Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

I. E. Irodov Solutions for Physics Class 11 & Class 12

JEE : Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

The document Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev is a part of the JEE Course I. E. Irodov Solutions for Physics Class 11 & Class 12.
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Q.201. Calculate the interval (in eV units) between neighbouring levels of free electrons in a metal at T = 0 near the Fermi level, if the concentration of free electrons is n = 2.0.1022  cm-3  and the volume of the metal is V = 1.0 cm3

Ans. We write the expression for the number of electrons as

Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

Hence if A £ is the spacing between neighbouring levels near the Fermi level we must have

Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

(2 on the RHS is to take care of both spins / electrons). Thus

Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

But Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

SoIrodov Solutions: Molecules and Crystals- 3 Notes | EduRev

Substituting the data we get

Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

 

Q.202. Making use of Eq. (6.4g), find at T = 0:
 (a) the velocity distribution of free electrons;
 (b) the ratio of the mean velocity of free electrons to their maximum velocity. 

Ans. (a) From

Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

we get on using Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

Irodov Solutions: Molecules and Crystals- 3 Notes | EduRevIrodov Solutions: Molecules and Crystals- 3 Notes | EduRev

This holds for 0 < v < vF where Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

and        Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

(b) Mean velocity is

Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

 

Q.203. On the basis of Eq. (6.4g) find the number of free electrons in a metal at T = 0 as a function of de Broglie wavelengths

Ans. Using the formula of the previous section

Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

We put  Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev where λ = de Broglie wavelength

Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

Taking account of the fact that λ decreases when v increases we write 

Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

 

Q.204. Calculate the electronic gas pressure in metallic sodium, at T = 0, in which the concentration of free electrons is n = = 2.5.1022 cm-3. Use the equation for the pressure of ideal gas.

Ans. From the kinetic theory of gasses we know

Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

Here U is the total interval energy of the gas. This result is applicable to Fermi gas also Now at T = 0

Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

so  Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

Substituting the values we get

p = 4.92 x 104 atmos

 

Q.205. The increase in temperature of a cathode in electronic tube by ΔT = 1.0 K from the value T= 2000 K results in the increase of saturation current by η =  1.4%. Find the work function of electron for the material of the cathode. 

Ans. From Richardson's equation 

Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

where A is the work function in eV. When T increases by ΔT , I increases to (1 + η)I. Then

Irodov Solutions: Molecules and Crystals- 3 Notes | EduRevIrodov Solutions: Molecules and Crystals- 3 Notes | EduRev

Expanding and neglecting higher powers of Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev we get

Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

Thus Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

Substituting we get            A = 4.48 eV

 

Q.206. Find the refractive index of metallic sodium for electrons with kinetic energy T = 135 eV. Only one free electron is assumed to correspond to each sodium atom. 

Ans. 

Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev   Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

The potential energy inside the metal is - U0 for the electron and it related to the work function A by

U0 = Ep + A

If T is the K.E. of electrons outside the metal, its K.E. inside the metal will be (E + U0) . On entering the metal electron connot experience any tangential force so the tangential component of momentum is unchanged. Then

Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

Hence

Irodov Solutions: Molecules and Crystals- 3 Notes | EduRevn by the definition of refractive index

In sodium with one free electron per Na atom

n = 2.54 x 1022 per c.c.

EF = 3.15 eV

A = 2.27 eV (from table)

U0 = 5.42 eV

n = 102

 

Q.207. Find the minimum energy of electron-hole pair formation in an impurity-free semiconductor whose electric conductance increases η = 5.0 times when the temperature increases from T1  = = 300 K to T2 = 400 K. 

Ans. In a pure (intrinsic) semiconductor the conductivity is related to the temperature by the following formula very closely :

Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

where Δε is the eneigy gap between the top of valence band and the bottom of conduction band; it is also the minimum energy required for the formation of electron-hole pair. The conductivity increases with temperature and we have

Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

or Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

Hence  Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

Substitution gives

Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

 

Q.208. At very low temperatures the photoelectric threshold short wavelength in an impurity-free germanium is equal to λih = 1.7μm. Find the temperature coefficient of resistance of this germanium sample at room temperature.

