Friedel Crafts Alkylation and Acylation Class 11 Notes | EduRev

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Friedel Crafts alkylation reaction

When benzene is treated with an alkyl halide in the presence of a Lewis acid such as anhydrous aluminium chloride, alkyl benzene is formed. This reaction is popularly known as Friedel Crafts alkylation reaction.

Friedel Crafts Alkylation and Acylation Class 11 Notes | EduRev
Friedel Crafts acylation reaction:

When benzene is treated with an acyl halide in the presence of Lewis acids such as anhydrous aluminium chloride, acyl benzene is formed. This reaction is popularly known as Friedel Crafts acylation reaction.

Friedel Crafts Alkylation and Acylation Class 11 Notes | EduRev
The mechanism for Friedel Crafts alkylation and acylation reactions of benzene:

Friedel Crafts alkylation and acylation reactions involve a three-step mechanism:

  1. Generation of electrophile:

    Due to the presence of a Lewis acid, generation of electrophile takes place. As Lewis acid accepts the electron pair from the attacking reagent.

  2. Formation of arenium ion:

    The electrophiles generated attacks on the benzene ring to form positively charged cyclohexadienyl cation better called arenium ion containing one sp3 hybridized carbon atom. The positive charge is effectively distributed over three carbon atoms due to resonance which makes it partially stable.

    As delocalization of electrons stops at sp3 hybridized carbon atom, the arenium ion is not aromatic in nature.

  3. Removal of positive charge from the carbo-cation intermediate:

    The arenium ion finally loses its proton from sphybridized carbon to a Lewis base restoring the aromaticity.

A general mechanism for Friedel Craft’s acylation is depicted below:

Friedel Crafts Alkylation and Acylation Class 11 Notes | EduRev

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