Page 1
Chapter 10. Atmospheric Pollution
Exercise 10
Solution 1.
The toxic substances that have an undesirable impact on different components of the
environment and are injurious to life and property are known as pollutants.
Solution 2.
Effect of Pollutant on living beings:
Fluorides: Effects teeth and bones.
Smoke Particles: Cause asthma and lung diseases.
Lead: Damages the nervous and digestive systems and can cause cancer .
Mercury compounds: They cause disease like Minamata commonly found in
fishermen.
Smog: It reduces visibility and induces respiratory troubles.
Nitrogen Oxide: Causes death of many plants.
Solution 3.
Air pollution: It is defined as the presence of a contaminant in the atmosphere in a
concentration large enough to injure human, plant and animal life.
Air pollution takes place due to the presence of gaseous pollutants like oxides of sulphur,
hydrocarbons, smoke, oxides of carbon, oxides of nitrogen, dust, particulate pollutants
like mist, spray and fume.
Solution 4.
Components of air is:
Pure Air
components
By Volume
percentage
Concentration parts
per million (ppm)
Nitrogen 78.09 780,900
Oxgyen 20.94 209,400
Inert Gases
Argon
0.93 9300
Neon 18
Helium 5
Krypton 1
Xenon 1
Carbon-dioxide 0.03 315
Page 2
Chapter 10. Atmospheric Pollution
Exercise 10
Solution 1.
The toxic substances that have an undesirable impact on different components of the
environment and are injurious to life and property are known as pollutants.
Solution 2.
Effect of Pollutant on living beings:
Fluorides: Effects teeth and bones.
Smoke Particles: Cause asthma and lung diseases.
Lead: Damages the nervous and digestive systems and can cause cancer .
Mercury compounds: They cause disease like Minamata commonly found in
fishermen.
Smog: It reduces visibility and induces respiratory troubles.
Nitrogen Oxide: Causes death of many plants.
Solution 3.
Air pollution: It is defined as the presence of a contaminant in the atmosphere in a
concentration large enough to injure human, plant and animal life.
Air pollution takes place due to the presence of gaseous pollutants like oxides of sulphur,
hydrocarbons, smoke, oxides of carbon, oxides of nitrogen, dust, particulate pollutants
like mist, spray and fume.
Solution 4.
Components of air is:
Pure Air
components
By Volume
percentage
Concentration parts
per million (ppm)
Nitrogen 78.09 780,900
Oxgyen 20.94 209,400
Inert Gases
Argon
0.93 9300
Neon 18
Helium 5
Krypton 1
Xenon 1
Carbon-dioxide 0.03 315
Methane 1
Hydrogen 0.5
Natural pollutants
Oxides of nitrogen
Ozone
0.52
0.02
Solution 5.
Particulate Pollutant are dust, smoke, mist, spray and fume.
Solution 6.
Cigarette smoking is harmful not only for one who is smoking but also for sitting nearby
and so one should avoid it. Tobacco smoke causes lung cancer and asthma.
Solution 7.
Smog: A smog is a pollutant which is a combination of oxides of sulphur and nitrogen,
partially oxidized hydrocarbons and their derivatives produced by industries and
automobiles from a dark, thick dust and soot laden fog known as smog.
Damaging Effect: Smog is noxious and irritating. It reduces visibility, induce respiratory
troubles and can cause death by suffocation.
Photochemical Smog damages the tissues of certain plants and even decreases the yield
of citrus fruits and grapes.
Solution 8.
ppm means parts per million. That is, share in 10, 00000.
Solution 9.
Major air pollutants are: Large amounts of Carbon monoxide, Sulphur dioxide, H
2
S,
Chlorine, HCl, Hydrocarbons and particulates. Particulate matter like sand, dust etc.
Secondary pollutant like (PAN) peroxyaryl.
Solution 10.
Control of: (i) Carbon monoxide, CO emission:
Emission of CO can be controlled by :
Switching over from internal combustion engine to electrically powered cars. (b)
Using alcohols, CNG, LNG in place of gasoline.
By using Catalytic Mufflers or Convertors.
Using pollution control devices to burn gasoline completely.
Using lead free petrol.
