PPT - Solution of Thermodynamics Civil Engineering (CE) Notes | EduRev

Thermodynamics

Civil Engineering (CE) : PPT - Solution of Thermodynamics Civil Engineering (CE) Notes | EduRev

 Page 1


Solution of Thermodynamics
Chemical Engineering
Thermodynamics
Page 2


Solution of Thermodynamics
Chemical Engineering
Thermodynamics
9.1 Fundamental Property Relation
9.2 The Chemical Potential and Phase Equilibria
9.3 Partial Properties of Solution
9.4 Ideal Gas Mixture
9.5 Fugacity and Fugacity Coefficient: Pure
Species and Species in Mixture/Solution
9.6 Fugacity Coefficient of Gas Mixture from the
Virial Equation of State
9.7 Ideal Solution and Excess Properties
9.8 Liquid Phase Properties from VLE data
9.9 Property Changes of Mixing
9.10 Heat Effects of Mixing Process
Chapter Outline
Page 3


Solution of Thermodynamics
Chemical Engineering
Thermodynamics
9.1 Fundamental Property Relation
9.2 The Chemical Potential and Phase Equilibria
9.3 Partial Properties of Solution
9.4 Ideal Gas Mixture
9.5 Fugacity and Fugacity Coefficient: Pure
Species and Species in Mixture/Solution
9.6 Fugacity Coefficient of Gas Mixture from the
Virial Equation of State
9.7 Ideal Solution and Excess Properties
9.8 Liquid Phase Properties from VLE data
9.9 Property Changes of Mixing
9.10 Heat Effects of Mixing Process
Chapter Outline
Multi-component gases and liquids commonly
undergoes composition changes by separation
and mixing processes.
This chapter gives the thermodynamics
applications of both gas mixtures and liquid
solutions.
Page 4


Solution of Thermodynamics
Chemical Engineering
Thermodynamics
9.1 Fundamental Property Relation
9.2 The Chemical Potential and Phase Equilibria
9.3 Partial Properties of Solution
9.4 Ideal Gas Mixture
9.5 Fugacity and Fugacity Coefficient: Pure
Species and Species in Mixture/Solution
9.6 Fugacity Coefficient of Gas Mixture from the
Virial Equation of State
9.7 Ideal Solution and Excess Properties
9.8 Liquid Phase Properties from VLE data
9.9 Property Changes of Mixing
9.10 Heat Effects of Mixing Process
Chapter Outline
Multi-component gases and liquids commonly
undergoes composition changes by separation
and mixing processes.
This chapter gives the thermodynamics
applications of both gas mixtures and liquid
solutions.
9.1 Fundamental Property Relation
The definition of the chemical potential of
species i in the mixture of any closed system:
( )
j
n T P
i
i
n
nG
, ,
ú
û
ù
ê
ë
é
¶
¶
º m
the Gibbs energy which is the function
of  temperature, pressure and number of moles
of the chemical species present.
Page 5


Solution of Thermodynamics
Chemical Engineering
Thermodynamics
9.1 Fundamental Property Relation
9.2 The Chemical Potential and Phase Equilibria
9.3 Partial Properties of Solution
9.4 Ideal Gas Mixture
9.5 Fugacity and Fugacity Coefficient: Pure
Species and Species in Mixture/Solution
9.6 Fugacity Coefficient of Gas Mixture from the
Virial Equation of State
9.7 Ideal Solution and Excess Properties
9.8 Liquid Phase Properties from VLE data
9.9 Property Changes of Mixing
9.10 Heat Effects of Mixing Process
Chapter Outline
Multi-component gases and liquids commonly
undergoes composition changes by separation
and mixing processes.
This chapter gives the thermodynamics
applications of both gas mixtures and liquid
solutions.
9.1 Fundamental Property Relation
The definition of the chemical potential of
species i in the mixture of any closed system:
( )
j
n T P
i
i
n
nG
, ,
ú
û
ù
ê
ë
é
¶
¶
º m
the Gibbs energy which is the function
of  temperature, pressure and number of moles
of the chemical species present.
9.2 The Chemical Potential and Phase
Equilibria
For a closed system consists of 2 phase in
equilibrium, the mass transfer between phases
may occur.
At the same P and T, the chemical potential of
each species of multiple phases in equilibrium
is the same for all species.
p b a
m m m
i i i
= = = .......
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