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31 Year NEET Previous Year Questions: Chemical Kinetics - NEET MCQ


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30 Questions MCQ Test - 31 Year NEET Previous Year Questions: Chemical Kinetics

31 Year NEET Previous Year Questions: Chemical Kinetics for NEET 2024 is part of NEET preparation. The 31 Year NEET Previous Year Questions: Chemical Kinetics questions and answers have been prepared according to the NEET exam syllabus.The 31 Year NEET Previous Year Questions: Chemical Kinetics MCQs are made for NEET 2024 Exam. Find important definitions, questions, notes, meanings, examples, exercises, MCQs and online tests for 31 Year NEET Previous Year Questions: Chemical Kinetics below.
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31 Year NEET Previous Year Questions: Chemical Kinetics - Question 1

Half life period of a first-order reaction is 1386 seconds. The specific rate constant of the reaction is: [2009]

Detailed Solution for 31 Year NEET Previous Year Questions: Chemical Kinetics - Question 1

For a first order reaction

31 Year NEET Previous Year Questions: Chemical Kinetics - Question 2

For the reaction A + B →  products, it is observed that: [2009]
(1) On doubling the initial concentration of A only, the rate of reaction is also doubled and
(2) On doubling the initial concentrations of both A and B, there is a change by a factor of 8 in the rate of the reaction.
The rate of this reaction is given by: 

Detailed Solution for 31 Year NEET Previous Year Questions: Chemical Kinetics - Question 2

When concentration A is doubled, rate is doubled. Hence order with respect to A is one.
When concentrations of both A and B are doubled, rate increases by 8 times hence order with respect to B is 2.
∴   rate = k [A]1 [B]2
Total order = 1 + 2 = 3

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31 Year NEET Previous Year Questions: Chemical Kinetics - Question 3

For the reaction the value of rate of disappearance of N2O5 is given as  6.25 × 10–3 mol L–1s–1. The rate of formation of NO2 and O2 is given respectively as : [2010]

Detailed Solution for 31 Year NEET Previous Year Questions: Chemical Kinetics - Question 3

31 Year NEET Previous Year Questions: Chemical Kinetics - Question 4

For an endothermic reaction, energy of activation is Ea and enthalpy of reaction of ΔH (both of these in kJ/mol). Minimum value of Ea will be. [2010]

Detailed Solution for 31 Year NEET Previous Year Questions: Chemical Kinetics - Question 4

Ea  >  ΔH

31 Year NEET Previous Year Questions: Chemical Kinetics - Question 5

During the kinetic study of the reaction, 2A + B → C + D, following results were obtained: 

Based on the above data which one of the following is correct? [2010]

Detailed Solution for 31 Year NEET Previous Year Questions: Chemical Kinetics - Question 5

31 Year NEET Previous Year Questions: Chemical Kinetics - Question 6

The rate of the reaction is given by the rate equation rate = k [NO]2 [Cl2]     [2010] The value of the rate constant can be increased by:

Detailed Solution for 31 Year NEET Previous Year Questions: Chemical Kinetics - Question 6

The value of rate constant can be increased by increasing the temperature.
∴ Correct choice : (b)

31 Year NEET Previous Year Questions: Chemical Kinetics - Question 7

Which one of the following statements for the order of a reaction is incorrect ? [2011]

Detailed Solution for 31 Year NEET Previous Year Questions: Chemical Kinetics - Question 7

order of reaction may be zero, whole number or fractional.

31 Year NEET Previous Year Questions: Chemical Kinetics - Question 8

For the reaction , the equilibrium constant is K1. The equilibrium constant is K2 for the reaction [2011] .What is K for the reaction

Detailed Solution for 31 Year NEET Previous Year Questions: Chemical Kinetics - Question 8

For the reaction

For the reaction

For the reaction

31 Year NEET Previous Year Questions: Chemical Kinetics - Question 9

The rate of the reaction can be written in three ways :

The relationship between k and k' and between k and k"are :

[2011 M]

Detailed Solution for 31 Year NEET Previous Year Questions: Chemical Kinetics - Question 9

Rate of disappearance of reactants = Rate of appearance of products

31 Year NEET Previous Year Questions: Chemical Kinetics - Question 10

The unit of rate constant for a zero order reaction is [2011 M]

Detailed Solution for 31 Year NEET Previous Year Questions: Chemical Kinetics - Question 10