(ii) (SOx) oxides of Sulphur emission: Oxides of sulphur (SO, SO) emission can be
reduced by- (a) Using coal or oil that has low sulphur content. (b) By using Scrubber, a
Page 3
Chapter 10. Atmospheric Pollution
Exercise 10
Solution 1.
The toxic substances that have an undesirable impact on different components of the
environment and are injurious to life and property are known as pollutants.
Solution 2.
Effect of Pollutant on living beings:
Fluorides: Effects teeth and bones.
Smoke Particles: Cause asthma and lung diseases.
Lead: Damages the nervous and digestive systems and can cause cancer .
Mercury compounds: They cause disease like Minamata commonly found in
fishermen.
Smog: It reduces visibility and induces respiratory troubles.
Nitrogen Oxide: Causes death of many plants.
Solution 3.
Air pollution: It is defined as the presence of a contaminant in the atmosphere in a
concentration large enough to injure human, plant and animal life.
Air pollution takes place due to the presence of gaseous pollutants like oxides of sulphur,
hydrocarbons, smoke, oxides of carbon, oxides of nitrogen, dust, particulate pollutants
like mist, spray and fume.
Solution 4.
Components of air is:
Pure Air
components
By Volume
percentage
Concentration parts
per million (ppm)
Nitrogen 78.09 780,900
Oxgyen 20.94 209,400
Inert Gases
Argon
0.93 9300
Neon 18
Helium 5
Krypton 1
Xenon 1
Carbon-dioxide 0.03 315
Methane 1
Hydrogen 0.5
Natural pollutants
Oxides of nitrogen
Ozone
0.52
0.02
Solution 5.
Particulate Pollutant are dust, smoke, mist, spray and fume.
Solution 6.
Cigarette smoking is harmful not only for one who is smoking but also for sitting nearby
and so one should avoid it. Tobacco smoke causes lung cancer and asthma.
Solution 7.
Smog: A smog is a pollutant which is a combination of oxides of sulphur and nitrogen,
partially oxidized hydrocarbons and their derivatives produced by industries and
automobiles from a dark, thick dust and soot laden fog known as smog.
Damaging Effect: Smog is noxious and irritating. It reduces visibility, induce respiratory
troubles and can cause death by suffocation.
Photochemical Smog damages the tissues of certain plants and even decreases the yield
of citrus fruits and grapes.
Solution 8.
ppm means parts per million. That is, share in 10, 00000.
Solution 9.
Major air pollutants are: Large amounts of Carbon monoxide, Sulphur dioxide, H
2
S,
Chlorine, HCl, Hydrocarbons and particulates. Particulate matter like sand, dust etc.
Secondary pollutant like (PAN) peroxyaryl.
Solution 10.
Control of: (i) Carbon monoxide, CO emission:
Emission of CO can be controlled by :
Switching over from internal combustion engine to electrically powered cars. (b)
Using alcohols, CNG, LNG in place of gasoline.
By using Catalytic Mufflers or Convertors.
Using pollution control devices to burn gasoline completely.
Using lead free petrol.
(ii) (SOx) oxides of Sulphur emission: Oxides of sulphur (SO, SO) emission can be
reduced by- (a) Using coal or oil that has low sulphur content. (b) By using Scrubber, a
device that absorbs gaseous pollutants.
Solution 11.
Acid rain
Factories in big cities release nitrogen dioxide and sulphur dioxide as their wastes. These
gases dissolve in rainwater during rains and form nitrous acid and sulphurous acid. As the
rain falls, these acids come down to the ground as an acid rain.
The normal rain is slightly acidic having a pH about 56 as carbon dioxide gas reacts with
it to form a weak carbonic acid.
CO
2
+ H
2
O ? H
2
CO
3
(Carbonic acid)
The pH of acid rain ranges between 56 – 35 and in some cases pH can go even lower
than 2.
The two forms of deposition of acid rains are:
Dry deposits-Particles containing sulphates and nitrates
Wet deposits-dew, rain, fog, smoke
Formation of acid rain
Acid rain refers to rain which has pH less than 5.6. It is mainly caused by
atmospheric pollutants.
Natural sources: Bacterial decomposition, forest fires, volcanic eruptions.
Man made sources: Industries and smelting plants, automobile exhausts, power
plants etc.
Oxides of nitrogen and sulphur interact with water vapour in presence of
sunlight in the atmosphere to form nitric acid and sulphuric acid mist respectively.
