Chemical Bonding, NCERT Solutions, Class 11, Chemistry | Additional Study Material for Class 11 PDF Download

Question 4.1: Explain the formation of a chemical bond.

Ans:- A chemical bond is defined as an attractive force that holds the constituents (atoms, ions etc.) together in a chemical species.

Various theories have been suggested for the formation of chemical bonds such as the electronic theory, valence shell electron pair repulsion theory, valence bond theory, and molecular orbital theory.

A chemical bond formation is attributed to the tendency of a system to attain stability. It was observed that the inertness of noble gases was because of their fully filled outermost orbitals. Hence, it was postulated that the elements having incomplete outermost shells are unstable (reactive). Atoms, therefore, combine with each other and complete their respective octets or duplets to attain the stable configuration of the nearest noble gases. This combination can occur either by sharing of electrons or by transferring one or more electrons from one atom to another. The chemical bond formed as a result of sharing of electrons between atoms is called a covalent bond. An ionic bond is formed as a result of the transference of electrons from one atom to another.

Question 4.2: Write Lewis dot symbols for atoms of the following elements: Mg, Na, B, O, N, Br.

Question 4.3: Write Lewis symbols for the following atoms and ions:

S and S^2–; Al and Al³ ; H and H^–

Ans:- (i) S and S^2–

The number of valence electrons in sulphur is 6.

The Lewis dot symbol of sulphur (S) is

The dinegative charge infers that there will be two electrons more in addition to the six valence electrons. Hence, the Lewis dot symbol of S^2– is

(ii) Al and Al³

The number of valence electrons in aluminium is 3.

The Lewis dot symbol of aluminium (Al) is  

The tripositive charge on a species infers that it has donated its three electrons. Hence, the Lewis dot symbol is [Al]³

(iii) H and H^–

The number of valence electrons in hydrogen is 1.

The Lewis dot symbol of hydrogen (H) is 

The tripositive charge on a species infers that it has donated its three electrons. Hence, the Lewis dot symbol is [Al]³

(iii) H and H^–

The number of valence electrons in hydrogen is 1.

The Lewis dot symbol of hydrogen (H) is 

Question 4.4: Draw the Lewis structures for the following molecules and ions:

H₂S, SiCl₄, BeF_2,  , HCOOH

Question 4.5: Define octet rule. Write its significance and limitations.

Ans:- The octet rule or the electronic theory of chemical bonding was developed by Kossel and Lewis. According to this rule, atoms can combine either by transfer of valence electrons from one atom to another or by sharing their valence electrons in order to attain the nearest noble gas configuration by having an octet in their valence shell.

The octet rule successfully explained the formation of chemical bonds depending upon the nature of the element.

Limitations of the octet theory:

The following are the limitations of the octet rule:

(a) The rule failed to predict the shape and relative stability of molecules.

(b) It is based upon the inert nature of noble gases. However, some noble gases like xenon and krypton form compounds such as XeF₂, KrF₂ etc.

(c) The octet rule cannot be applied to the elements in and beyond the third period of the periodic table. The elements present in these periods have more than eight valence electrons around the central atom. For example: PF₅, SF_6, etc.

Question 4.6: Write the favourable factors for the formation of ionic bond.

Ans:- An ionic bond is formed by the transfer of one or more electrons from one atom to another. Hence, the formation of ionic bonds depends upon the ease with which neutral atoms can lose or gain electrons. Bond formation also depends upon the lattice energy of the compound formed.

Hence, favourable factors for ionic bond formation are as follows:

(i) Low ionization enthalpy of metal atom.

(ii) High electron gain enthalpy (Δ_eg H) of a non-metal atom.

(iii) High lattice energy of the compound formed.

Question 4.7: Discuss the shape of the following molecules using the VSEPR model:

BeCl₂, BCl₃, SiCl₄, AsF₅, H₂S, PH₃

Ans:- BeCl_2:

The central atom has no lone pair and there are five bond pairs. Hence, AsF₅ is of the type AB₅. Therefore, the shape is trigonal bipyramidal.

H₂S:

The central atom has one lone pair and there are two bond pairs. Hence, H₂S is of the type AB₂E. The shape is Bent.

