Table of contents | |
Practical Applications of Capillarity | |
Capillary Rise (Height of a Liquid in a Capillary Tube) | |
Discussion | |
Capillary Rise in a Tube of Insufficient Length |
A glass tube with a very fine bore throughout its length is called a capillary tube. When a capillary tube is dipped in water, the water wets the inner side of the tube and rises inside it, as shown in figure (a). Conversely, if the same capillary tube is dipped in mercury, the mercury is depressed, as shown in figure (b). This phenomenon, where liquids rise or fall in a capillary tube, is known as capillarity.
Consider a liquid that wets the wall of the tube, forming a concave meniscus as shown in the figure. Let a capillary tube of radius r be dipped in a liquid with surface tension T and density ρ. Let h be the height the liquid rises in the tube. The excess pressure (p−pa) is given by:
where R is the radius of the meniscus. This excess pressure causes the liquid to rise in the capillary tube until it balances the hydrostatic pressure hρg. Thus, in equilibrium:
From triangle DOAC:
Therefore,
and
This expression is called the Ascent Formula.
(i) Wetting Liquids: For liquids that wet the glass tube, θ<90∘ and cosθ is positive, hence h is positive. These liquids rise in the capillary tube. Examples include water, milk, kerosene oil, and petrol.
(ii) Non-wetting Liquids: For liquids that do not wet the glass tube, θ>90∘ and cosθ is negative, hence h is negative. These liquids are depressed in the capillary tube, such as mercury.
(iii) Jurin’s Law: Since and g are constants, . Thus, the liquid rises more in a narrow tube and less in a wider tube.
(iv) Parallel Plates in Water: If two parallel plates with spacing d are placed in a water reservoir, the height of the rise h is:
(v) Concentric Tubes: If two concentric tubes of radii r1 and r2 (inner one solid) are placed in water, the height of the rise h is:
(vi) Considering Liquid Weight in Meniscus:
(vii) Meniscus Shape in Capillary Tube: When the capillary tube is vertical, the upper meniscus is concave, and the pressure due to surface tension is directed vertically upward.
(a) If , the lower meniscus is concave downward.
(b) If , the lower meniscus is convex upward. (c) If , the lower surface will be flat.
(viii) Liquid Between Two Plates: When a small drop of water is placed between two glass plates, it forms a thin film concave outward along its boundary.
The pressure inside the film is:
If (water and glass), the upper plate is pressed downward by:
The height to which a liquid rises in a capillary tube of radius r is given by the equation:
where:
When a capillary tube is cut and its length is less than the calculated height h (let's denote this shorter length as h′), the liquid rises to the top of the tube and spreads out, increasing the radius R′ of the liquid meniscus. The liquid does not overflow because the product hR remains constant. Therefore, constant.
Given that , it follows that , which implies , leading to , and hence .
Problem Statement: A 5 cm long capillary tube with an internal diameter of 0.1 mm, open at both ends, is dipped in water with a surface tension of 75 dyne/cm. Determine:
Solution: Given:
Using the formula for capillary rise height h:
cm
Since the capillary tube length is 5 cm:
The radius of curvature of the liquid meniscus adjusts such that R′h′=Rh:
R' = 0.0306 cm
Temperature: Surface tension decreases with an increase in temperature. According to Ferguson's formula:
where To is the surface tension at 0°C,
is the absolute temperature,
θc is the critical temperature, and is a constant (mean value 1.21).
Surface tension becomes zero at the critical temperature.
Impurities: The addition of impurities affects surface tension. Highly soluble substances like NaCl increase water's surface tension, while sparingly soluble substances like phenol and soap decrease it.
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1. How does capillarity affect the height of a liquid in a capillary tube? |
2. What factors affect the capillary rise in a tube of insufficient length? |
3. How is capillarity related to the mechanical properties of fluids? |
4. Can capillarity be used in practical applications beyond capillary rise in tubes? |
5. How can the concept of capillarity be tested or demonstrated in a laboratory setting? |
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