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Test: Voltammetry, Polarography & Chromatography - Chemistry MCQ


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10 Questions MCQ Test - Test: Voltammetry, Polarography & Chromatography

Test: Voltammetry, Polarography & Chromatography for Chemistry 2024 is part of Chemistry preparation. The Test: Voltammetry, Polarography & Chromatography questions and answers have been prepared according to the Chemistry exam syllabus.The Test: Voltammetry, Polarography & Chromatography MCQs are made for Chemistry 2024 Exam. Find important definitions, questions, notes, meanings, examples, exercises, MCQs and online tests for Test: Voltammetry, Polarography & Chromatography below.
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Test: Voltammetry, Polarography & Chromatography - Question 1

What is the primary purpose of using voltammetry in chemical analysis?

Detailed Solution for Test: Voltammetry, Polarography & Chromatography - Question 1
Voltammetry is primarily used to determine the concentration of an analyte through electrochemical reactions. It measures the current response as a function of the applied potential, allowing for both qualitative and quantitative analysis of various chemical substances.
Test: Voltammetry, Polarography & Chromatography - Question 2

In classic polarography, which electrode is typically made of mercury and serves as the site for the electrochemical reaction with the analyte?

Detailed Solution for Test: Voltammetry, Polarography & Chromatography - Question 2
In classic polarography, the indicator electrode is typically made of mercury and serves as the site for the electrochemical reaction with the analyte.
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Test: Voltammetry, Polarography & Chromatography - Question 3

In AC voltammetry, which aspect of electrochemical reactions is particularly studied?

Detailed Solution for Test: Voltammetry, Polarography & Chromatography - Question 3
AC voltammetry is particularly useful for studying the extent to which electrochemical reactions are reversible, focusing on the reversibility of reactions in the forward and reverse directions.
Test: Voltammetry, Polarography & Chromatography - Question 4
What is the fundamental difference between coulometry and electrogravimetry?
Detailed Solution for Test: Voltammetry, Polarography & Chromatography - Question 4
The fundamental difference is that coulometry measures the total charge (coulombs) required for a reaction, whereas electrogravimetry measures the change in mass of the electrode due to the reaction product.
Test: Voltammetry, Polarography & Chromatography - Question 5
What is the primary purpose of using triangular wave voltammetry (TWV) compared to other voltammetric methods?
Detailed Solution for Test: Voltammetry, Polarography & Chromatography - Question 5
Triangular wave voltammetry (TWV) is used to reduce interference in the electrochemical reaction by providing forward and reverse scans, which can help distinguish between reactions and improve the accuracy of analysis.
Test: Voltammetry, Polarography & Chromatography - Question 6
What is the main difference between pulse voltammetry and differential pulse voltammetry?
Detailed Solution for Test: Voltammetry, Polarography & Chromatography - Question 6
The main difference is that in pulse voltammetry, current is measured only at the beginning of the pulse, whereas in differential pulse voltammetry, it is measured at the end of the pulse. This difference allows for improved sensitivity in differential pulse voltammetry.
Test: Voltammetry, Polarography & Chromatography - Question 7
In amperometry, what property of the analyte is typically measured and related to its concentration?
Detailed Solution for Test: Voltammetry, Polarography & Chromatography - Question 7
In amperometry, the current that flows between the indicator electrode and a second electrode in the solution is typically measured and related to the concentration of the analyte.
Test: Voltammetry, Polarography & Chromatography - Question 8
In potentiometry, what type of electrode is used to reflect the potential of the bulk solution into which it is dipped?
Detailed Solution for Test: Voltammetry, Polarography & Chromatography - Question 8
An inert-indicator electrode is used in potentiometry to reflect the potential of the bulk solution into which it is dipped, without responding to specific ions.
Test: Voltammetry, Polarography & Chromatography - Question 9
What is the primary advantage of ion-selective electrodes over inert-indicator electrodes in potentiometry?
Detailed Solution for Test: Voltammetry, Polarography & Chromatography - Question 9
The primary advantage of ion-selective electrodes is that they can selectively respond to specific ions in the solution, making them highly selective for particular analytes.
Test: Voltammetry, Polarography & Chromatography - Question 10
What does mass spectrometry primarily rely on to separate ions or ionic fragments?
Detailed Solution for Test: Voltammetry, Polarography & Chromatography - Question 10
Mass spectrometry primarily relies on magnetic fields to separate ions or ionic fragments based on their mass-to-charge ratios (m/z). Magnetic fields alter the paths of ions, allowing for mass separation.
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