PH_3:

The central atom has one lone pair and there are three bond pairs. Hence, PH₃ is of the AB₃E type. Therefore, the shape is trigonal bipyramidal.

Question 4.8: Although geometries of NH₃ and H₂O molecules are distorted tetrahedral, bond angle in water is less than that of ammonia. Discuss.

Ans:- The molecular geometry of NH₃ and H₂O can be shown as:

The central atom (N) in NH₃ has one lone pair and there are three bond pairs. In H₂O, there are two lone pairs and two bond pairs.

The two lone pairs present in the oxygen atom of H₂O molecule repels the two bond pairs. This repulsion is stronger than the repulsion between the lone pair and the three bond pairs on the nitrogen atom.

Since the repulsions on the bond pairs in H₂O molecule are greater than that in NH₃, the bond angle in water is less than that of ammonia.

Question 4.9: How do you express the bond strength in terms of bond order?

Ans:- Bond strength represents the extent of bonding between two atoms forming a molecule. The larger the bond energy, the stronger is the bond and the greater is the bond order.

Question 4.10: Define the bond length.

Ans:- Bond length is defined as the equilibrium distance between the nuclei of two bonded atoms in a molecule.

Bond lengths are expressed in terms of Angstrom (10^–10 m) or picometer

(10^–12 m) and are measured by spectroscopic X-ray diffractions and electron-diffraction techniques.

In an ionic compound, the bond length is the sum of the ionic radii of the constituting atoms (d = r r_–). In a covalent compound, it is the sum of their covalent radii (d = r_A r_B).

Question 4.11: Explain the important aspects of resonance with reference to the   ion

Ans : - According to experimental findings, all carbon to oxygen bonds in are equivalent. Hence, it is inadequate to represent

  ion by a single Lewis structure having two single bonds and one double bond.

Therefore, carbonate ion is described as a resonance hybrid of the following structures:

Ans:- The given structures cannot be taken as the canonical forms of the resonance hybrid of H₃PO₃ because the positions of the atoms have changed.

Question 4.13: Write the resonance structures for SO₃, NO₂ and 

Ans:- The resonance structures are:

Question 4.14: Use Lewis symbols to show electron transfer between the following atoms to form cations and anions: (a) K and S (b) Ca and O (c) Al and N.

Ans: -  (a) K and S:

The electronic configurations of K and S are as follows:

K: 2, 8, 8, 1

S: 2, 8, 6

Question 4.15: Although both CO₂ and H₂O are triatomic molecules, the shape of H₂O molecule is bent while that of CO₂ is linear. Explain this on the basis of dipole moment.

Ans:- According to experimental results, the dipole moment of carbon dioxide is zero. This is possible only if the molecule is linear so that the dipole moments of C–O bonds are equal and opposite to nullify each other.

Resultant μ = 0 D

H₂O, on the other hand, has a dipole moment value of 1.84 D (though it is a triatomic molecule as CO₂). The value of the dipole moment suggests that the structure of H₂O molecule is bent where the dipole moment of O–H bonds are unequal.

Question 4.16: Write the significance/applications of dipole moment.

Ans:- In heteronuclear molecules, polarization arises due to a difference in the electronegativities of the constituents of atoms. As a result, one end of the molecule acquires a positive charge while the other end becomes negative. Hence, a molecule is said to possess a dipole.

The product of the magnitude of the charge and the distance between the centres of positive-negative charges is called the dipole moment (μ) of the molecule. It is a vector quantity and is represented by an arrow with its tail at the positive centre and head pointing towards a negative centre.

Dipole moment (μ) = charge (Q) × distance of separation (r)

The SI unit of a dipole moment is ‘esu’.

1 esu = 3.335 × 10^–30 cm

Dipole moment is the measure of the polarity of a bond. It is used to differentiate between polar and non-polar bonds since all non-polar molecules (e.g. H₂, O₂) have zero dipole moments. It is also helpful in calculating the percentage ionic character of a molecule.

Question 4.17: Define electronegativity. How does it differ from electron gain enthalpy?

Ans:- Electronegativity is the ability of an atom in a chemical compound to attract a bond pair of electrons towards itself.

Electronegativity of any given element is not constant. It varies according to the element to which it is bound. It is not a measurable quantity. It is only a relative number.