This mist remains as vapours at high temperatures and condenses at low
temperatures. These acids mix with rain (snow or fog) and fall down on the Earth
resulting in acid rain.
Causes of acid rain
The formation of mineral acids like carbonic acid, nitric acid and sulphuric acid is
the main cause of acid rain.
Formation of Nitric acid and Nitrous acid
Nitrogen and oxygen (that is oxides of nitrogen) combines in the presence of
thunder and lightning to form nitric acid.
They are also produced by internal combustion engines (automobile engines). This
then gets oxidized in the atmosphere to nitrogen dioxide. Nitrogen dioxide
combines with water to form a mixture of nitrous acid and nitric acid.
N
2
+ O
2
? 2NO
(Nitrogen oxide)
Page 4
Chapter 10. Atmospheric Pollution
Exercise 10
Solution 1.
The toxic substances that have an undesirable impact on different components of the
environment and are injurious to life and property are known as pollutants.
Solution 2.
Effect of Pollutant on living beings:
Fluorides: Effects teeth and bones.
Smoke Particles: Cause asthma and lung diseases.
Lead: Damages the nervous and digestive systems and can cause cancer .
Mercury compounds: They cause disease like Minamata commonly found in
fishermen.
Smog: It reduces visibility and induces respiratory troubles.
Nitrogen Oxide: Causes death of many plants.
Solution 3.
Air pollution: It is defined as the presence of a contaminant in the atmosphere in a
concentration large enough to injure human, plant and animal life.
Air pollution takes place due to the presence of gaseous pollutants like oxides of sulphur,
hydrocarbons, smoke, oxides of carbon, oxides of nitrogen, dust, particulate pollutants
like mist, spray and fume.
Solution 4.
Components of air is:
Pure Air
components
By Volume
percentage
Concentration parts
per million (ppm)
Nitrogen 78.09 780,900
Oxgyen 20.94 209,400
Inert Gases
Argon
0.93 9300
Neon 18
Helium 5
Krypton 1
Xenon 1
Carbon-dioxide 0.03 315
Methane 1
Hydrogen 0.5
Natural pollutants
Oxides of nitrogen
Ozone
0.52
0.02
Solution 5.
Particulate Pollutant are dust, smoke, mist, spray and fume.
Solution 6.
Cigarette smoking is harmful not only for one who is smoking but also for sitting nearby
and so one should avoid it. Tobacco smoke causes lung cancer and asthma.
Solution 7.
Smog: A smog is a pollutant which is a combination of oxides of sulphur and nitrogen,
partially oxidized hydrocarbons and their derivatives produced by industries and
automobiles from a dark, thick dust and soot laden fog known as smog.
Damaging Effect: Smog is noxious and irritating. It reduces visibility, induce respiratory
troubles and can cause death by suffocation.
Photochemical Smog damages the tissues of certain plants and even decreases the yield
of citrus fruits and grapes.
Solution 8.
ppm means parts per million. That is, share in 10, 00000.
Solution 9.
Major air pollutants are: Large amounts of Carbon monoxide, Sulphur dioxide, H
2
S,
Chlorine, HCl, Hydrocarbons and particulates. Particulate matter like sand, dust etc.
Secondary pollutant like (PAN) peroxyaryl.
Solution 10.
Control of: (i) Carbon monoxide, CO emission:
Emission of CO can be controlled by :
Switching over from internal combustion engine to electrically powered cars. (b)
Using alcohols, CNG, LNG in place of gasoline.
By using Catalytic Mufflers or Convertors.
Using pollution control devices to burn gasoline completely.
Using lead free petrol.
(ii) (SOx) oxides of Sulphur emission: Oxides of sulphur (SO, SO) emission can be
reduced by- (a) Using coal or oil that has low sulphur content. (b) By using Scrubber, a
device that absorbs gaseous pollutants.
Solution 11.
Acid rain
Factories in big cities release nitrogen dioxide and sulphur dioxide as their wastes. These
gases dissolve in rainwater during rains and form nitrous acid and sulphurous acid. As the
rain falls, these acids come down to the ground as an acid rain.
The normal rain is slightly acidic having a pH about 56 as carbon dioxide gas reacts with
it to form a weak carbonic acid.