Rate = K(A)0 Unit of K = mol L–1 sec–1

31 Year NEET Previous Year Questions: Chemical Kinetics - Question 11

In a reaction, A + B → Product, rate is doubled when the concentration of B is doubled, and rate increases by a factor of 8 when the concentrations of both the reactants (A and B) are doubled rate, law for the reaction can be written as : [2012]

Detailed Solution for 31 Year NEET Previous Year Questions: Chemical Kinetics - Question 11

According to statement given in the question, it is clear that r ∝ [A]2 and r ∝ [B]
That means order of reaction with respect to B is 1 and w.r.t A is 2
Hence, Rate = k[A]2[B]1

31 Year NEET Previous Year Questions: Chemical Kinetics - Question 12

In a zero-order reaction for every 10° rise of temperature, the rate is doubled. If the temperature is increased from 10°C to 100°C, the rate of the reaction will become : [2012]

Detailed Solution for 31 Year NEET Previous Year Questions: Chemical Kinetics - Question 12

*Multiple options can be correct
31 Year NEET Previous Year Questions: Chemical Kinetics - Question 13

Activation energy (Ea) and rate constants (k1 and k2) of a chemical reaction at two different temperatures (T1 and T2) are related by : [2012 M]

Detailed Solution for 31 Year NEET Previous Year Questions: Chemical Kinetics - Question 13

According to Arrhenius equation

31 Year NEET Previous Year Questions: Chemical Kinetics - Question 14

What is the activation energy for a reaction if its rate doubles when the temperature is raised from 20°C to 35°C? (R = 8.314 J mol–1 K–1) [NEET 2013]

Detailed Solution for 31 Year NEET Previous Year Questions: Chemical Kinetics - Question 14

= 34673 J mole-1
= 34.7 J mole-1

31 Year NEET Previous Year Questions: Chemical Kinetics - Question 15

A reaction having equal energies of activation for forward and reverse reaction has : [NEET 2013]

Detailed Solution for 31 Year NEET Previous Year Questions: Chemical Kinetics - Question 15

31 Year NEET Previous Year Questions: Chemical Kinetics - Question 16

A reaction is 50% completed in 2 hours and 75% completed in 4 hours. The order of reaction is     [NEET Kar. 2013]

Detailed Solution for 31 Year NEET Previous Year Questions: Chemical Kinetics - Question 16

For a first order reaction, t75% = 2 × t50%

31 Year NEET Previous Year Questions: Chemical Kinetics - Question 17

For a reaction between A and B the order with respect to A is 2 and the order with respect to B is 3. The concentrations of both A and B are doubled, the rate will increase by a factor of: [NEET Kar. 2013]

Detailed Solution for 31 Year NEET Previous Year Questions: Chemical Kinetics - Question 17

Rate = k[A]2[B]3 when concentrations of both A and B are doubled then rate = k[2A]2[2B]3 = 32 k[A]2[B]3
∴       rate will increase by a factor of 32.

31 Year NEET Previous Year Questions: Chemical Kinetics - Question 18

For an exothermic reaction, the energy of activation of the reactants is [1994]

Detailed Solution for 31 Year NEET Previous Year Questions: Chemical Kinetics - Question 18

 Ea(Forward) + ΔH = Ea(back word)
For Exothermic reaction, ΔH = –ve and
∴  activation energy of reactant is less than the energy of activation of products.

31 Year NEET Previous Year Questions: Chemical Kinetics - Question 19

A substance 'A' decomposes by a first or der reaction starting initially with [A] = 2.00 m and after 200 min, [A] becomes 0.15 m. For this reaction t1/2 is [1995]

Detailed Solution for 31 Year NEET Previous Year Questions: Chemical Kinetics - Question 19

Given initial concentration (a) = 2.00 m; Time taken (t) = 200 min and final concentration (a – x)    = 0.15 m. For a first order reation rate constant,

Further

31 Year NEET Previous Year Questions: Chemical Kinetics - Question 20

In a reaction, → Product, rate is doubled when the concentration of is doubled, and rate increases by a factor of 8 when the concentrations of both the reactants (and B) are doubled, rate law for the reaction can be written as 

Detailed Solution for 31 Year NEET Previous Year Questions: Chemical Kinetics - Question 20

 

31 Year NEET Previous Year Questions: Chemical Kinetics - Question 21

Activation energy of a chemical reaction can be determined by [1998]

Detailed Solution for 31 Year NEET Previous Year Questions: Chemical Kinetics - Question 21

We know that the activation energy of chemical reaction is given by formula

where k1 is the rate constant at temperature T1 and k2 is the rate constant at temperature T2 and Ea is the activation energy.  Therefore activation energy of chemical reaction is determined by evaluating rate constant at two different temperatures.

