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Any object can be broadly classified in either of the following two categories on the basis of its electrical properties:
(i) Conductors
(ii) Insulators

Definition: Materials that allow electric charge (usually electrons) to move through them easily are called conductors. Metals such as copper, aluminium and iron are typical electrical conductors because they contain mobile (free) electrons.
In a conductor, some electrons are not bound to individual atoms but can move throughout the material. When an electric field is applied, these free electrons acquire an average velocity called drift velocity and produce an electric current.
The relation between current density and microscopic quantities is
J = nqvd
where J is current density, n is the number density of charge carriers, q is the charge of each carrier (for electrons q = -e) and vd is the drift velocity.
In many conductors under steady conditions the current density is proportional to the applied electric field:
J = σE
where σ is the electrical conductivity (SI unit S m-1). The reciprocal of conductivity is resistivity ρ, so ρ = 1/σ. For a uniform wire of length L and cross-sectional area A, the resistance is
R = ρ L / A
A simple microscopic model (Drude model) gives conductivity as
σ = ne²τ / m
where n is carrier density, e the electronic charge, m the electron mass and τ the mean time between collisions (relaxation time).
For metals, resistivity typically increases with temperature. Close to room temperature the dependence can be approximated by
ρ(T) ≈ ρ0[1 + α(T - T0)]
where α is the temperature coefficient of resistivity. For semiconductors and intrinsic insulators, conductivity increases strongly with temperature because thermal energy excites more charge carriers across the band gap.

Fig: Use of conductors in lighting a bulb

Fig: Insulators
Definition: Materials that do not allow free flow of electric charge under normal conditions are called insulators or dielectrics. In insulators electrons remain tightly bound to atoms; there are very few free charge carriers.
In band theory terms, an insulator has a completely filled valence band and a large energy gap to the conduction band (large band gap). Thermal excitation across this gap is negligible at ordinary temperatures, so electrical conductivity is extremely low. Typical insulators have band gaps of several electronvolts (eV).
When an electric field is applied to an insulator, bound charges shift slightly producing electric dipoles; this phenomenon is called polarisation. Polarisation leads to a reduction of the internal field and is quantified by the dielectric constant (relative permittivity) εr. Dielectrics are important in capacitors and insulating supports.
If the applied electric field exceeds a material-dependent critical value called the dielectric strength, the insulator may undergo electrical breakdown and start conducting (sparking or damaging the material). This is important for high-voltage design.

Fig: An insulator is used to protect wire opening
Electrical conductivity and thermal conductivity are related in metals (Wiedemann-Franz law) because electrons carry both charge and heat. However, a material may be a good electrical conductor but a poor thermal conductor or vice versa in non-metals. For example, diamond is an electrical insulator but an excellent thermal conductor.
Summary: Conductors permit easy flow of electric charge because of mobile carriers; they are described by conductivity, resistivity and microscopic carrier parameters. Insulators lack free carriers, exhibit polarisation as dielectrics and have a large band gap; they are essential for safety and device operation. Understanding their microscopic behaviour, temperature dependence and practical limitations is important for circuit design, high-voltage systems and many everyday applications.
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| 1. What is the difference between conductors and insulators? | ![]() |
| 2. Why are metals good conductors of electricity? | ![]() |
| 3. How does the conductivity of a material affect its use as a conductor or insulator? | ![]() |
| 4. What factors determine the conductivity of a material? | ![]() |
| 5. Can insulators conduct electricity under certain conditions? | ![]() |