Passage
The earth's atmosphere has several layers of gases with different characteristics and temperatures. The atmosphere has a total mass of 5 × 1018 kg, and is composed mainly of nitrogen, oxygen, argon, and carbon dioxide, as well as water vapor to a variable degree. Seventy-five percent of this mass is within 11 km from the earth's surface. Although the limit between outer space and the atmosphere is not definite, the Kármán Line, approximately 100 km above sea level, is often taken as the boundary
The five main layers of atmosphere are the exosphere, thermosphere, mesosphere, stratosphere, and troposphere. The troposphere is the innermost layer, and extends to approximately 6 km above the earth's surface at the poles and approximately 20 km above sea level at the equator. The next layer is the stratosphere. The ozone layer, which is considered to be a layer of its own because of its unique composition, is within the stratosphere. Approximately 90 percent of the O3 in the atmosphere is found in the ozone layer, although the actual concentrations are quite low (2-8 ppm). This layer is very important as it absorbs much of the ultraviolet (UV) light emitted from the sun. The mesosphere is the middle layer of the atmosphere with a temperature of approximately 100°C. The thermosphere and exosphere in that order are the outermost layers.
The pressure, density, and temperature of the atmosphere vary with altitude. Both pressure and density decrease with increasing altitude. At sea level, the density of air is 1.2 kg/m3 and drops by approximately 50 percent every 5.5 km.
The atmosphere contains greenhouse gases, which absorb and emit thermal infrared radiation, leading to the greenhouse effect. Greenhouse gases include water vapor, methane, nitrous oxide, carbon dioxide, and ozone. These gases are needed to maintain the temperature of the earth, which would otherwise be much colder. However, it is thought that an increase in the amount of greenhouse gases in the atmosphere has contributed to the increase in average temperature in the twentieth century. Methane is a very potent greenhouse gas. It can be oxidized in the atmosphere to produce carbon dioxide and water, with a half-life of 7 years.
Question for Practice Passage Test - 5
Try yourself:How long would it take for a 1 L sample of methane to decrease to 1 percent of its original amount from atmospheric oxidation?
Explanation
The passage states that the half-life of methane is 7 years. Starting with 100 percent and dividing by 2 for each half-life, six half-lives would leave 1.5 percent of the methane remaining, and seven half-lives would leave 0.8 percent of the methane remaining. Therefore, it would require 42 to 49 years, making answer choice C the correct answer.
Report a problem
Question for Practice Passage Test - 5
Try yourself:What is the partial pressure of nitrogen gas in the atmosphere at sea level?
Explanation
The pressure at sea level is 1 atm ≈ 100 kPa = 1 × 105 Pa. According to Table 1, nitrogen comprises approximately 80 percent of atmospheric air, thus the partial pressure of nitrogen at sea level is approximately (0.8)(1 × 105 Pa) = 8 × 104 Pa.
Report a problem
Question for Practice Passage Test - 5
Try yourself:The summit of Mount Everest is 8.8 km above sea level. What is the approximate density of air at this point?
Explanation
The passage states that the density of air is 1.2 kg/m3 and that the density drops by 50 percent every 5.5 km. Therefore, at 8.8 km, the density will be between 25 to 50 percent of the density at sea level, or 0.3–0.6 kg/m3. Choice B is the only answer in this range.
Report a problem
Question for Practice Passage Test - 5
Try yourself:A sample of gas containing oxygen, nitrogen, argon, and carbon dioxide in equal molar proportions is in a closed container. Which of these gases would escape the fastest if a small hole were punctured in the container?
Explanation
Since rate of effusion is inversely proportional to the square root of mass, the gas with the smallest mass will have the highest rate of effusion. Thus, N2 (28 g/mol) will escape fastest.
Report a problem
Question for Practice Passage Test - 5
Try yourself:All of the following are true regarding the earth’s atmosphere EXCEPT:
Explanation
The passage states that the limit between outer space and the atmosphere is not definite, so choice A is a true statement. The passage also states that the mass of the atmosphere is 5 × 1018 kg, and 75 percent of this (3.75 × 1018 kg) is 11 km from the surface of the earth. Therefore, choice C is also a true statement. Water vapor was listed as a greenhouse gas in the last paragraph, thus choice D is a true statement. Although the majority of ozone is located in the ozone layer, the passage states that concentrations of ozone are 2–8 ppm. To be the primary component, concentrations would have to exceed 500,000 ppm. Choice B is a false statement and therefore the correct answer.
Report a problem