Page 1
UNIT I: CHEMISTRY OF LIFE
A. Elements
? All life forms made up of matter
? All matter made up of elements
¦ Elements
? Substances that cannot be broken down into smaller substances by
chemical means
B. Essential Elements of Life
? 96% of the mass of all living things made up of 4 elements:
? Oxygen (O)
? Carbon (C)
? Hydrogen (H)
? Nitrogen (N)
? Other elements (collectively 4% of biomass)
? Calcium (Ca)
? Phosphorus (P)
? Potassium (K)
? Sulfur (S)
? Sodium (Na)
? Chlorine (Cl)
? Magnesium (Mg)
? Trace elements
? IRon (Fe)
? Iodine (I)
? Copper (Cu)
C. Subatomic Particles
? Atom
? Smallest unit of an element
? Building blocks of physical world
? Subatomic PArticles
? Protons
¦ Packed with neutrons in nucleus
¦ Positively charged
¦ Most atoms have same amount of protons as electrons, making them electrically
neutral
? Neutrons
¦ Packed with protons in nucleus
¦ No charge
¦ Isotopes
? Same element with different amount of neutrons in nucleus
? Vary in mass
Page 2
UNIT I: CHEMISTRY OF LIFE
A. Elements
? All life forms made up of matter
? All matter made up of elements
¦ Elements
? Substances that cannot be broken down into smaller substances by
chemical means
B. Essential Elements of Life
? 96% of the mass of all living things made up of 4 elements:
? Oxygen (O)
? Carbon (C)
? Hydrogen (H)
? Nitrogen (N)
? Other elements (collectively 4% of biomass)
? Calcium (Ca)
? Phosphorus (P)
? Potassium (K)
? Sulfur (S)
? Sodium (Na)
? Chlorine (Cl)
? Magnesium (Mg)
? Trace elements
? IRon (Fe)
? Iodine (I)
? Copper (Cu)
C. Subatomic Particles
? Atom
? Smallest unit of an element
? Building blocks of physical world
? Subatomic PArticles
? Protons
¦ Packed with neutrons in nucleus
¦ Positively charged
¦ Most atoms have same amount of protons as electrons, making them electrically
neutral
? Neutrons
¦ Packed with protons in nucleus
¦ No charge
¦ Isotopes
? Same element with different amount of neutrons in nucleus
? Vary in mass
? Radioactive isotopes decay spontaneously, giving off particles and
energy
? Electrons
¦ Negatively charged
¦ Spin around nucleus
¦ Very small; effectively massless
¦ Electrons on an atom differ in their amounts of potential energy
¦ Electron’s state of potential energy is called its energy level, or electron shell
¦ Valence electrons are those in the outermost shell, or valence shell
¦ Chemical behavior of an atom is mostly determined by the distribution of
electrons in electron shells
? Valence shell most important
? Elements with full valence shells are chemically inert
? Atoms with incomplete valence shells can share or transfer valence
electrons with certain other atoms
? Atoms of different various elements differ in number of subatomic particles
? Atomic number=#protons in nucleus
? Mass Number= protons+neutrons
¦ Average of all isotopes
? Atomic mass+atom’s weighted average total mass
D. Compounds
? Compound occurs as result of 2 or more individual elements combining in a fixed ratio
? Different properties of individual elements
? Formed by chemical reaction
? Bonds that hold compounds together
? Ionic bonds
¦ nonmetal+metal
¦ One or more electrons is transferred from one atom to another
¦ One atom loses electrons (becomes positively charged) while the other gains
electrons (becomes negatively charged)
¦ Results from attraction of two oppositely charged ions
Page 3
UNIT I: CHEMISTRY OF LIFE
A. Elements
? All life forms made up of matter
? All matter made up of elements
¦ Elements
? Substances that cannot be broken down into smaller substances by
chemical means
B. Essential Elements of Life
? 96% of the mass of all living things made up of 4 elements:
? Oxygen (O)
? Carbon (C)
? Hydrogen (H)
? Nitrogen (N)
? Other elements (collectively 4% of biomass)
? Calcium (Ca)
? Phosphorus (P)
? Potassium (K)
