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IIT JAM Chemistry - MCQ Test 2 - Chemistry MCQ


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30 Questions MCQ Test - IIT JAM Chemistry - MCQ Test 2

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IIT JAM Chemistry - MCQ Test 2 - Question 1

The order of decreasing energy among covalent bond (CB), dipole-dipole interaction (DDI) and London dispersion forces (LDF) is:

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IIT JAM Chemistry - MCQ Test 2 - Question 2

T50 (half-life period) of first order reaction is 10 min. Starting with 10 mol L-1, rate after 20 min is:

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IIT JAM Chemistry - MCQ Test 2 - Question 3

The set representing the correct order of ionic radius is:

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IIT JAM Chemistry - MCQ Test 2 - Question 4

Which of the following magnetic moment values will correspond to highest ionization energy form Mn species:

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IIT JAM Chemistry - MCQ Test 2 - Question 5

For the reaction   

Then relation between k1, k2 and k3 is 

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IIT JAM Chemistry - MCQ Test 2 - Question 6

Efficiency of Carnot’s engine is 100 % when

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IIT JAM Chemistry - MCQ Test 2 - Question 7

Arrange the following compounds in order of Ca—Cb bond length:

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IIT JAM Chemistry - MCQ Test 2 - Question 8

All the following are the resonance structure of one another except:

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IIT JAM Chemistry - MCQ Test 2 - Question 9

Bombardment of aluminium by α-particle leads to its artificial disintegration in two ways (i) and (ii) as shown. Product X, Y and Z respectively are:

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IIT JAM Chemistry - MCQ Test 2 - Question 10

Heat of dissociation of CH3COOH is 0.005 kcal g-1, hence enthalpy change when 1 mole of Ca(OH)is completely neutralized by CH3COOH is:

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IIT JAM Chemistry - MCQ Test 2 - Question 11

The heat released on neutralization of CsOH with all strong acids is 13.4 kcal mol-1. The heat released on neutralization of CsOH with HF (weak acid) is 16.4 kcal mol-1. ΔH° of ionization of HF in water is:

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IIT JAM Chemistry - MCQ Test 2 - Question 12

At low pressure, that Vander Waal’s equation is reduced to:

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IIT JAM Chemistry - MCQ Test 2 - Question 13

Correct order of stability of the following carbocation is:

Detailed Solution for IIT JAM Chemistry - MCQ Test 2 - Question 13

At metaposition, hyperconjugation do not take place. 

Inductive effect order −H<−D i.e R−CH3​<R−CD3 (Stability)

Hyperconjugation order −H<−D i.e R−CH3>R−CD3​ (Stability)

and Hyperconjugated compound is always more stable than inductive effect.

Therefore, Order is I>II>IV>III

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IIT JAM Chemistry - MCQ Test 2 - Question 14

The decay modes of 14C and 14O are:

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IIT JAM Chemistry - MCQ Test 2 - Question 15

If 3/4 quantity of a radioactive element disintegrates in two hours its half- life would be:

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IIT JAM Chemistry - MCQ Test 2 - Question 16

What is the stereochemical relationship between the following compound:

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IIT JAM Chemistry - MCQ Test 2 - Question 17

Among the structures given below, the most stable conformation for the following compound is:

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IIT JAM Chemistry - MCQ Test 2 - Question 18

Following configuration of the tartaric acid represents:

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IIT JAM Chemistry - MCQ Test 2 - Question 19

The gauche conformation (θ = 60°) of n-butane possess:

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IIT JAM Chemistry - MCQ Test 2 - Question 20

Rate of formation of SO3 in the following reaction

is 100g min-1. Hence, rate of disappearance of O2 is:

Detailed Solution for IIT JAM Chemistry - MCQ Test 2 - Question 20

Rate of a reaction is defined as the rate of change of concentration per unit time.

The rate in terms of reactants is given as negative as the concentration of reactants is decreasing with time whereas the rate in terms of products is given as positive as the concentration of products is increasing with time.

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IIT JAM Chemistry - MCQ Test 2 - Question 21

Any gas shows maximum deviation from ideal gas at:

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IIT JAM Chemistry - MCQ Test 2 - Question 22

The de-Broglie wavelength of the electron in the ground state of hydrogen atom is ? Given: KE = 13.6 eV, 1 eV = 1.6*10 -19J.

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IIT JAM Chemistry - MCQ Test 2 - Question 23

For a first order homogenous gaseous reaction, then initial pressure was P, while total pressure after time ‘t’ was Pt. The write expression for the rate constants k in terms of Pi, Pt and t is:

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IIT JAM Chemistry - MCQ Test 2 - Question 24

In which of the following reactions, hydrogen peroxide acts as on oxidizing agent:

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IIT JAM Chemistry - MCQ Test 2 - Question 25

Heat of neutralization of H2C2O4 (oxalic acid) is - 2 6 kcal mol-1. Hence dissociation energy of:

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IIT JAM Chemistry - MCQ Test 2 - Question 26

Which is the correct order of dipole moments of the compounds:

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IIT JAM Chemistry - MCQ Test 2 - Question 27

Which carbocation is the most stabilized:

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IIT JAM Chemistry - MCQ Test 2 - Question 28

Nodal plane in the π bond is located in:

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IIT JAM Chemistry - MCQ Test 2 - Question 29

The correct order of increasing bond angles in the following triatomic species  

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IIT JAM Chemistry - MCQ Test 2 - Question 30

The schrodinger wave equation for hydrogen atom is:

where ao is Bohr radius. Find position of radial node.

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