Barton Reaction - Competitive Examinations PDF Download

Barton Reaction - Competitive ExaminationsBarton Reaction - Competitive Examinations

Barton Reaction - Competitive Examinations

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FAQs on Barton Reaction - Competitive Examinations

1. What is the Barton reaction?
Ans. The Barton reaction is a chemical reaction named after its discoverer, Sir Derek Barton. It involves the conversion of a carbonyl compound, such as a ketone or aldehyde, into an alkene using a combination of a radical initiator and a reducing agent.
2. How does the Barton reaction work?
Ans. The Barton reaction involves the generation of a radical intermediate from the carbonyl compound. This is achieved by the action of a radical initiator, such as a peroxide or azo compound. The radical then reacts with a reducing agent, such as tributyltin hydride, to form an alkene product.
3. What are the applications of the Barton reaction?
Ans. The Barton reaction is widely used in organic synthesis for the preparation of various alkenes. It offers a mild and efficient method for the conversion of carbonyl compounds into valuable intermediates for the synthesis of complex organic molecules. It has found applications in the pharmaceutical and agrochemical industries.
4. Are there any limitations or challenges associated with the Barton reaction?
Ans. Yes, the Barton reaction has some limitations and challenges. It may not be applicable to all types of carbonyl compounds, and the reaction conditions need to be carefully optimized for each specific case. Additionally, the reaction can be sensitive to air and moisture, requiring rigorous exclusion of these factors during the reaction.
5. Can the Barton reaction be used in competitive examinations?
Ans. Yes, the Barton reaction is a topic that can be included in competitive examinations for chemistry or organic chemistry. It tests the understanding of radical reactions, carbonyl chemistry, and synthetic organic chemistry. Students may be asked to identify the reagents, products, mechanisms, or applications of the Barton reaction.
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