On the other hand, electron gain enthalpy is the enthalpy change that takes place when an electron is added to a neutral gaseous atom to form an anion. It can be negative or positive depending upon whether the electron is added or removed. An element has a constant value of the electron gain enthalpy that can be measured experimentally.

Question 4.18: Explain with the help of suitable example polar covalent bond.

Ans:- When two dissimilar atoms having different electronegativities combine to form a covalent bond, the bond pair of electrons is not shared equally. The bond pair shifts towards the nucleus of the atom having greater electronegativity. As a result, electron distribution gets distorted and the electron cloud is displaced towards the electronegative atom.

As a result, the electronegative atom becomes slightly negatively charged while the other atom becomes slightly positively charged. Thus, opposite poles are developed in the molecule and this type of a bond is called a polar covalent bond.

HCl, for example, contains a polar covalent bond. Chlorine atom is more electronegative than hydrogen atom. Hence, the bond pair lies towards chlorine and therefore, it acquires a partial negative charge.

Question 4.19: Arrange the bonds in order of increasing ionic character in the molecules: LiF, K₂O, N₂, SO₂ & ClF₃

Ans:- The ionic character in a molecule is dependent upon the electronegativity difference between the constituting atoms. The greater the difference, the greater will be the ionic character of the molecule.

On this basis, the order of increasing ionic character in the given molecules is

N₂ < SO₂ < ClF₃ < K₂O < LiF.

Question 4.20: The skeletal structure of CH₃COOH as shown below is correct, but some of the bonds are shown incorrectly. Write the correct Lewis structure for acetic acid

Question 4.21: Apart from tetrahedral geometry, another possible geometry for CH₄ is square planar with the four H atoms at the corners of the square and the C atom at its centre. Explain why CH₄ is not square planar?

Ans:- Electronic configuration of carbon atom:

₆C: 1s² 2s² 2p²

In the excited state, the orbital picture of carbon can be represented as:

Hence, carbon atom undergoes sp³ hybridization in CH₄ molecule and takes a tetrahedral shape.

For a square planar shape, the hybridization of the central atom has to be dsp². However, an atom of carbon does not have d-orbitalsto undergo dsp² hybridization. Hence, the structure of CH₄ cannot be square planar.

Moreover, with a bond angle of 90° in square planar, the stability of CH₄ will be very less because of the repulsion existing between the bond pairs. Hence, VSEPR theory also supports a tetrahedral structure for CH₄.

Question 4.22: Explain why BeH₂ molecule has a zero dipole moment although the Be–H bonds are polar.

Ans:- The Lewis structure for BeH₂ is as follows:

There is no lone pair at the central atom (Be) and there are two bond pairs. Hence, BeH₂ is of the type AB₂. It has a linear structure

Dipole moments of each H–Be bond are equal and are in opposite directions. Therefore, they nullify each other. Hence, BeH₂ molecule has zero dipole moment.

Question 4.23: Which out of NH₃ and NF₃ has higher dipole moment and why?

Ans:- In both molecules i.e., NH₃ and NF₃, the central atom (N) has a lone pair electron and there are three bond pairs. Hence, both molecules have a pyramidal shape. Since fluorine is more electronegative than hydrogen, it is expected that the net dipole moment of NF₃ is greater than NH₃. However, the net dipole moment of NH₃ (1.46 D) is greater than that of NF₃ (0.24 D).

This can be explained on the basis of the directions of the dipole moments of each individual bond in NF₃ and NH₃. These directions can be shown as:

Thus, the resultant moment of the N–H bonds add up to the bond moment of the lone pair (the two being in the same direction), whereas that of the three N – F bonds partly cancels the moment of the lone pair.

Hence, the net dipole moment of NF₃ is less than that of NH₃.

Question 4.24: What is meant by hybridisation of atomic orbitals? Describe the shapes of sp, sp², sp³ hybrid orbitals.

Ans:- Hybridization is defined as an intermixing of a set of atomic orbitals of slightly different energies, thereby forming a new set of orbitals having equivalent energies and shapes.

For example, one 2s-orbital hybridizes with two 2p-orbitals of carbon to form three new sp² hybrid orbitals.