? Sulfur (S)
? Sodium (Na)
? Chlorine (Cl)
? Magnesium (Mg)
? Trace elements
? IRon (Fe)
? Iodine (I)
? Copper (Cu)
C. Subatomic Particles
? Atom
? Smallest unit of an element
? Building blocks of physical world
? Subatomic PArticles
? Protons
¦ Packed with neutrons in nucleus
¦ Positively charged
¦ Most atoms have same amount of protons as electrons, making them electrically
neutral
? Neutrons
¦ Packed with protons in nucleus
¦ No charge
¦ Isotopes
? Same element with different amount of neutrons in nucleus
? Vary in mass
? Radioactive isotopes decay spontaneously, giving off particles and
energy
? Electrons
¦ Negatively charged
¦ Spin around nucleus
¦ Very small; effectively massless
¦ Electrons on an atom differ in their amounts of potential energy
¦ Electron’s state of potential energy is called its energy level, or electron shell
¦ Valence electrons are those in the outermost shell, or valence shell
¦ Chemical behavior of an atom is mostly determined by the distribution of
electrons in electron shells
? Valence shell most important
? Elements with full valence shells are chemically inert
? Atoms with incomplete valence shells can share or transfer valence
electrons with certain other atoms
? Atoms of different various elements differ in number of subatomic particles
? Atomic number=#protons in nucleus
? Mass Number= protons+neutrons
¦ Average of all isotopes
? Atomic mass+atom’s weighted average total mass
D. Compounds
? Compound occurs as result of 2 or more individual elements combining in a fixed ratio
? Different properties of individual elements
? Formed by chemical reaction
? Bonds that hold compounds together
? Ionic bonds
¦ nonmetal+metal
¦ One or more electrons is transferred from one atom to another
¦ One atom loses electrons (becomes positively charged) while the other gains
electrons (becomes negatively charged)
¦ Results from attraction of two oppositely charged ions
¦ Cation has a positive charge
¦ Anion has a negative charge
¦ Cation and anion form to create ionic bond
? Covalent bonds
¦ nonmetal+nonmetal
¦ Molecule consists of 2 or more atoms held together by covalent bonds
¦ Formed when electrons are shared between atoms
¦ In nonpolar covalent bond, electrons are shared equally
¦ In polar covalent bond, electrons are shared unequally
¦ In a single covalent bond, one pair of electrons is shared
? Double covalent when 2 pairs are shared, etc.
¦ Structural formula used to represent atoms and bonding
? Ex. H-H
¦ Molecular formula abbreviates structural formula
? Ex. H
2
? Electronegativity is an atom’s attraction for the atoms in a covalent
bond
? The more electronegative an atom, the more strongly it pulls
shared electrons toward itself
? Hydrogen bonds
¦ Hydrogen atom covalently bonds to one electronegative ato is also attracted to
another electronegative atom
¦ In living cells, hydrogen bonds are usually oxygen or other nitrogen atoms
? Van der Waals Interactions
¦ Weakest
¦ If electrons are distributed asymmetrically in molecules or atoms, they can result
in “hot spots” of positive or negative charge
¦ Attractions between molecules that are close together as a result of these charges
? How geckos climb
E. Water: The Versatile Molecule
? In water, electrons are not shared equally in the bonds between hydrogen and oxygen
? Hydrogen atoms have a partial positive charge while oxygen atoms has a partial negative
charge
¦ Water is polar
Page 4
UNIT I: CHEMISTRY OF LIFE
A. Elements
? All life forms made up of matter
? All matter made up of elements
¦ Elements
? Substances that cannot be broken down into smaller substances by
chemical means
B. Essential Elements of Life
? 96% of the mass of all living things made up of 4 elements:
? Oxygen (O)
? Carbon (C)
? Hydrogen (H)
? Nitrogen (N)
? Other elements (collectively 4% of biomass)