CO
2
+ H
2
O ? H
2
CO
3
(Carbonic acid)
The pH of acid rain ranges between 56 – 35 and in some cases pH can go even lower
than 2.
The two forms of deposition of acid rains are:
Dry deposits-Particles containing sulphates and nitrates
Wet deposits-dew, rain, fog, smoke
Formation of acid rain
Acid rain refers to rain which has pH less than 5.6. It is mainly caused by
atmospheric pollutants.
Natural sources: Bacterial decomposition, forest fires, volcanic eruptions.
Man made sources: Industries and smelting plants, automobile exhausts, power
plants etc.
Oxides of nitrogen and sulphur interact with water vapour in presence of
sunlight in the atmosphere to form nitric acid and sulphuric acid mist respectively.
This mist remains as vapours at high temperatures and condenses at low
temperatures. These acids mix with rain (snow or fog) and fall down on the Earth
resulting in acid rain.
Causes of acid rain
The formation of mineral acids like carbonic acid, nitric acid and sulphuric acid is
the main cause of acid rain.
Formation of Nitric acid and Nitrous acid
Nitrogen and oxygen (that is oxides of nitrogen) combines in the presence of
thunder and lightning to form nitric acid.
They are also produced by internal combustion engines (automobile engines). This
then gets oxidized in the atmosphere to nitrogen dioxide. Nitrogen dioxide
combines with water to form a mixture of nitrous acid and nitric acid.
N
2
+ O
2
? 2NO
(Nitrogen oxide)
2NO + O
2
? 2NO
2
(Nitrogen dioxide)
2NO
2
+ H
2
O ? HNO
2
+ HNO
3
(Nitrous acid) (Nitric acid)
Formation of Sulphuric acid and Sulphurous acid
Impurities in the coal: Coal used in power plants contains upto 4% sulphur. On
combustion it forms pollutant sulphur dioxide (i.e, oxides of sulphur).
S + O
2
? SO
2
(Sulphur dioxide)
Sulphur dioxide reacts with water vapour to form sulphurous acid.
SO
2
+ H
2
O ? H
2
SO
3
(Sulphurous acid)
Sulphur dioxide can also be oxidized to sulphur trioxide.
2SO
2
+ O
2
? 2SO
3
(Sulphur trioxide)
Sulphur trioxide reacts with water vapour to form sulphuric acid.
SO
3
+ H
2
O H
2
SO
4
(Sulphuric acid)
Impact of Acid rain
Changes the acidity of soil: The acids present in the acid rain like, nitric acid, nitrous acid
and sulphuric acid, sulphurous acid increases the acidity of soil. It removes calcium and
potassium minerals i.e., basic ingredients from the soil losing their fertility.
The hydrogen ions H
+
which are added to the soil, when acid rain falls on the Earth
interact chemically with existing soil minerals.
Affects water bodies and marine organisms: The water of lakes and rivers is becoming
acidic, which may no longer support aquatic life.
Material damage: It increases corrosion of metals, disintegrates paper and leather.
Weakens building materials such as statues, marbles, sculptures, limestone, slate, mortar
etc. These materials become pitted and weakened mechanically. The Taj Mahal in India
faces this problem.
CaCO
3
+ H
2
SO
4
? CaSO
4
+ CO
2
+ H
2
O
CaCO
3
+ 2HNO
3
? Ca(NO
3
)
2
+ CO
2
+ H
2
O
Impact on living things: It damages forests. Acid rain gets absorbed by plants, animals
directly or indirectly toxicity enters food chain affecting humans. They can affect a
person’s breathing, at sufficiently high concentrations. Sulphur dioxide irritates the upper
Page 5
Chapter 10. Atmospheric Pollution
Exercise 10
Solution 1.
The toxic substances that have an undesirable impact on different components of the
environment and are injurious to life and property are known as pollutants.
Solution 2.
Effect of Pollutant on living beings:
Fluorides: Effects teeth and bones.
Smoke Particles: Cause asthma and lung diseases.
Lead: Damages the nervous and digestive systems and can cause cancer .
Mercury compounds: They cause disease like Minamata commonly found in
fishermen.
Smog: It reduces visibility and induces respiratory troubles.
Nitrogen Oxide: Causes death of many plants.
Solution 3.
