Which of the following is a tertiary amine?

N – ethyl – 1 – propanamine

For producing amines, the reaction of nitro compounds with iron scrap is preferred because

HCl is formed on hydrolysis of FeCl 2

Not too much HCl is formed in the reaction

Nitro compounds are easily available

Direct nitration of aniline yields significant amount of meta derivative. To obtain more p – nitro derivative, one or more of the below can be done

controlling the nitration reaction

Quaternary ammonium salt is formed

by serial nucleophilic substitution of the product

By treating an alkyl or benzyl halide with ammonia

By nucleophilic substitution reaction

Sec – Butylamine is the common name of what compound?

N – methyl – 1 – propanamine

Aniline does not undergo Friedel – Crafts reaction

Anilium ion deactivates any further reaction.

aluminium chloride, the catalyst reacts with NH 2 group

nitrogen of aniline acquires positive charge

Arrange the following in order of increasing basicity: aniline, p – nitroaniline, p – toluidine,and p – methoxyaniline

p – methoxyaniline p – nitroaniline < aniline < p – toluidine

p – nitroaniline < aniline < p – toluidine < p – methoxyaniline

aniline < p – methoxyaniline p – nitroaniline < p – toluidine

p – nitroaniline < aniline< p – methoxyaniline < p – toluidine

Aniline does not undergo Friedel – Crafts reaction

Anilium ion deactivates any further reaction.

aluminium chloride, the catalyst reacts with NH 2 group

nitrogen of aniline acquires positive charge

Hinsberg’s reagent reacts with primary and secondary amines to form sulphonamides. This reagent is also known as

p – toluenesulphonyl chloride

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