Maxwell Relations Civil Engineering (CE) Notes | EduRev

Thermodynamics

Civil Engineering (CE) : Maxwell Relations Civil Engineering (CE) Notes | EduRev

The document Maxwell Relations Civil Engineering (CE) Notes | EduRev is a part of the Civil Engineering (CE) Course Thermodynamics.
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Maxwell Relations

All the four types of energy relations above satisfy the mathematical condition of being continuous variables, as they are themselves functions of state variables. One can thus apply of the criterion of exact differential for these functions.
For a function of the form P = P(X ,Y) one can write the following total differential:

Maxwell Relations Civil Engineering (CE) Notes | EduRev

Applying eqn. 5.11 to 5.3, 5.5, 5.6 and 5.7 one may derive the following relationships termed Maxwell relations:

 

Maxwell Relations Civil Engineering (CE) Notes | EduRev                              ...(5.12 , 5.13)

 

Maxwell Relations Civil Engineering (CE) Notes | EduRev                             ...(5.14, 5.15)

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