31 Year NEET Previous Year Questions: Chemical Kinetics - Question 22

In the following reaction , how is the rate of appearance of the underlined product related to the rate of disappearance of the underlined reactant ? [2000]

Detailed Solution for 31 Year NEET Previous Year Questions: Chemical Kinetics - Question 22

Rate of reaction

31 Year NEET Previous Year Questions: Chemical Kinetics - Question 23

When a biochemical reaction is carried out in laboratory in the absence of enzyme then rate of reaction obtained is 10–6 times, then activation energy of reaction in the presence of enzyme is

Detailed Solution for 31 Year NEET Previous Year Questions: Chemical Kinetics - Question 23

The presence of enzyme (catalyst) increases the speed of reaction by lowering the energy barrier, i.e. a new path is followed with lower activation energy.

Here ET is the threshold energy.
Ea and Ea1 is energy of activation of reaction in absence and presence of catalyst respectively.

31 Year NEET Previous Year Questions: Chemical Kinetics - Question 24

For the reaction rate and rate constant are 1.02 × 10–4 mol lit–1 sec–1 and 3.4 × 10–5 sec–1 respectively then concentration of N2O5 at that time will be [2001]

Detailed Solution for 31 Year NEET Previous Year Questions: Chemical Kinetics - Question 24

from the unit of rate constant it is clear that the reaction follow first order kinetics. Hence by rate law equation,    
 r = k [N2O5] where r = 1.02 × 10–4,
k = 3.4 × 10–5 1.02 × 10–4 = 3.4 × 10–5 [N2O5]
[N2O5] = 3M

31 Year NEET Previous Year Questions: Chemical Kinetics - Question 25

, rate of reaction    is equal to

Detailed Solution for 31 Year NEET Previous Year Questions: Chemical Kinetics - Question 25

Rate of appearance of B is equal to rate of disappearance of A.

31 Year NEET Previous Year Questions: Chemical Kinetics - Question 26

The temperature dependence of rate constant (k) of a chemical reaction is written in terms of Arrhenius equation, . Activation energy of the reaction can be calculated by plotting [2003]

Detailed Solution for 31 Year NEET Previous Year Questions: Chemical Kinetics - Question 26

k = Ae-Ea / Rt

Comparing the above equation with y = mx + c

Thus A plot of log10k vs 1/T should be a straight line, with slope equal to – Ea/2.303 RT and intercept equal to log A

or  Ea = –2.303R x Slope

31 Year NEET Previous Year Questions: Chemical Kinetics - Question 27

If the rate of the reaction is equal to the rate constant, the order of the reaction is [2003]

Detailed Solution for 31 Year NEET Previous Year Questions: Chemical Kinetics - Question 27

∵ r = k[A]n
if n = 0
r = k[A]0 or  r = k thus for zero order reactions rate is equal to the rate constant.

31 Year NEET Previous Year Questions: Chemical Kinetics - Question 28

For the reaction 2A + B → 3C + D which of the following does not express the reaction rate ? [2006]

Detailed Solution for 31 Year NEET Previous Year Questions: Chemical Kinetics - Question 28

In the given options  will not represent the reaction rate. It should not have –ve sign as it is product. since  show the rate of formation ofproduct C which will be positive.

31 Year NEET Previous Year Questions: Chemical Kinetics - Question 29

The reaction of hydrogenandiodine monochloride is given as: [2007]

The reaction is of first order with respect to H2(g) and ICI(g), following mechanisms were proposed.
Mechanism A:

Mechanism B:


Which of the above mechanism(s) can be consistent with the given information about the reaction?

Detailed Solution for 31 Year NEET Previous Year Questions: Chemical Kinetics - Question 29

As the slowest step is the rate determining step thus the mechanism B will be more consistent with the given information also because it involve one molecule of H2 and one molecule of  ICl it can expressed as r = k [H2][ICl] Which shows that the reaction is first order w.r.t. both H2 & ICl.

31 Year NEET Previous Year Questions: Chemical Kinetics - Question 30

The rate constants k1 and k2 for two different reactions are 1016 . e–2000/T and 1015 . e–1000/T, respectively. The temperature at which k1 = k2 is :

Detailed Solution for 31 Year NEET Previous Year Questions: Chemical Kinetics - Question 30

Given, 

when k1 and k2 are equal at any temperature T, we have

or 2.303 ×1×T=1000           [∴ log 10= 1]

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