JEE Advanced Previous Year Questions (2018 - 2023): Chemical Kinetics | Chemistry for JEE Main & Advanced PDF Download

2022

Q1: Match the rate expressions in LIST-I for the decomposition of X with the corresponding profiles provided in LIST-II. X_s and k are constants having appropriate units.   [JEE Advanced 2022 Paper 1]

(a) I → P ; II → Q; III → S ; IV → T
(b) I → R ; II → S ; III → S ; IV → T
(c) I → P ; II → Q; III → Q; IV → R
(d) I → R ; II → S ; III → Q; IV → R
Ans: (a)

In this case curve-R given in List-II will match.
∴ I → P, Q, R, S, T (The graph of half-life should start from origin)

2021

Q1: For the following reaction,  the rate of reaction is  

Two moles of X are mixed with one mole of Y to make 1.0 L of solution. At 50 s, 0.5 mole of Y is left in the reaction mixture. The correct statement(s) about the reaction is(are)
(Use : ln 2 = 0.693)     [JEE Advanced 2021 Paper 2]
(a) A The rate constant, k, of the reaction is 13.86 × 10⁻⁴ s⁻¹ 
(b) Half-life of X is 50 s.
(c) At 50 s,  = 13.86 × 10⁻³ mol L⁻¹ s⁻¹.
(d) At 100 s,  = 3.46 × 10⁻³ mol L⁻¹ s⁻¹.
Ans: (b, c, d)

As the concentration of reactant becomes half at t = 50 s. So, half-time of reaction is 50 s.
Given,


So, options (b), (c) and (d) are correct.

2020

Q1:  is known to undergo radioactive decay to form  by emitting alpha and beta particles. A rock initially contained 68 x 10-6 g of  If the number of alpha particles that it would emit during its radioactive decay of  in three half-lives is Z × 10¹⁸, then what is the value of Z?   [JEE Advanced 2020 Paper 1]
Ans: 1.2

Number of moles of  present initially

After three half-lifes, moles of  decayed

Therefore, number of α-particles emitted


≈ 1.2 × 10¹⁸
Thus, the correct answer is 1.2.

Q2: Which of the following plots is(are) correct for the given reaction?
([P]₀ is the initial concentration of P)     [JEE Advanced 2020 Paper 2]

(a)

(b)

(c)

(d)

Ans: (a)

This is first order reaction and for first order reaction
So, half-life is independent of initial concentration.
Therefore, the plot (a) correct.
For first order reaction,

Hence, plot (b) and (d) are incorrect. For first order reaction,

Hence, plot (c) is incorrect.

2019

Q1: The decomposition reaction is started in a closed cylinder under isothermal isochoric condition at an initial pressure of 1 atm. After Y × 10³ s, the pressure inside the cylinder is found to be 1.45 atm. If the rate constant of the reaction is 5 × 10^-4s^-1, assuming ideal gas behaviour, the value of Y is ...............   [JEE Advanced 2019 Paper 2]
Ans: 2.3
At constant V, T
At initial t = 0 and final t = y × 10³ sec

p_Total = 1 − 2p + 2p + p

1.4 = 1 + p
p = 0.45 atm
According to first order reaction,

p_i = 1 atm (given)
2p = 2 × 0.45 = 0.9 atm
On substituting the values in above equation,

Note : Unit of rate constant (k), i.e. s⁻¹ represents that it is a first order reaction.

Q2: Consider the kinetic data given in the following table for the reaction A + B + C → Product.