Air pollution: It is defined as the presence of a contaminant in the atmosphere in a
concentration large enough to injure human, plant and animal life.
Air pollution takes place due to the presence of gaseous pollutants like oxides of sulphur,
hydrocarbons, smoke, oxides of carbon, oxides of nitrogen, dust, particulate pollutants
like mist, spray and fume.
Solution 4.
Components of air is:
Pure Air
components
By Volume
percentage
Concentration parts
per million (ppm)
Nitrogen 78.09 780,900
Oxgyen 20.94 209,400
Inert Gases
Argon
0.93 9300
Neon 18
Helium 5
Krypton 1
Xenon 1
Carbon-dioxide 0.03 315
Methane 1
Hydrogen 0.5
Natural pollutants
Oxides of nitrogen
Ozone
0.52
0.02
Solution 5.
Particulate Pollutant are dust, smoke, mist, spray and fume.
Solution 6.
Cigarette smoking is harmful not only for one who is smoking but also for sitting nearby
and so one should avoid it. Tobacco smoke causes lung cancer and asthma.
Solution 7.
Smog: A smog is a pollutant which is a combination of oxides of sulphur and nitrogen,
partially oxidized hydrocarbons and their derivatives produced by industries and
automobiles from a dark, thick dust and soot laden fog known as smog.
Damaging Effect: Smog is noxious and irritating. It reduces visibility, induce respiratory
troubles and can cause death by suffocation.
Photochemical Smog damages the tissues of certain plants and even decreases the yield
of citrus fruits and grapes.
Solution 8.
ppm means parts per million. That is, share in 10, 00000.
Solution 9.
Major air pollutants are: Large amounts of Carbon monoxide, Sulphur dioxide, H
2
S,
Chlorine, HCl, Hydrocarbons and particulates. Particulate matter like sand, dust etc.
Secondary pollutant like (PAN) peroxyaryl.
Solution 10.
Control of: (i) Carbon monoxide, CO emission:
Emission of CO can be controlled by :
Switching over from internal combustion engine to electrically powered cars. (b)
Using alcohols, CNG, LNG in place of gasoline.
By using Catalytic Mufflers or Convertors.
Using pollution control devices to burn gasoline completely.
Using lead free petrol.
(ii) (SOx) oxides of Sulphur emission: Oxides of sulphur (SO, SO) emission can be
reduced by- (a) Using coal or oil that has low sulphur content. (b) By using Scrubber, a
device that absorbs gaseous pollutants.
Solution 11.
Acid rain
Factories in big cities release nitrogen dioxide and sulphur dioxide as their wastes. These
gases dissolve in rainwater during rains and form nitrous acid and sulphurous acid. As the
rain falls, these acids come down to the ground as an acid rain.
The normal rain is slightly acidic having a pH about 56 as carbon dioxide gas reacts with
it to form a weak carbonic acid.
CO
2
+ H
2
O ? H
2
CO
3
(Carbonic acid)
The pH of acid rain ranges between 56 – 35 and in some cases pH can go even lower
than 2.
The two forms of deposition of acid rains are:
Dry deposits-Particles containing sulphates and nitrates
Wet deposits-dew, rain, fog, smoke
Formation of acid rain
Acid rain refers to rain which has pH less than 5.6. It is mainly caused by
atmospheric pollutants.
Natural sources: Bacterial decomposition, forest fires, volcanic eruptions.
Man made sources: Industries and smelting plants, automobile exhausts, power
plants etc.
Oxides of nitrogen and sulphur interact with water vapour in presence of
sunlight in the atmosphere to form nitric acid and sulphuric acid mist respectively.
This mist remains as vapours at high temperatures and condenses at low
temperatures. These acids mix with rain (snow or fog) and fall down on the Earth
resulting in acid rain.
Causes of acid rain
The formation of mineral acids like carbonic acid, nitric acid and sulphuric acid is
the main cause of acid rain.
Formation of Nitric acid and Nitrous acid
Nitrogen and oxygen (that is oxides of nitrogen) combines in the presence of
thunder and lightning to form nitric acid.
They are also produced by internal combustion engines (automobile engines). This
then gets oxidized in the atmosphere to nitrogen dioxide. Nitrogen dioxide
combines with water to form a mixture of nitrous acid and nitric acid.