These hybrid orbitals have minimum repulsion between their electron pairs and thus, are more stable. Hybridization helps indicate the geometry of the molecule.

Shape of sp hybrid orbitals: sp hybrid orbitals have a linear shape. They are formed by the intermixing of s and p orbitals as:

Shape of sp³ hybrid orbitals:

Four sp³ hybrid orbitals are formed by intermixing one s-orbital with three p-orbitals. The four sp³ hybrid orbitals are arranged in the form of a tetrahedron as:

Hence, it undergoes sp² hybridization to give a trigonal planar arrangement (in AlCl₃).

To form AlCl₄^–, the empty 3p_z orbital also gets involved and the hybridization changes from sp² to sp³. As a result, the shape gets changed to tetrahedral.

Question 4.26: Is there any change in the hybridisation of B and N atoms as a result of the following reaction?

BF₃ NH₃ → F₃B.NH₃

Ans:- Boron atom in BF₃ is sp² hybridized. The orbital picture of boron in the excited state can be shown as:

After the reaction has occurred, an adduct F₃B⋅NH₃ is formed as hybridization of ‘B’ changes to sp³. However, the hybridization of ‘N’ remains

Question 4.27: Draw diagrams showing the formation of a double bond and a triple bond between carbon atoms in C₂H₄ and C₂H₂ molecules.

Ans:- C₂H₄ :

The electronic configuration of C-atom in the excited state is:

In the formation of an ethane molecule (C₂H₄), one sp² hybrid orbital of carbon overlaps a sp² hybridized orbital of another carbon atom, thereby forming a C-C sigma bond.

The remaining two sp² orbitals of each carbon atom form a sp²-s sigma bond with two hydrogen atoms. The unhybridized orbital of one carbon atom undergoes sidewise overlap with the orbital of a similar kind present on another carbon atom to form a weak π-bond.

C₂H₂ :

In the formation of C₂H₂ molecule, each C–atom is sp hybridized with two 2p-orbitals in an unhybridized state.

One sp orbital of each carbon atom overlaps with the other along the internuclear axis forming a C–C sigma bond. The second sp orbital of each C–atom overlaps a half-filled 1s-orbital to form a σ bond.

The two unhybridized 2p-orbitals of the first carbon undergo sidewise overlap with the 2p orbital of another carbon atom, thereby forming two pi (π) bonds between carbon atoms. Hence, the triple bond between two carbon atoms is made up of one sigma and two π-bonds.

Question 4.28: What is the total number of sigma and pi bonds in the following molecules?

(a) C₂H₂                                                               (b) C₂H₄

Ans:- A single bond is a result of the axial overlap of bonding orbitals. Hence, it contributes a sigma bond. A multiple bond (double or triple bond) is always formed as a result of the sidewise overlap of orbitals. A pi-bond is always present in it. A triple bond is a combination of two pi-bonds and one sigma bond.

Structure of C₂H₂ can be represented as:

Hence, there are five sigma bonds and one pi-bond in C₂H₄.

Question 4.29: Considering x-axis as the internuclear axis which out of the following will not form a sigma bond and why? (a) 1s and 1s (b) 1s and 2p_x (c) 2p_y and 2p_y (d) 1s and 2s.

Ans:- 2p_y and 2p_y orbitals will not a form a sigma bond. Taking x-axis as the internuclear axis, 2p_y and 2p_y orbitals will undergo lateral overlapping, thereby forming a pi (π) bond.

Question 4.30: Which hybrid orbitals are used by carbon atoms in the following molecules?

CH₃–CH₃; (b) CH₃–CH=CH₂; (c) CH₃-CH₂-OH; (d) CH₃-CHO (e) CH₃COOH

Ans:- (a)

Question 4.31: What do you understand by bond pairs and lone pairs of electrons? Illustrate by giving one example of each type.

Ans:- When two atoms combine by sharing their one or more valence electrons, a covalent bond is formed between them.

The shared pairs of electrons present between the bonded atoms are called bond pairs. All valence electrons may not participate in bonding. The electron pairs that do not participate in bonding are called lone pairs of electrons.

For example, in C₂H₆ (ethane), there are seven bond pairs but no lone pair present.

Question 4.32: Distinguish between a sigma and a pi bond.