Ans. The photoelectric threshold determines the band gap Δε by

Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

On the other hand the temperature coefficient of resistance is defined by (p is resistivity)

Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

where σ is the conductivity. But

Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

Then Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

 

Q.209. Fig. 6.11 illustrates logarithmic electric conductance as a function of reciprocal temperature (7' in kK units) for some 

Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

n-type semiconductor. Using this plot, find the width of the forbidden band of the semiconductor and the activation energy of donor levels.

Ans. At high temperatures (small values of T-1) most of the conductivity is intrinsic i.e. it is due to the transition of electrons from the upper levels of the valance band into the lower levels of conduction vands.
For this we can apply approximately the formula

Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

or  Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

From this we get the band gap

Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

The slope must be calculated at small Irodov Solutions: Molecules and Crystals- 3 Notes | EduRevEvaluation gives Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev= 7000 K

Hence              Eg = 1.21 eV

At low temperatures (high values of  Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev) the conductance is mostly due to impurities. If E0 is the ionization energy of donor levels then we can write the approximate formula (valid at low temperature)

Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

So Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

The slope must be calculated at low temperatures. Evaluation gives the slope

Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

Then  Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

 

Q.210. The resistivity of an impurity-free semiconductor at room temperature is ρ = 50 Ω•cm. It becomes equal to ρ= 40 Ω•cm when the semiconductor is illuminated with light, and t = 8 ms after switching off the light source the resistivity becomes equal to ρ2 = 45 Ω•cm. Find the mean lifetime of conduction electrons and holes. 

Ans. We write the conductivity of the sample as 

Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

where σi = intrinsic conductivity and σγ is the photo conductivity. At t = 0, assuming saturation we have

Irodov Solutions: Molecules and Crystals- 3 Notes | EduRevIrodov Solutions: Molecules and Crystals- 3 Notes | EduRev

Time t after light source is switched off

we have because of recombination of electron and holes in the sample

Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

where T = mean lifetime of electrons and holes.

Thus Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

or Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

or  Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

Hence  Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

Substitution gives Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

 

Q.211. In Hall effect measurements a plate of width h = 10 mm and length l = 50 mm made of p-type semiconductor was placed in a magnetic field with induction B = 5.0 kG. A potential difference V = 10 V was applied across the edges of the plate. In this case the Hall field is V= 50 mV and resistivity ρ = 2.5 Ω•cm. Find the concentration of holes and hole mobility. 

Ans. 

Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

We shall ignore minority carriers.
Drifting holes experience a sideways force in the magnetic field and react by setting up a Hall electric field Eγ to counterbalance it Thus

Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

If the concentration of carriers is n then

Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

Hence  Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

Also using Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

we get  Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

Substituting the data (note that in MKS units B = 5.0 k G = 0.5 T)

ρ = 2.5 x 10-2 ohm-m

we get        n = 4.99 x 1021 m -3

= 4.99 x 1015 per cm3

Also the mobility is   Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

Substitution gives  U= 0.05 m2/ V - s

 

Q.212. In Hall effect measurements in a magnetic field with induction B = 5.0 kG the transverse electric field strength in an impurity-free germanium turned out to be η = 10 times less than the longitudinal electric field strength. Find the difference in the mobilities of conduction electrons and holes in the given semiconductor. 

Ans.

Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

If an electric Geld Ex is present in a sample containing equal amounts of both electrons and holes, the two drift in opposite directions.
In the presence of a magnetic field Bz = B they set up Hall voltages in opposite directions.

The net Hall electric field is given by

Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

But Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

Substitution gives Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

 

Q.213. The Hall effect turned out to be not observable in a semiconductor whose conduction electron mobility was η = 2.0 times that of the hole mobility. Find the ratio of hole and conduction electron concentrations in that semiconductor

Ans. 

Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

When the sample contains unequal number of carriers of both types whose mobilities are different, static equilibrium (i.e. no transverse movement of either electron or holes) is impossible in a magnetic Geld. The transverse electric Geld acts differently on electrons and holes. If the Ey that is set up is as shown, the net Lorentz force per unit charge (effective transverse electric Geld) on electrons is

Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

and on holes

Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

(we are assuming B = Bz). There is then a transverse drift of electrons and holes and the net transverse current must vanish in equilibrium. Using mobility

Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

or  Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

On the other hand

Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

Thus, the Hall coefficient is

Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev

We see that RH = 0 when

Irodov Solutions: Molecules and Crystals- 3 Notes | EduRev 

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