N
2
+ O
2
? 2NO
(Nitrogen oxide)
2NO + O
2
? 2NO
2
(Nitrogen dioxide)
2NO
2
+ H
2
O ? HNO
2
+ HNO
3
(Nitrous acid) (Nitric acid)
Formation of Sulphuric acid and Sulphurous acid
Impurities in the coal: Coal used in power plants contains upto 4% sulphur. On
combustion it forms pollutant sulphur dioxide (i.e, oxides of sulphur).
S + O
2
? SO
2
(Sulphur dioxide)
Sulphur dioxide reacts with water vapour to form sulphurous acid.
SO
2
+ H
2
O ? H
2
SO
3
(Sulphurous acid)
Sulphur dioxide can also be oxidized to sulphur trioxide.
2SO
2
+ O
2
? 2SO
3
(Sulphur trioxide)
Sulphur trioxide reacts with water vapour to form sulphuric acid.
SO
3
+ H
2
O H
2
SO
4
(Sulphuric acid)
Impact of Acid rain
Changes the acidity of soil: The acids present in the acid rain like, nitric acid, nitrous acid
and sulphuric acid, sulphurous acid increases the acidity of soil. It removes calcium and
potassium minerals i.e., basic ingredients from the soil losing their fertility.
The hydrogen ions H
+
which are added to the soil, when acid rain falls on the Earth
interact chemically with existing soil minerals.
Affects water bodies and marine organisms: The water of lakes and rivers is becoming
acidic, which may no longer support aquatic life.
Material damage: It increases corrosion of metals, disintegrates paper and leather.
Weakens building materials such as statues, marbles, sculptures, limestone, slate, mortar
etc. These materials become pitted and weakened mechanically. The Taj Mahal in India
faces this problem.
CaCO
3
+ H
2
SO
4
? CaSO
4
+ CO
2
+ H
2
O
CaCO
3
+ 2HNO
3
? Ca(NO
3
)
2
+ CO
2
+ H
2
O
Impact on living things: It damages forests. Acid rain gets absorbed by plants, animals
directly or indirectly toxicity enters food chain affecting humans. They can affect a
person’s breathing, at sufficiently high concentrations. Sulphur dioxide irritates the upper
respiratory tract, which serve to expel soot particles and dust in the inhaled air. At even
lower concentrations, it does still greater harm by injuring lung tissues.
Solution 12.
Sulphur dioxide pollutes the air, effects the yield of crops and causes damage to lungs,
SO
2
gets converted to SO
3
and combines with water drops of air and cause acid rain.
Solution 13.
In the atmosphere ozone is formed by the action of ultraviolet rays of the sun on oxygen.
3O
2 (g)
? 2O
3(g)
The high energy UV radiations break oxygen molecules into oxygen atoms.
O
2
+ Far UV ? O + O
Oxygen molecule Oxygen atoms
Oxygen atom reacts with oxygen molecule to form ozone.
O + O
2
? O
3
Atom Molecule Ozone
The Net reaction is:
3O
2
+ Far UV ? 2O
3
Solution 14.
It is formed by the action of ultraviolet rays of the Sun on oxygen.
O
3
? O + O
2
Ozone layer acts as a blanket in the atmosphere 16 km height above the Earths surface.
It absorbs harmful ultraviolet rays (UV radiations) coming from the Sun and prevents
them to reach the surface of the Earth.
Ultraviolet rays have very harmful effects on living things. It causes skin cancer. It
destroys many organic species which are necessary for life.
Thus it protects the life on earth from harmful effects of Ultra Violet Rays. Which can
cause (a) Skin cancer (b) destroy many organic species necessary for life.
Solution 15.
Chemicals responsible for ozone destruction free radical chlorine (Cl) and nitrioxide (NO)
are responsible for ozone depletion i.e. react with O
3
Free radical chlorine (Cl) is produced
by UV rays from chlorofluoro carbons enter the atmosphere because of excessive use as
solvents, Aerosol, Spray, Propellants, Refrigerants and blowing agents for plastic foams.
Chemicals responsible for the depletion of ozone layer
Fuel of planes: Burning of fuels of planes emits large quantity of nitric oxide and other
gases in the atmosphere. Nitric oxide reacts with ozone and form nitrogen dioxide and
nitrogen trioxide. This causes depletion of ozone.
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