The rate of the reaction for [A] = 0.15 mol dm^-3, [B] = 0.25 mol dm^-3 and [C] = 0.15 mol dm^-3 is found to be Y × 10^-5 mol dm^-3s^-1. The value of Y is _______    [JEE Advanced 2019 Paper 1]
Ans: 6.75

⇒ x = 1
So, rate = k[A]¹[C]¹ 
From exp-Ist,
Rate = 6.0 × 10⁻⁵ mol dm⁻³ s⁻¹ 
6.0 × 10⁻⁵ = k[0.2]¹[0.1]¹ 
k = 3 × 10⁻³ 
Given, [A] = 0.15 mol dm⁻³ 
[B] = 0.25 mol dm⁻³ 
[C] = 0.15 mol dm⁻³ 
∴ Rate = (3 × 10⁻³) × [0.15]¹[0.25]⁰[0.15]¹ 
= 3 × 10⁻³ × 0.15 × 0.15
Rate = 6.75 × 10⁻⁵ mol dm⁻³ s⁻¹ 
Thus, Y = 6.75

Q3: In the decay sequence.

x₁, x₂, x₃ and x₄ are particles/radiation emitted by the respective isotopes. The correct option(s) is(are)    [JEE Advanced 2019 Paper 1]
(a) Z is an isotope of uranium
(b) x₂ is β^-
(c) x₁ will deflect towards negatively charged plate
(d) x₃ is γ -ray
Ans: (a, b, c)
In decay sequence,

X₁ particle will deflect towards negatively charged plate due to presence of positive charge on α - particles.
Hence, options (a, b, c) are correct.

2018

Q1: Consider the following reversible reaction, A (g) + B (g) → AB (g).
The activation energy of the backward reaction exceeds that of the forward reaction by 2RT (in J mol ⁻¹). If the pre-exponential factor of the forward reaction is 4 times that of the reverse reaction, the absolute value of ΔG^∘ (in J mol⁻¹) for the reaction at 300 K is ____________.
(Given; ln ⁡ (2) = 0.7 , RT = 2500 J mol⁻¹ at 300 K and G is the Gibbs energy)     [JEE Advanced 2018 Paper 2]
Ans: 8500

At 300 K ,
For the reversible reaction,
A (g) + B (g) ⇌ AB (g)
(i) Pre-exponential factor for forward reaction (A_f) = 4 × pre-exponential factor for backward reverse reaction (A_b)
Af = 4 × A_b 
(ii) Activation energy for backward reaction (E_b)_f − Activation energy = 2 RT for forward reaction (E_a)_f- Ab − A_f  = 2 RT
(iii) Equilibrium constant

The expression for the change in Gibbs free energy of reaction (ΔG) is given as:
ΔG = ΔG^∘ + RT ln ⁡ k
At equilibrium, ΔG = 0
ΔG^∘ = − RT ln ⁡ Keq
Substituting the value of RT and ln ⁡ K_eq 
ΔG^∘ = − 2500 J mol⁻¹ × 3.4
ΔG^∘ = − 8500 J mol⁻¹ 
The absolute value of Gibbs free energy (ΔG^∘) for the reaction at 300 K is 8500 J mol⁻¹.

Q2: For a first order reaction A (g) → 2B(g) + C(g) at constant volume and 300 K , the total pressure at the beginning (t = 0) and at time t are P₀ and P₁ , respectively. Initially, only A is present with concentration [A]₀ , and t_1/3 is the time required for the partial pressure of A to reach 1/3^rd of its initial value. The correct option(s) is (are) (Assume that all these gases behave as ideal gases)    [JEE Advanced 2018 Paper 2]
(a)

(b)

(c)

(d)

Ans: (a, d)
Total pressure of gaseous mixture at beginning (T = 0) = P₀ 
Total pressure of gaseous mixture after time t (T = t) = P_t
Initial concentration of A = [A]₀ 
Temperature of the reaction mixture (T) = 300 K
For the first order reaction,

Total pressure after time (T = t) = P₀ − P + 2P + P

According to integrated rate law for the first order reaction:


Comparing equation (ii) with equation of straight option line

y = c + mx

Plot of ln ⁡ (3 P₀ − P) verses time (t) is represented as:
Option (A) is correct.
(ii) For the first order reaction,


Substituting the value of P_t in eq (i)

 is independent of concentration of (A).
Option (B) is not correct.
(iii) At any time t , rate constant (k) is independent of concentration of [A].
For example:

Hence, Option (D) is correct.