Q.1. 10 moles of are treated with 8 moles of CH3MgBr followed by hydrolysis. How many moles of diol will be obtained?
Ans. 0
Because of acidic hydrogen of -CH2- group 8 moles of CH4 will be obtained.
Q.2.
Identify number of reagent that can be used for above conversion.
(a) Zn — Hg / HCl
(b) LiAlH4
(c) CHCl3 / KOH
(d)
(e)
(f) SeO2
Ans. 3
Clemmensen reduction (Zn - Hg / HCl) , Wolff Kishner reduction and Raney Nickel Desulphurization (Ni / H2 with reduces the carbonyl group to -CH2- on reaction with
Q.3. Consider the following reaction
How many times Michael addition reaction can take place.
Ans. 2
Q.4. In the following structure, H at C-x is involved in crossed aldol reaction.
Ans. 2
C-2 is involved in cross aldol reaction. It's the case of intramolecular aldol condensation reaction.
Q.5. CH3CHO + CH3COCH3 products
Total number of possible aldol products are:
Ans. 4
Q.6. Number of carbon atom in compound D is
Ans. 3
Q.7. How many carbon–carbon double bonds are present in the end product ‘Z’
Ans. 1
Q.8. What would be the value of ∧CH3 COOH in Scm2 eq–1 in a solution of pH = 2, if ∧∞ for CH3COOH is 400 Scm2 eq-1.
Ans. 4
Q.9. Number of organic compounds out of the following which can show positive iodoform test is acetaldehyde, Methanal, Butanone, Acetone, Glyoxal, pentan-2one.
Ans. 4
Compound containing undergo iodoform
Q.10. Consider the following sequence of reaction:
What is the sum of stereoisomer of (X) and (Y).
Ans. 4
(X) → Two enantiomers
(Y) → Two geometric isomers.
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