Alcohols MCQ - 1 (Advanced) - JEE MCQ

A water soluble C₆H₁₄O₂ compound is oxidized by lead tetraacetate (or periodic acid) to a single C₃H₆O carbonyl compound. Which of the following would satisfy this fact ?

A racemic mixture of (±) 2-phenyl propanoic acid on esterificaton with (+) 2-butanol gives two esters. Mention the sterochemistry of two esters formed -

Compound which gives alcohol on reduction is/are (When reacts with LiAH₄)

Which of following compound undergo acidic hydrolysis.

Which of the following alcohol can not be oxidized by KMnO₄ :

Which of the following reaction esterification ?

Identify X, Y, Z :

Which is/are corect statement ?

3-methyl-3-hexanol can be prepared by -

 (X)

 (Y) 

Identify the product X and Y.

Aldehydes and ketones react with oine molecule of analcohol to form compounds called hemiacetals, in which there is one hydroyl group and one either-like group. Reaction of a hemiacetal with a second molecule of alcohol gives an acetal and a molecule of water. We study this reaction

Draw structural formulas for the hemicetal and acetal formed from these reagents. The stoichiometry of each reaction is given in the problem.

(A) 
 (B) 
(C) 

Q. 

Product P is -

Aldehydes and ketones react with oine molecule of analcohol to form compounds called hemiacetals, in which there is one hydroyl group and one either-like group. Reaction of a hemiacetal with a second molecule of alcohol gives an acetal and a molecule of water. We study this reaction

Draw structural formulas for the hemicetal and acetal formed from these reagents. The stoichiometry of each reaction is given in the problem.

(A) 
 (B) 
(C) 

Q.

Product Q is -

Aldehydes and ketones react with oine molecule of analcohol to form compounds called hemiacetals, in which there is one hydroyl group and one either-like group. Reaction of a hemiacetal with a second molecule of alcohol gives an acetal and a molecule of water. We study this reaction

Draw structural formulas for the hemicetal and acetal formed from these reagents. The stoichiometry of each reaction is given in the problem.

(A) 
 (B) 
(C) 

Q.

 Product R is -

Which can be cleaved by HIO₄ ?

Benzenediazonium chloride on reaction with phenol in weakly basic medium gives

Match the following X, yZ (C₅H₁₂O) are isomeric alcohols on oxidation `X' gives a given, Y gives acid and Z is not oxidised X gives positive  test. The activity order with HBr is Z > X > Y.

1-propanol & 2-propanol can be best distinguished by -

Identify the correct order of boiling point of the following compounds :

[JEE 2002]

 Product formed by P & Q can be differentiated by:

Reactn of entainomerically pure acid with 1 chiral carbon and racemic alcohol with 1 chiral carbon gives an ester which is -