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__Carbocation__

**Properties of Carbocation :**

**1. **It is positively charged species.

**2. **It has sixtet of electrons i.e. diamagnetic.

**3. **It is formed by heterolysis.

**4. **It is generally formed due to polar solvent.

**Structure :**

(sp^{2}), Triangular planar

**Stability :**

Its stability can be determined with the help of Inductive effect, Hyperconjugation and Resonance effect.

**Stability of Carbocation:**

Stability of carbocation can also be determined by Hyperconjugation (no bond Resonance).

9 α C - H bond 6αC - H bond 3α C - H bond

__Allylic Carbocation:__

__Benzylic Carbocation:__

**Ex**.**8** Compare the stability of the following carbocation:

(a) (b) (c)

→ more s character

→ more electronegativity

→ +ve charge on more electronegative element is symbol of unstability.

**a > b > c**

**Ex.9 **Compare the stability of the following compounds:

(a) (b) (c) (d)

**Sol. **d > c > b > a

Being most electron attracting group it decreases the e^{-} density from positively charged C-atom and decreases the charge density and makes the carbocation less stable.

**Ex.10 **Compare the stability of the following carbocation :

(a) (b) (c) (d)

**Sol. **Due to greater size of Iodine, its L.P. will not be available for coordinate bond. Therefore L.P. would not stabilize carbocation.

In case of F due to its small size its lone pair can be easily coordinated to making it most stable.

a > b > c > d (Stability)

* By coordination the carbocation completes its octet and structure having complete octet of its atom is supposed to be most stable.

(Each atom has its full octet)

*

**Note : **In Resonating Structure of at least one C gets sixtet of e^{-}s and hence less stable than coordinated compound.

**Ex.11 **Compare the stabilities of the following carbocation:

(a) (b) (c)

**Sol. **N, O, F belongs to same period

→ In period Electronegativity of the atom is deciding factor

→ F being most electronegative, holds its e^{-} pair very firmly.

→ Its L.P. will not be easily available for coordination.

→ Stability by it will be minimum.

a > b > c

**Ex.12 Compare the following carbocation in order of their stability.**

**(a) (b) **

**Sol.** If periods of atoms which have to donate their electrons for coordination (for stability) is different then atomic size will be deciding factor. The atom whose size is greater will be unable to make its e^{-} pair available for coordination.

b > a.

**Ex**.**13** Compare the stability of the following compounds:

(a) (b) (c)

**Sol** → more s-character

→ more e.n.

→ attracts e^{-}

→ reduces stability

b > a > c

__Carbanion__

**1. **It is a -ve charged species **2. **It has octet of electrons. **3. **diamagnetic

**Structure :**

*** **If -ve charge is in Resonance then the hybridisation of carbanion is sp^{2}(Triangular planar shape).

* If -ve charge is not in Resonance then the hybridisation of carbanion is sp^{3}(pyramidal).

**Stability :**

Its stability can be determined with the help of

(1) Inductive effect

(2) Resonance effect

**Ex.14 **

a > b (stability)

* Stability of the carbanion is as follows

**Ex.15 **Compare the stability of the following carbocation:

(a) (b) (c)

**Sol. c > a > b**

**Ex.16 **Compare the stability of the following carbanion:

(a)

(b)

(c)

→ become more stable

**Sol. b > a > c**

**Ex.17 **Compare the stability of the following carbanion:

(a) (b) (c)

**Sol. **a > b > c

**Ex.18 **Arrange the following anion in order of their stability:

(a) Cl^{-}, (b) Br^{-} (c) F^{-}_{ }(d) I^{- }(maximum size)

→ maximum dispersion of -ve charge

→ max stability

**Sol. **d > b > a > c

**Ex.19 **Compare the stability of the following:

**Ex.20 **Compare the acidic strength:

(a) HCl (b) HF (C) HBr (D) HI

**Sol. **Acidic strength ≈ stability of the anion formed (conjugate base)

As we know, I^{- }> Br^{-} > Cl^{-} > F^{-}

→ HI > HBr > HCl > HF

**Ex.21 **Compare the Acidic strength of the following:

(a) NH_{3} (b) pH_{3} (c) AsH_{3} (d) SbH_{3} (e) BiH_{3}

**Sol. **Anion formed from these acids are:

→ acidic strength e > d > c > b > a

**Ex.22 **Compare the acidic strength of the following compounds:

CH_{4}, NH_{3}, H_{2}O, HF

**Sol. **The conjugate base of the given acid is as follows:

we have already proved that

> > > (Stability)

→ HF > H_{2}O > NH_{3} > CH_{4} (acidic strength)

**Ex.24 **Compare the stability of the following carbanion.

(a) ** **

(b)

(c)

(d)

**Sol. **d > c > b > a

* M or -M is not distance dependent

**Ex.25 compare the stability of the following carbocation**

**(a) (b) (c) (d) **

**Sol. a > b > c > d**

**Ex.26 **Compare the stability of the following carbocation.

(a)

(b)

(c)

(d)

**Sol. ** M (OH) > M (OCH_{3})

b > c > d > a

**Ex.27 **Compare the stability of the following carbocation

(a)

(b)

(c)

**Sol. **c > a > b

**Ex.28 **Compare order of dehydration of the following alcohols :

(a)

(b)

(c) C - C - C - OH

**Sol. **After formation of carbocation

,

Since 3° carbocation is most stable therefore it will show greatest tendency to lose water as after loss of water it comes in stable form.

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