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Chemistry - 2019 Past Year Paper - IIT JAM MCQ


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30 Questions MCQ Test - Chemistry - 2019 Past Year Paper

Chemistry - 2019 Past Year Paper for IIT JAM 2024 is part of IIT JAM preparation. The Chemistry - 2019 Past Year Paper questions and answers have been prepared according to the IIT JAM exam syllabus.The Chemistry - 2019 Past Year Paper MCQs are made for IIT JAM 2024 Exam. Find important definitions, questions, notes, meanings, examples, exercises, MCQs and online tests for Chemistry - 2019 Past Year Paper below.
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Chemistry - 2019 Past Year Paper - Question 1

For a reaction of the type A + B → Products, the unit of the rate constant is mol L–1 s–1. The overall order of the reaction is ______.

Detailed Solution for Chemistry - 2019 Past Year Paper - Question 1

Unit of k = (mole/L)1-n s-1
On Substituting, n=0
⇒ The unit of k = mol L–1 s–1
i.e. same as given.

Thus, the given reaction is a zero-order reaction or the overall order of the reaction is 0.

Chemistry - 2019 Past Year Paper - Question 2

The thermodynamic criterion for spontaneity of a process in a system under constant volume and temperature and in the absence of any work other than expansion work (if any) is:

Detailed Solution for Chemistry - 2019 Past Year Paper - Question 2

 

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Chemistry - 2019 Past Year Paper - Question 3

The number of vibrational mode(s) of a carbon dioxide molecule that can be detected using infrared spectroscopy is ______.

Detailed Solution for Chemistry - 2019 Past Year Paper - Question 3
  • CO2 molecule is linear so its vibrational degree of freedom is (3n - 5)
    = (3 * 3 - 5) = 4 
  • 1 is symmetrical stretching means IR inactive and 3 is (symmetrical +bending) means IR active.
  • Hence, the number of vibrational mode(s) of a carbon dioxide molecule that can be detected using infrared spectroscopy is 3.
Chemistry - 2019 Past Year Paper - Question 4

For three non-coplanar vectors a, b and c, the expression a ∙ (b × c) can be written as:

Detailed Solution for Chemistry - 2019 Past Year Paper - Question 4

(b×c) =b. (c×a) =-c.(a×b)=(a×b).c

So, (A) is the correct option.

Chemistry - 2019 Past Year Paper - Question 5

The correct trend in the bond order is:

Detailed Solution for Chemistry - 2019 Past Year Paper - Question 5

Bond order for the following:
(i) O2​ = 1.5
(ii) O2+​ = 2.5
(iii) O22- = 1

The correct trend will be:

Chemistry - 2019 Past Year Paper - Question 6

The correct option for the metal ion present in the active site of myoglobin, hemocyanin, and vitamin B12, respectively, are:

Detailed Solution for Chemistry - 2019 Past Year Paper - Question 6

Chemistry - 2019 Past Year Paper - Question 7

The correct order of wavelength (λmax) of the halide to metal charge-transfer band of [Co(NH3)5Cl]2+ (I), [Co(NH3)5Br]2+ (II) and [Co(NH3)5I]2+ (III), is

Detailed Solution for Chemistry - 2019 Past Year Paper - Question 7
  • Down the group, Electronegativity decreases from Cl to I.
  • So, in III less energy is required for the electron in Iodine to transfer, than that of Chlorine.
  • As energy decreases, wavelength(λmax) increases from Cl to I.
Chemistry - 2019 Past Year Paper - Question 8

The correct option for the major products of the following reaction is

Detailed Solution for Chemistry - 2019 Past Year Paper - Question 8

This is the reaction named by favorskii rearrangement in which base abstracts the proton from left carbon of carbonyl group and withdraws the leaving group Cl by rearrangement and makes ester.

Chemistry - 2019 Past Year Paper - Question 9

The major product formed in the following reaction is

Chemistry - 2019 Past Year Paper - Question 10

The complementary strand for the following single strand of DNA is:

Detailed Solution for Chemistry - 2019 Past Year Paper - Question 10
  • In DNA, Adenine (A) pairs with Thymine (T) and Guanine (G) pairs with Cytosine (C).
  • Hence, on replication of DNA in M phase, complementary nucleotides for each base pair will be added as follows:
    (i) A - T
    (ii) T - A
    (iii) G - C
    (iv) C - G
  • Since replication occurs in 5'-3' direction, so the complementary strand will be formed in 3'-5' direction.
  • Hence the sequence of complementary strand formed upon replication will be:
Chemistry - 2019 Past Year Paper - Question 11

The function f(x) x e-x2 has a minimum at

Chemistry - 2019 Past Year Paper - Question 12

The correct option for the number of bending modes of vibration in each of H2O, CS2 and SO2 molecules, respectively, is

Chemistry - 2019 Past Year Paper - Question 13

The total number of degrees of freedom of an HBr molecule that is constrained to translate along a straight line but does not have any constraints for its rotation and vibration is:

