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Mechanical Properties of Fluids: Capillarity | Physics for JEE Main & Advanced PDF Download

A glass tube with a very fine bore throughout its length is called a capillary tube. When a capillary tube is dipped in water, the water wets the inner side of the tube and rises inside it, as shown in figure (a). Conversely, if the same capillary tube is dipped in mercury, the mercury is depressed, as shown in figure (b). This phenomenon, where liquids rise or fall in a capillary tube, is known as capillarity.

Mechanical Properties of Fluids: Capillarity | Physics for JEE Main & Advanced

Practical Applications of Capillarity

  1. Oil in a Lamp: The oil rises in the wick by capillary action.
  2. Pen Nib: The tip of the nib is split to form a narrow capillary, allowing ink to rise continuously.
  3. Sap in Trees: Sap and water rise to the top of tree leaves by capillary action.
  4. Wet Towels: If one end of a towel is dipped in a bucket of water and the other end hangs outside, the towel becomes wet throughout due to capillary action.
  5. Blotting Paper: Ink is absorbed by blotting paper due to capillary action.
  6. Soil Moisture: Sandy soil is drier than clay because the capillaries between sand particles are too large to draw water up effectively.
  7. Agricultural Practices: Moisture rises in soil capillaries to the surface, where it evaporates. Ploughing and leveling fields break these capillaries to preserve soil moisture.
  8. Porous Bricks: Bricks are porous and act like capillaries.

Capillary Rise (Height of a Liquid in a Capillary Tube)

Consider a liquid that wets the wall of the tube, forming a concave meniscus as shown in the figure. Let a capillary tube of radius rrr be dipped in a liquid with surface tension TTT and density ρ\rhoρ. Let hhh be the height the liquid rises in the tube. The excess pressure (ppa)(p - p_a)(p−pa) is given by:

Mechanical Properties of Fluids: Capillarity | Physics for JEE Main & Advanced

where R is the radius of the meniscus. This excess pressure causes the liquid to rise in the capillary tube until it balances the hydrostatic pressure h\rho ghρg. Thus, in equilibrium:

Mechanical Properties of Fluids: Capillarity | Physics for JEE Main & Advanced

Mechanical Properties of Fluids: Capillarity | Physics for JEE Main & Advanced

From triangle DOAC:

Mechanical Properties of Fluids: Capillarity | Physics for JEE Main & Advanced

Therefore,

Mechanical Properties of Fluids: Capillarity | Physics for JEE Main & Advanced

and

Mechanical Properties of Fluids: Capillarity | Physics for JEE Main & Advanced

This expression is called the Ascent Formula.

Discussion

(i) Wetting Liquids: For liquids that wet the glass tube, θ<90\theta < 90^\circθ<90∘ and cosθ\cos \thetacosθ is positive, hence hhh is positive. These liquids rise in the capillary tube. Examples include water, milk, kerosene oil, and petrol.

(ii) Non-wetting Liquids: For liquids that do not wet the glass tube, θ>90\theta > 90^\circθ>90∘ and cosθ\cos \thetacosθ is negative, hence hhh is negative. These liquids are depressed in the capillary tube, such as mercury.

Mechanical Properties of Fluids: Capillarity | Physics for JEE Main & Advanced

(iii) Jurin’s Law: Since T,θ,r and gg are constants, h1rh \propto \frac{1}{r} . Thus, the liquid rises more in a narrow tube and less in a wider tube.

(iv) Parallel Plates in Water: If two parallel plates with spacing d are placed in a water reservoir, the height of the rise hh is:

Mechanical Properties of Fluids: Capillarity | Physics for JEE Main & Advanced

Mechanical Properties of Fluids: Capillarity | Physics for JEE Main & Advanced

(v) Concentric Tubes: If two concentric tubes of radii r1r_1r1 and r2r_2r2 (inner one solid) are placed in water, the height of the rise hhh is:

Mechanical Properties of Fluids: Capillarity | Physics for JEE Main & Advanced

Mechanical Properties of Fluids: Capillarity | Physics for JEE Main & Advanced

(vi) Considering Liquid Weight in Meniscus:

Mechanical Properties of Fluids: Capillarity | Physics for JEE Main & Advanced

Mechanical Properties of Fluids: Capillarity | Physics for JEE Main & Advanced

(vii) Meniscus Shape in Capillary Tube: When the capillary tube is vertical, the upper meniscus is concave, and the pressure due to surface tension is directed vertically upward.

(a) If p1>p2p_1 > p_2, the lower meniscus is concave downward. 

(b) If p1<p2p_1 < p_2, the lower meniscus is convex upward. (c) If p1=p2p_1 = p_2, the lower surface will be flat.

(viii) Liquid Between Two Plates: When a small drop of water is placed between two glass plates, it forms a thin film concave outward along its boundary.

Mechanical Properties of Fluids: Capillarity | Physics for JEE Main & Advanced

The pressure inside the film is:

Mechanical Properties of Fluids: Capillarity | Physics for JEE Main & Advanced

If θ=0\theta = (water and glass), the upper plate is pressed downward by:

Mechanical Properties of Fluids: Capillarity | Physics for JEE Main & Advanced

Capillary Rise in a Tube of Insufficient Length

The height to which a liquid rises in a capillary tube of radius rrr is given by the equation:

Mechanical Properties of Fluids: Capillarity | Physics for JEE Main & Advanced

where:

  • TT is the surface tension,
  • θ\theta is the contact angle,
  • ρ\rho is the density,
  • gg is the acceleration due to gravity.