? Calcium (Ca)
? Phosphorus (P)
? Potassium (K)
? Sulfur (S)
? Sodium (Na)
? Chlorine (Cl)
? Magnesium (Mg)
? Trace elements
? IRon (Fe)
? Iodine (I)
? Copper (Cu)
C. Subatomic Particles
? Atom
? Smallest unit of an element
? Building blocks of physical world
? Subatomic PArticles
? Protons
¦ Packed with neutrons in nucleus
¦ Positively charged
¦ Most atoms have same amount of protons as electrons, making them electrically
neutral
? Neutrons
¦ Packed with protons in nucleus
¦ No charge
¦ Isotopes
? Same element with different amount of neutrons in nucleus
? Vary in mass
? Radioactive isotopes decay spontaneously, giving off particles and
energy
? Electrons
¦ Negatively charged
¦ Spin around nucleus
¦ Very small; effectively massless
¦ Electrons on an atom differ in their amounts of potential energy
¦ Electron’s state of potential energy is called its energy level, or electron shell
¦ Valence electrons are those in the outermost shell, or valence shell
¦ Chemical behavior of an atom is mostly determined by the distribution of
electrons in electron shells
? Valence shell most important
? Elements with full valence shells are chemically inert
? Atoms with incomplete valence shells can share or transfer valence
electrons with certain other atoms
? Atoms of different various elements differ in number of subatomic particles
? Atomic number=#protons in nucleus
? Mass Number= protons+neutrons
¦ Average of all isotopes
? Atomic mass+atom’s weighted average total mass
D. Compounds
? Compound occurs as result of 2 or more individual elements combining in a fixed ratio
? Different properties of individual elements
? Formed by chemical reaction
? Bonds that hold compounds together
? Ionic bonds
¦ nonmetal+metal
¦ One or more electrons is transferred from one atom to another
¦ One atom loses electrons (becomes positively charged) while the other gains
electrons (becomes negatively charged)
¦ Results from attraction of two oppositely charged ions
¦ Cation has a positive charge
¦ Anion has a negative charge
¦ Cation and anion form to create ionic bond
? Covalent bonds
¦ nonmetal+nonmetal
¦ Molecule consists of 2 or more atoms held together by covalent bonds
¦ Formed when electrons are shared between atoms
¦ In nonpolar covalent bond, electrons are shared equally
¦ In polar covalent bond, electrons are shared unequally
¦ In a single covalent bond, one pair of electrons is shared
? Double covalent when 2 pairs are shared, etc.
¦ Structural formula used to represent atoms and bonding
? Ex. H-H
¦ Molecular formula abbreviates structural formula
? Ex. H
2
? Electronegativity is an atom’s attraction for the atoms in a covalent
bond
? The more electronegative an atom, the more strongly it pulls
shared electrons toward itself
? Hydrogen bonds
¦ Hydrogen atom covalently bonds to one electronegative ato is also attracted to
another electronegative atom
¦ In living cells, hydrogen bonds are usually oxygen or other nitrogen atoms
? Van der Waals Interactions
¦ Weakest
¦ If electrons are distributed asymmetrically in molecules or atoms, they can result
in “hot spots” of positive or negative charge
¦ Attractions between molecules that are close together as a result of these charges
? How geckos climb
E. Water: The Versatile Molecule
? In water, electrons are not shared equally in the bonds between hydrogen and oxygen
? Hydrogen atoms have a partial positive charge while oxygen atoms has a partial negative
charge
¦ Water is polar
? Hydrogen bonds
? Weak attractions that result of water’s polarity
¦ Positive end of another polar molecule attracted to oxygen negative charge, and
vice versa with the hydrogen end
¦ Hydrogen atom covalently bonded to one electronegative atom is also attracted to
another electronegative atom
