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Liquids

Electrolytes and Non-electrolytes

  • Electrolytes are substances that can conduct electricity in their aqueous or molten state.
  • They dissociate into ions when dissolved or melted, allowing the flow of electric current.
  • Examples of electrolytes include acids, bases, and salts.
  • Non-electrolytes, on the other hand, do not dissociate into ions and cannot conduct electricity.
  • Examples of non-electrolytes include sugar, alcohol, and pure water.

Concept of Electrolysis

  • Electrolysis is the process of using electric current to bring about a chemical reaction.
  • It occurs in an electrolytic cell consisting of two electrodes (anode and cathode) and an electrolyte solution.
  • When a direct current is passed through the electrolyte, positive ions move towards the cathode, and negative ions move towards the anode.
  • At the electrodes, reduction (gain of electrons) occurs at the cathode, and oxidation (loss of electrons) occurs at the anode.

Faraday's Laws of Electrolysis

  • Faraday's First Law states that the amount of a substance produced or consumed during electrolysis is directly proportional to the quantity of electric charge passed through the electrolyte.
  • Faraday's Second Law states that the amounts of different substances produced by the same quantity of electric charge are in the ratio of their respective chemical equivalent weights.

Application of Electrolysis

  • Electroplating: It is the process of depositing a layer of metal onto a conductive surface using electrolysis. It is used to improve the appearance, protect against corrosion, and modify the properties of objects.
  • Calibration of ammeter: Electrolysis can be used to calibrate an ammeter by passing a known current through a solution and measuring the amount of substance produced.

Gases

Discharge through Gases

  • Discharge through gases refers to the flow of electric current through a gas.
  • Gases can conduct electricity under specific conditions, such as low pressure or when ionized.
  • When a high voltage is applied across a gaseous medium, it can undergo electrical breakdown and become ionized, allowing current to flow.
  • This leads to the formation of a plasma, which consists of positive ions, negative ions, and free electrons.

Application of Conduction of Electricity through Gases

  • Neon signs and fluorescent lamps: These lighting devices utilize the conduction of electricity through gases to produce light.
  • Gas discharge tubes: They are used in physics experiments to study the behavior of charged particles in electric and magnetic fields.
  • Lightning: The phenomenon of lightning is a natural example of electricity conducted through gases (air) due to a potential difference between the cloud and the ground.
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