvent can halogenated hydrocarbon dissociate into carbocation and halogen ion and solvents with a strong polarity is favorable for solvation of carbocation, increasing its stability. Generally speaking, the substitution reaction of tertiary haloalkane is based on SN1 mechanism in solvents with a strong polarity (for example, ethanol containing water).Q. Polar solvents make the reaction faster as they

The chemical reaction in which reactants require high amount of activation energy are generallya)Slowb)Spontaneousc)Instantaneousd)FastCorrect answer is option 'A'. Can you explain this answer?
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