¦ Weak Individually, but strong on a larger scale
? Lends watermany special properties
¦ Cohesion
? Tendency for water to stick to water
? Important during transpiration
? Water evaporates, pulls other water molecules with it, pulling all
the way down from leaves to roots
¦ Adhesion
? Tendency of water to stick to other substances
? Cohesion + Adhesion = capillary action
? Allows water to flow up roots/trunks/branches of trees in thin
vessels
¦ Surface tension
? Results from cohesion of water molecules
? Ex. water striders can sit on top of water without sinking
¦ High heat capacity
? Heat CApacity=ability of a substance to resist temperature changes
? Keeps ocean temperatures stable
? Allows organisms to keep constant body temperature, since most life
forms are mostly made up of water
? Heat is absorbed when hydrogen bonds break, released when hydrogen
bonds form
¦ High heat of vaporization
? Heat a liquid must absorb for 1g to be converted to gas
Page 5
UNIT I: CHEMISTRY OF LIFE
A. Elements
? All life forms made up of matter
? All matter made up of elements
¦ Elements
? Substances that cannot be broken down into smaller substances by
chemical means
B. Essential Elements of Life
? 96% of the mass of all living things made up of 4 elements:
? Oxygen (O)
? Carbon (C)
? Hydrogen (H)
? Nitrogen (N)
? Other elements (collectively 4% of biomass)
? Calcium (Ca)
? Phosphorus (P)
? Potassium (K)
? Sulfur (S)
? Sodium (Na)
? Chlorine (Cl)
? Magnesium (Mg)
? Trace elements
? IRon (Fe)
? Iodine (I)
? Copper (Cu)
C. Subatomic Particles
? Atom
? Smallest unit of an element
? Building blocks of physical world
? Subatomic PArticles
? Protons
¦ Packed with neutrons in nucleus
¦ Positively charged
¦ Most atoms have same amount of protons as electrons, making them electrically
neutral
? Neutrons
¦ Packed with protons in nucleus
¦ No charge
¦ Isotopes
? Same element with different amount of neutrons in nucleus
? Vary in mass
? Radioactive isotopes decay spontaneously, giving off particles and
energy
? Electrons
¦ Negatively charged
¦ Spin around nucleus
¦ Very small; effectively massless
¦ Electrons on an atom differ in their amounts of potential energy
¦ Electron’s state of potential energy is called its energy level, or electron shell
¦ Valence electrons are those in the outermost shell, or valence shell
¦ Chemical behavior of an atom is mostly determined by the distribution of
electrons in electron shells
? Valence shell most important
? Elements with full valence shells are chemically inert
? Atoms with incomplete valence shells can share or transfer valence
electrons with certain other atoms
? Atoms of different various elements differ in number of subatomic particles
? Atomic number=#protons in nucleus
? Mass Number= protons+neutrons
¦ Average of all isotopes
? Atomic mass+atom’s weighted average total mass
D. Compounds
? Compound occurs as result of 2 or more individual elements combining in a fixed ratio
? Different properties of individual elements
? Formed by chemical reaction
? Bonds that hold compounds together
? Ionic bonds
¦ nonmetal+metal
¦ One or more electrons is transferred from one atom to another
¦ One atom loses electrons (becomes positively charged) while the other gains
electrons (becomes negatively charged)
¦ Results from attraction of two oppositely charged ions
¦ Cation has a positive charge
¦ Anion has a negative charge
¦ Cation and anion form to create ionic bond
? Covalent bonds
¦ nonmetal+nonmetal
¦ Molecule consists of 2 or more atoms held together by covalent bonds
¦ Formed when electrons are shared between atoms
¦ In nonpolar covalent bond, electrons are shared equally
¦ In polar covalent bond, electrons are shared unequally
¦ In a single covalent bond, one pair of electrons is shared
? Double covalent when 2 pairs are shared, etc.
