|Table of contents|
|1 Crore+ students have signed up on EduRev. Have you?|
The entire positive charge and nearly the entire mass of atom is concentrated in a very small space called the nucleus of an atom.
The nucleus consists of protons and neutrons. They are called nucleons.
(i) Atomic Number The number of protons in the nucleus of an atom of the element is called atomic number (Z) of the element.
(ii) Mass Number The total number of protons and neutrons present inside the nucleus of an atom of the element is called mass number (A) of the element.
(iii) Nuclear Size The radius of the nucleus R ∝ A1/3
⇒ R = Ro A1/3
where, Ro = 1.1 * 10-15 m is an empirical constant.
(iv) Nuclear Density Nuclear density is independent of mass number and therefore same for all nuclei.
ρ = mass of nucleus / volume of nucleus ⇒ ρ = 3m / 4π R3o
where, m = average mass of a nucleon.
(v) Atomic Mass Unit It is defined as 1 / 12th the mass of carbon nucleus.
It is abbreviated as arnu and often denoted by u. Thus
1 amu = 1.992678 * 10-26 / 12 kg
= 1.6 * 10-27 kg = 931 Me V
The atoms of an element having same atomic number but different mass numbers. are called isotopes.
e.g., 1H1, 1H2, 1H3 are isotopes of hydrogen.
The atoms of different elements having same mass numbers but different atomic numbers, are called isobars.
e.g., 1H3, 2He3 and 10Na22, 10Ne22 are isobars.
The atoms of different elements having different atomic numbers and different mass numbers but having same number of neutrons, are called isotones.
e.g., 1H3, 2He4 and 6C14, 8O16 are isobars.
Atoms having the same mass number and the same atomic number but different radioactive properties are called isomers,
The force acting inside the nucleus or acting between nucleons is called nuclear force.
Nuclear forces are the strongest forces in nature.
According to the Yukawa, the nuclear force acts between the nucleon due to continuous exchange of meson particles.
The difference between the sum of masses of all nucleons (M) mass of the nucleus (m) is called mass defect.
Mass Defect (Δm) = M – m = [Zmp + (A – Z)mn – mn]
The minimum energy required to separate the nucleons up to an infinite distance from the nucleus, is called nuclear binding energy.
Nuclear binding energy per nucleon = Nuclear binding energy / Total number of nucleons
Binding energy, Eb = [Zmp + (A – Z) mn – mN]c2
Packing Fraction (P)
p = (Exact nuclear mass) – (Mass number) / Mass number
= M – A / M
The larger the value of packing friction. greater is the stability of the nucleus.
[The nuclei containing even number of protons and even number of neutrons are most stable.
The nuclei containing odd number of protons and odd number of neutrons are most instable.]
The phenomena of disintegration of heavy elements into comparatively lighter elements by the emission of radiations is called radioactivity. This phenomena was discovered by Henry Becquerel in 1896.
Radiations Emitted by a Radioactive Element
Three types of radiations emitted by radioactive elements
(iii) γ – rays
α-rays consists of α-particles, which are doubly ionised helium ion.
β-rays are consist of fast moving electrons.
γ – rays are electromagnetic rays.
[When an α – particle is emitted by a nucleus its atomic number decreases by 2 and mass number decreases by 4.
When a β -particle is emitted by a nucleus its atomic number is Increases by one and mass number remains unchanged.
When a γ – particle is emitted by a nucleus its atomic number and mass number remain unchanged
The rate of disintegration of radioactive atoms at any instant is directly proportional to the number of radioactive atoms present in the sample at that instant.
Rate of disintegration ( – dN / dt) ∝ N
– dN / dt = λ N
where λ is the decay constant.
The number of atoms present undecayed in the sample at any instant N = No e-λt
where, No is number of atoms at time t = 0 and N is number of atoms at time t.
The time is which the half number of atoms present initially in any sample decays, is called half-life (T) of that radioactive element
Relation between half-life and disintegration constant is given by
T = log2e / λ = 0.6931 / λ
Average life or mean life (τ) of a radioactive element is the ratio of total life time of all the atoms and total number of atoms present initially in the sample.
Relation between average life and decay constant τ = 1 / λ
Relation between half-life and average life τ = 1.44 T
The number of atoms left undecayed after n half-lifes is given by
N = No (1 / 2)n = No (1 / 2) t/T
where, n = t / T, here t = total time.
Activity of a Radioactive Element
The activity of a radioactive element is equal to its rate of disintegration.
Activity R = (– dN / dt)
Activity of the sample after time t,
R = Ro e-λt
Its SI unit is Becquerel (Bq).
Its other units are Curie and Rutherford.
1 Curie = 3.7 * 1010 decay/s
1 Rutherford = 106 decay/s
The process of the splitting of a heavy nucleus into two or more lighter nuclei is called nuclear fission.
When a slow moving neutron strikes with a uranium nucleus (92U235), it splits into 56Ba141 and 36Kr92 along with three neutrons and a lot of energy.
If the particle starting the nuclear fission reaction is produced as a product and further take part in the nuclear fission reaction, then a chain of fission reaction started, which is called nuclear chain reaction.
Nuclear chain reaction are of two types
(i) Controlled chain reaction
(ii) Uncontrolled chain reaction
The main parts of a nuclear reactor are following
(i) Fuel Fissionable materials like 92U235, 92U238, 94U239 are used as fuel.
(ii) Moderator Heavy water, graphite and beryllium oxide are used to slower down fast moving neutrons.
(iii) Coolant The cold water, liquid oxygen, etc. are used to remove heat generated in the fission process.
(iv) Control rods Cadmium or boron rods are good absorber of neutrons and therefore used to control the fission reaction.
Atom bomb working is based on uncontrolled chain reaction.
The process of combining of two lighter nuclei to form one heavy nucleus, is called nuclear fusion.
Three deuteron nuclei (1H2) fuse, 21.6 MeV is energy released and nucleus of helium (2He4) is formed.
In this process, a large amount of energy is released.
Nuclear fusion takes place at very high temperature approximately about 107 K and at very high pressure 106 atmosphere.
Hydrogen bomb is based on nuclear fusion.
The source of Sun’s energy is the nuclear fusion taking place at sun.
The energy released during nuclear fusion is know as thermonuclear energy. Protons are needed for fusion while neutrons are needed for fission process.