Laws of Thermodynamics and Enthalpy Class 11 Notes | EduRev

Chemistry for JEE

Class 11 : Laws of Thermodynamics and Enthalpy Class 11 Notes | EduRev

The document Laws of Thermodynamics and Enthalpy Class 11 Notes | EduRev is a part of the Class 11 Course Chemistry for JEE.
All you need of Class 11 at this link: Class 11

LAWS OF THERMODYNAMICS
Zeroth Law
Based on thermal equilibrium if A & B, & B & C are in thermal equilibrium then A & C must be in thermal equilibrium.

First Law of Thermodynamics
First law of thermodynamics is based on energy conservation

E= E1 + q + w (E1 is the Ei)
E- E= q + w (E1 q w is Ef)
(Ei = Ef)

ΔE = Q+w

For an isolated system, q = 0, w = 0
ΔU = 0
or U = constant
For cyclic process.

Laws of Thermodynamics and Enthalpy Class 11 Notes | EduRev  

Work done = - Fext.dx
= - P. A dx

 dW = -PextdV

for expansion → dW = - ve
compression → dW = +ve
dq = CdT
⇒ dqv = CvdT
Cv = dqv/dT = qv/ΔT
For an isochoric process dv = 0
dU = qV 
⇒ dU =  CdTa
dU = n CVdT
ΔU = nCv(T2 - T1)
If CV is a function of temperature

Laws of Thermodynamics and Enthalpy Class 11 Notes | EduRev

We know that
U = f(T, V, P)
consider U = f(T, V)
Laws of Thermodynamics and Enthalpy Class 11 Notes | EduRev

For isochoric process dv = 0

Laws of Thermodynamics and Enthalpy Class 11 Notes | EduRev

for 1 mole of gas

Laws of Thermodynamics and Enthalpy Class 11 Notes | EduRev

For an ideal gas U = f(T) only

Laws of Thermodynamics and Enthalpy Class 11 Notes | EduRev

 du = CVdT
ΔU = nCVΔT = nCV(T2 - T1)

ΔU = nCVΔT = nCV(T2 - T1)


ENTHALPY
H = U PV
dH = dU d(PV)
∫dH =  ∫dU + P∫dV
at constant pressure
⇒ ΔH = ΔU + PΔV

From, Ist law of thermodynamics at constant pressure.
dU = dqp + dW
dU = dqp - PdV
dqp = dU + PdV
dH = dU + PdV
ΔH = ΔU + PΔV  ....(1)
at constant volume
ΔH = Δ U +  VΔP ..........(2)

When P & V both changes
ΔH = Δ U +  (P2V2 - P1V1) ..........(3)
ΔH = Δ U + d(PV)
ΔH = Δ U + d(nRT)
ΔH = Δ U + RTDng

For an ideal gas expansion or compression

ΔH = ΔU + nRΔT

ΔH = nCVΔT +  nRΔT
= nΔT[CV  + R]

ΔH = nΔT Cp

We know that, H = f(T, P)
Laws of Thermodynamics and Enthalpy Class 11 Notes | EduRev

At constant pressure
dP = 0

Laws of Thermodynamics and Enthalpy Class 11 Notes | EduRev


Calculation of Δng for any chemical reaction:

Laws of Thermodynamics and Enthalpy Class 11 Notes | EduRev

If reaction is 50% completed.

Laws of Thermodynamics and Enthalpy Class 11 Notes | EduRev

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