Detailed Solution for Chemistry - 2019 Past Year Paper - Question 13
  • The total degree of freedom of a molecule is 3N where N refers to its atomicity.
  • Ideally, it should be 6 (∵ HBr is a diatomic linear molecule).
  • But it is constrained to move along a straight line (i.e. assuming that it can move only along one axis).
  • Therefore, the total translational degree of freedom would be 1.
  • Hence, overall it would be 4.
Chemistry - 2019 Past Year Paper - Question 14

According to the kinetic theory of gases, the ratio of the root mean square velocity of molecular oxygen and molecular hydrogen at 300 K is:

Detailed Solution for Chemistry - 2019 Past Year Paper - Question 14

Vrmsoxygen/Vrmshydrogen = √Mhydrogen/√Moxygen
∵ Vrms is inversely proportional to the molar mass

Vrmsoxygen/Vrmshydrogen = √1/√16 = 1/4

Chemistry - 2019 Past Year Paper - Question 15

The half-life of the chemical reaction, A → Product, for initial reactant concentrations of 0.1 and 0.4 mol L–1 are 200 and 50 s, respectively. The order of the reaction is:

Detailed Solution for Chemistry - 2019 Past Year Paper - Question 15

Chemistry - 2019 Past Year Paper - Question 16

The ratio of the nearest neighbor atomic distances in body-centered cubic (bcc) and facecentered cubic (fcc) crystals with the same unit cell edge length is

Detailed Solution for Chemistry - 2019 Past Year Paper - Question 16
  • In BCC, the nearest atom from one corner is at the body center, at a distance of √(3a/2).
  • In FCC, the nearest atom from one corner is at the face center at a distance of √(2a/2).
  • The ratio would be √(3/2).
Chemistry - 2019 Past Year Paper - Question 17

The correct trend in the rate of substitution of Cl- by pyridine in the following complexes is

Chemistry - 2019 Past Year Paper - Question 18

In the qualitative inorganic analysis of metal ions, the ion which precipitates as sulfide in the presence of H2S in warm dilute HCl is:

Detailed Solution for Chemistry - 2019 Past Year Paper - Question 18
  • Group II → Bi3+
    Group III A → Al3+, Cr3+
    Group III B → Co2+
  • Second group cations are precipitated as sulphides because of their low solubility products whereas sulphides of other metals remain in solution because of their high solubility products.
  • HCl acts as a source of H+ which decrease the concentration of S2− ion that exceeds only the solubility products of the metal sulphide of the IInd group.
Chemistry - 2019 Past Year Paper - Question 19

The correct statement regarding the observed magnetic properties of NO, O2, B2, and C2 in their ground state is:

Detailed Solution for Chemistry - 2019 Past Year Paper - Question 19
  • In B2, there are two unpaired electrons in the π bonding orbital.
  • In O2, there are also two π electrons in antibonding orbitals.
  • In NO, there is one unpaired electron in π* antibonding orbital
  • Since the paramagnetic nature is based on the presence of unpaired electrons.
  • Thus, B2, O2, and NO are paramagnetic.
Chemistry - 2019 Past Year Paper - Question 20

The observed magnetic moments of octahedral Mn3+, Fe3+ and Co3+ complexes are 4.95, 6.06 and 0.00 BM, respectively. The correct option for the electronic configuration of Mn3+, Fe3+ and Co3+ metal ions in these complexes, respectively, is

Chemistry - 2019 Past Year Paper - Question 21

Among the following compounds, the one having the lowest boiling point is

Chemistry - 2019 Past Year Paper - Question 22

The correct option having one complex from each of the following pairs which is more reactive towards the oxidative addition reaction by hydrogen molecule is
Pair 1: IrCl(PMe3)3 (I) and IrCl(CO)(PMe3)2 (II)
Pair 2: IrCl(CO)(PPh3)2 (III) and IrCl3(PPh3) (IV)

Detailed Solution for Chemistry - 2019 Past Year Paper - Question 22

Chemistry - 2019 Past Year Paper - Question 23

Among the following, the correct statement is

Chemistry - 2019 Past Year Paper - Question 24

The major product of the following reaction is:

Chemistry - 2019 Past Year Paper - Question 25

In 1H NMR spectrum of the given molecule, the correct order of chemical shifts of the labelled protons (HX, HY, HZ) is

Chemistry - 2019 Past Year Paper - Question 26

In the following reaction of (D)-Glucose, a product P is formed.
Among the following compounds, the one which will give the same product (P) under identical reaction conditions is

Chemistry - 2019 Past Year Paper - Question 27

The major product of the following reaction is

Chemistry - 2019 Past Year Paper - Question 28

The correct option for the product(s) of the following reaction is

Chemistry - 2019 Past Year Paper - Question 29

The increasing order of acidity of the given molecules in aqueous media is:

 

Detailed Solution for Chemistry - 2019 Past Year Paper - Question 29

Chemistry - 2019 Past Year Paper - Question 30

The compound formed upon subjecting an aliphatic amine to Lassaigne’s test is

Detailed Solution for Chemistry - 2019 Past Year Paper - Question 30

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