When a capillary tube is cut and its length is less than the calculated height hhh (let's denote this shorter length as hh'h′), the liquid rises to the top of the tube and spreads out, increasing the radius RR'R′ of the liquid meniscus. The liquid does not overflow because the product hRhRhR remains constant. Therefore, hR=hR=constanth'R' = hR = \text{constant}constant.

Given that h<hh' < h, it follows that R>RR' > R, which implies cosθr>cosθr\cos \theta' r > \cos \theta r, leading to cosθ<cosθ\cos \theta' < \cos \theta, and hence θ>θ\theta' > \theta.

Example Problem

Problem Statement: A 5 cm long capillary tube with an internal diameter of 0.1 mm, open at both ends, is dipped in water with a surface tension of 75 dyne/cm. Determine:

  1. Whether water will rise halfway in the capillary.
  2. Whether water will rise to the upper end of the capillary.
  3. Whether water will overflow out of the upper end of the capillary.

Solution: Given:

  • Surface tension of water, T=75 dyne/cm,
  • Radius of the capillary tube, r=0.12r = \frac{0.1}{2}r=20.1 mm = 0.05 mm = 0.005 cm,
  • Density of water, ρ=1\rho = 1 g/cm³,
  • Contact angle, θ=0°\theta = 0°.

Using the formula for capillary rise height hhh:

Mechanical Properties of Fluids: Capillarity | Physics for JEE Main & Advanced

h=30.58 cmh = 30.58 \text{ cm} cm

Since the capillary tube length hh' is 5 cm:

  1. Water will not rise halfway in the capillary: hhh is greater than h\frac{h'}{2}'/ 2.
  2. Water will rise to the upper end of the capillary: The tube is insufficiently long, so the water rises to its upper end.
  3. Water will not overflow: It will rise only to the tube's upper end.

The radius of curvature RR' of the liquid meniscus adjusts such that Rh=RhR'h' = RhR′h′=Rh:

Mechanical Properties of Fluids: Capillarity | Physics for JEE Main & Advanced

R' = 0.0306 cm

Applications of Surface Tension

  1. Detergents and Waterproofing: Detergents decrease the contact angle, increasing wettability. Waterproofing agents increase the contact angle, making fabrics water-repellent.
  2. Antiseptics: Low surface tension prevents droplet formation, allowing antiseptics to spread over wounds. Similarly, lubricating oils and paints have low surface tension to cover large areas effectively.
  3. Oil Spreading on Water: Oil spreads over water because its surface tension is lower than that of cold water.
  4. Calming Rough Seas: Oil can calm rough seas by reducing the surface tension of water.

Effect of Temperature and Impurities on Surface Tension

  • Temperature: Surface tension decreases with an increase in temperature. According to Ferguson's formula:

Mechanical Properties of Fluids: Capillarity | Physics for JEE Main & Advanced

 where T_0To is the surface tension at 0°C, 

θ\theta is the absolute temperature, 

\theta_Cθc is the critical temperature, and nn is a constant (mean value 1.21). 

Surface tension becomes zero at the critical temperature.

  • Impurities: The addition of impurities affects surface tension. Highly soluble substances like NaCl increase water's surface tension, while sparingly soluble substances like phenol and soap decrease it.

The document Mechanical Properties of Fluids: Capillarity | Physics for JEE Main & Advanced is a part of the JEE Course Physics for JEE Main & Advanced.
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FAQs on Mechanical Properties of Fluids: Capillarity - Physics for JEE Main & Advanced

1. How does capillarity affect the height of a liquid in a capillary tube?
Ans. Capillarity is the phenomenon where a liquid rises or falls in a narrow tube due to the forces of adhesion and cohesion. The height of the liquid in a capillary tube is determined by the balance between these forces, with the liquid rising higher in tubes with smaller diameters.
2. What factors affect the capillary rise in a tube of insufficient length?
Ans. The capillary rise in a tube of insufficient length can be affected by factors such as the diameter of the tube, the surface tension of the liquid, and the angle of contact between the liquid and the tube. If the tube is too short, the capillary rise may not be able to overcome gravity and the liquid may not rise at all.
3. How is capillarity related to the mechanical properties of fluids?
Ans. Capillarity is related to the mechanical properties of fluids as it demonstrates the ability of fluids to flow and interact with solid surfaces. The phenomenon of capillarity is influenced by factors such as surface tension, viscosity, and adhesion, which are important properties of fluids in mechanical applications.
4. Can capillarity be used in practical applications beyond capillary rise in tubes?
Ans. Yes, capillarity has various practical applications beyond capillary rise in tubes. It is used in industries such as inkjet printing, microfluidics, and soil science. Capillarity also plays a role in the transportation of water in plants and the functioning of medical devices.
5. How can the concept of capillarity be tested or demonstrated in a laboratory setting?
Ans. The concept of capillarity can be tested in a laboratory setting by using capillary tubes of different diameters and liquids with varying surface tensions. By measuring the height of the liquid rise in the tubes, the relationship between capillarity and the mechanical properties of fluids can be observed and studied.
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