The Mn3 ion is unstable in solution and undergoes disproportionation ...
2e- + 2 H2O +2mn3+-------------=mn2+ mnO2 +4H+
is the reaction is correct?
The Mn3 ion is unstable in solution and undergoes disproportionation ...
The disproportionation of the Mn3+ ion in solution can be represented by the following balanced ionic equation:
2Mn3+ (aq) → Mn2+ (aq) + MnO2 (s) + 2H+ (aq)
Explanation:
1. Oxidation State of Mn:
The Mn3+ ion has a +3 oxidation state, which means it has lost three electrons.
2. Disproportionation:
Disproportionation is a redox reaction in which the same element undergoes both oxidation and reduction simultaneously. In this case, the Mn3+ ion undergoes disproportionation to form both Mn2+ and MnO2.
3. Formation of Mn2+:
In the reaction, two Mn3+ ions each lose one electron to form two Mn2+ ions. This is a reduction process as the Mn3+ ions are gaining electrons and their oxidation state decreases from +3 to +2.
4. Formation of MnO2:
Simultaneously, one Mn3+ ion loses two electrons to form MnO2, which is manganese dioxide. This is an oxidation process as the Mn3+ ion is losing electrons and its oxidation state increases from +3 to +4.
5. Formation of H+:
The reaction also involves the formation of two H+ ions. This indicates that the reaction is taking place in an acidic solution.
6. Balanced Equation:
By balancing the number of atoms and charges on both sides of the equation, the balanced ionic equation for the disproportionation of the Mn3+ ion is obtained as:
2Mn3+ (aq) → Mn2+ (aq) + MnO2 (s) + 2H+ (aq)
In this equation, the charges are balanced, and the number of atoms of each element is the same on both sides.
Overall, the disproportionation of the Mn3+ ion in solution results in the formation of Mn2+, MnO2, and H+ ions. This reaction occurs due to the unstable nature of the Mn3+ ion, which undergoes simultaneous oxidation and reduction processes to achieve more stable oxidation states.
To make sure you are not studying endlessly, EduRev has designed Class 11 study material, with Structured Courses, Videos, & Test Series. Plus get personalized analysis, doubt solving and improvement plans to achieve a great score in Class 11.