¦ Structural formula used to represent atoms and bonding
? Ex. H-H
¦ Molecular formula abbreviates structural formula
? Ex. H
2
? Electronegativity is an atom’s attraction for the atoms in a covalent
bond
? The more electronegative an atom, the more strongly it pulls
shared electrons toward itself
? Hydrogen bonds
¦ Hydrogen atom covalently bonds to one electronegative ato is also attracted to
another electronegative atom
¦ In living cells, hydrogen bonds are usually oxygen or other nitrogen atoms
? Van der Waals Interactions
¦ Weakest
¦ If electrons are distributed asymmetrically in molecules or atoms, they can result
in “hot spots” of positive or negative charge
¦ Attractions between molecules that are close together as a result of these charges
? How geckos climb
E. Water: The Versatile Molecule
? In water, electrons are not shared equally in the bonds between hydrogen and oxygen
? Hydrogen atoms have a partial positive charge while oxygen atoms has a partial negative
charge
¦ Water is polar
? Hydrogen bonds
? Weak attractions that result of water’s polarity
¦ Positive end of another polar molecule attracted to oxygen negative charge, and
vice versa with the hydrogen end
¦ Hydrogen atom covalently bonded to one electronegative atom is also attracted to
another electronegative atom
¦ Weak Individually, but strong on a larger scale
? Lends watermany special properties
¦ Cohesion
? Tendency for water to stick to water
? Important during transpiration
? Water evaporates, pulls other water molecules with it, pulling all
the way down from leaves to roots
¦ Adhesion
? Tendency of water to stick to other substances
? Cohesion + Adhesion = capillary action
? Allows water to flow up roots/trunks/branches of trees in thin
vessels
¦ Surface tension
? Results from cohesion of water molecules
? Ex. water striders can sit on top of water without sinking
¦ High heat capacity
? Heat CApacity=ability of a substance to resist temperature changes
? Keeps ocean temperatures stable
? Allows organisms to keep constant body temperature, since most life
forms are mostly made up of water
? Heat is absorbed when hydrogen bonds break, released when hydrogen
bonds form
¦ High heat of vaporization
? Heat a liquid must absorb for 1g to be converted to gas
? Evaporative cooling
? As a liquid evaporates, its remaining surface cools
¦ How sweat works to cool body down
¦ Expansion on freezing
? Lattice structure of ice causes water to expand on freezing
? Allows ice to float on top of lakes in winter
? Animal life can live beneath ice
¦ Versatility as a solvent
? Solution is a liquid that is a homogenous mix of substances
? Solvent is the dissolving agent of a solution
? Solute is the substance that is dissolved
? Aqueous solution is one where water is the solvent
? Polarity of water allows it to be a versatile solvent
? Can form hydrogen bonds easily
? Hydrophobic substances do not dissolve in water, but hydrophilic ones
will
F. Acids and Bases
? Solution is acidic if it contains a lot of H
+
? Solution is alkaline if it contains a lot of OH
-
? Measured on pH scale
? Logarithmic
? Numbered 1-14
¦ Acids 1-7 pH
¦ Bases 7-14 pH
? Buffers maintain stable pH
G. Organic Molecules
? Organic compound contains Carbon
? Inorganic compound does not contain carbon
? Carbon often surrounded by hydrogen
? Carbon is a versatile atom
? Can bind with many elements
? Many “slots” to bind with elements
¦ 4 valence electrons
? Can form 4 covalent bonds
¦ Makes large, complex molecules possible
? In molecules with multiple carbons, each carbon bonded to 4 other atoms has a
tetrahedral shape
¦ When 2 carbons are formed by a double bond, the atoms joined to the carbons are
one the same plane as the carbons
? Electron configuration gives it covalent compatibility with other elements
? Hydrocarbons consist of only carbon and hydrogen
¦ Can undergo reactions that release a large amount of energy
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