Ans:- The following are the differences between sigma and pi-bonds:

Question 4.33: Explain the formation of H₂ molecule on the basis of valence bond theory.

Ans:- Let us assume that two hydrogen atoms (A and B) with nuclei (N_A and N_B) and electrons (e_A and e_B) are taken to undergo a reaction to form a hydrogen molecule.

When A and B are at a large distance, there is no interaction between them. As they begin to approach each other, the attractive and repulsive forces start operating.

Attractive force arises between:

(a) Nucleus of one atom and its own electron i.e., N_A – e_A and N_B – e_B.

(b) Nucleus of one atom and electron of another atom i.e., N_A – e_B and N_B – e_A.

Repulsive force arises between:

(a) Electrons of two atoms i.e., e_A – e_B.

(b) Nuclei of two atoms i.e., N_A – N_B.

The force of attraction brings the two atoms together, whereas the force of repulsion tends to push them apart.

The magnitude of the attractive forces is more than that of the repulsive forces. Hence, the two atoms approach each other. As a result, the potential energy decreases. Finally, a state is reached when the attractive forces balance the repulsive forces and the system acquires minimum energy. This leads to the formation of a dihydrogen molecule.

Question 4.34: Write the important conditions required for the linear combination of atomic orbitals to form molecular orbitals.

Ans:- The given conditions should be satisfied by atomic orbitals to form molecular orbitals:

(a) The combining atomic orbitals must have the same or nearly the same energy. This means that in a homonuclear molecule, the 1s-atomic orbital of an atom can combine with the 1s-atomic orbital of another atom, and not with the 2s-orbital.

(b) The combining atomic orbitals must have proper orientations to ensure that the overlap is maximum.

(c) The extent of overlapping should be large.

Question 4.35: Use molecular orbital theory to explain why the Be₂ molecule does not exist.

Ans:- The electronic configuration of Beryllium is.

The molecular orbital electronic configuration for Be₂ molecule can be written as:

Question 4.37: Write the significance of a plus and a minus sign shown in representing the orbitals.

Ans:- Molecular orbitals are represented by wave functions. A plus sign in an orbital indicates a positive wave function while a minus sign in an orbital represents a negative wave function.

Question 4.38: Describe the hybridisation in case of PCl₅. Why are the axial bonds longer as compared to equatorial bonds?

Ans:- The ground state and excited state outer electronic configurations of phosphorus (Z = 15) are:

Ground state:

There are five P–Cl sigma bonds in PCl₅. Three P–Cl bonds lie in one plane and make an angle of 120° with each other. These bonds are called equatorial bonds.

The remaining two P–Cl bonds lie above and below the equatorial plane and make an angle of 90° with the plane. These bonds are called axial bonds.

As the axial bond pairs suffer more repulsion from the equatorial bond pairs, axial bonds are slightly longer than equatorial bonds.

Question 4.39: Define hydrogen bond. Is it weaker or stronger than the van der Waals forces?

Ans:- A hydrogen bond is defined as an attractive force acting between the hydrogen attached to an electronegative atom of one molecule and an electronegative atom of a different molecule (may be of the same kind).

Due to a difference between electronegativities, the bond pair between hydrogen and the electronegative atom gets drifted far away from the hydrogen atom. As a result, a hydrogen atom becomes electropositive with respect to the other atom and acquires a positive charge.

The magnitude of H-bonding is maximum in the solid state and minimum in the gaseous state.

There are two types of H-bonds:

(i) Intermolecular H-bond e.g., HF, H₂O etc.

(ii) Intramolecular H-bond e.g., o-nitrophenol

Hydrogen bonds are stronger than Van der Walls forces since hydrogen bonds are regarded as an extreme form of dipole-dipole interaction.

Question 4.40: What is meant by the term bond order? Calculate the bond order of: N₂, O₂,  and 

Ans:- Bond order is defined as one half of the difference between the number of electrons present in the bonding and anti-bonding orbitals of a molecule.

If N_a is equal to the number of electrons in an anti-bonding orbital, then N_b is equal to the number of electrons in a bonding orbital.

Number of bonding electrons, N_b = 10

Number of anti-bonding electrons, N_a = 4

Thus, the bond order of   is 2.5