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Gaseous State MCQ - 2 (Advanced) - JEE MCQ


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15 Questions MCQ Test - Gaseous State MCQ - 2 (Advanced)

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Gaseous State MCQ - 2 (Advanced) - Question 1

In the Figure, isotherms of CO2 at several temperatures near the critical point are shown. At the critical point (critical state), the distinction between the liquid and gaseous states disappear and the density of the gaseous substance is equal to that in the liquid state. For every gas this occurs at specific values of temperature and pressure, called critical temperature and critical pressure respectively. At temperatures and pressures above the critical point value, a gas is said be in a supercritical state. Critical constants are evaluated by solving the Vander W aals equation which is a cubic in volume. The values are Tc 

In the supercritical region the behaviour is studied by plotting Z vs P plots. The variation in this region is studied with respect to boyles temperature a

At temperature 
higher than CB the variation is linear (Plot I) and at temperature lower than CB the variation is non linear (Plot II) With reference to the passage answers the following questions:

Q.

Which statement(s) about the behaviour of a real gas is/are wrong?

Gaseous State MCQ - 2 (Advanced) - Question 2

In the Figure, isotherms of CO2 at several temperatures near the critical point are shown. At the critical point (critical state), the distinction between the liquid and gaseous states disappear and the density of the gaseous substance is equal to that in the liquid state. For every gas this occurs at specific values of temperature and pressure, called critical temperature and critical pressure respectively. At temperatures and pressures above the critical point value, a gas is said be in a supercritical state. Critical constants are evaluated by solving the Vander W aals equation which is a cubic in volume. The values are Tc 

In the supercritical region the behaviour is studied by plotting Z vs P plots. The variation in this region is studied with respect to boyles temperature a

At temperature 
higher than CB the variation is linear (Plot I) and at temperature lower than CB the variation is non linear (Plot II) With reference to the passage answers the following questions:

Q.

The figure shows the effect of pressure on the compressibility factor, Z of a gas :The wrong conclusion(s) is/are:

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Gaseous State MCQ - 2 (Advanced) - Question 3

In the Figure, isotherms of CO2 at several temperatures near the critical point are shown. At the critical point (critical state), the distinction between the liquid and gaseous states disappear and the density of the gaseous substance is equal to that in the liquid state. For every gas this occurs at specific values of temperature and pressure, called critical temperature and critical pressure respectively. At temperatures and pressures above the critical point value, a gas is said be in a supercritical state. Critical constants are evaluated by solving the Vander W aals equation which is a cubic in volume. The values are Tc 

In the supercritical region the behaviour is studied by plotting Z vs P plots. The variation in this region is studied with respect to boyles temperature a

At temperature 
higher than CB the variation is linear (Plot I) and at temperature lower than CB the variation is non linear (Plot II) With reference to the passage answers the following questions:

Q.

Two vandaer waals gases have same value of 'a' but different value of b which of the following statement is correct.

Gaseous State MCQ - 2 (Advanced) - Question 4

In the Figure, isotherms of CO2 at several temperatures near the critical point are shown. At the critical point (critical state), the distinction between the liquid and gaseous states disappear and the density of the gaseous substance is equal to that in the liquid state. For every gas this occurs at specific values of temperature and pressure, called critical temperature and critical pressure respectively. At temperatures and pressures above the critical point value, a gas is said be in a supercritical state. Critical constants are evaluated by solving the Vander W aals equation which is a cubic in volume. The values are Tc 

In the supercritical region the behaviour is studied by plotting Z vs P plots. The variation in this region is studied with respect to boyles temperature a

At temperature 
higher than CB the variation is linear (Plot I) and at temperature lower than CB the variation is non linear (Plot II) With reference to the passage answers the following questions:

Q.

Two Vander waals gases have same value 'b' but different 'a' value then which of the following statement is correct under similar condition.

Gaseous State MCQ - 2 (Advanced) - Question 5

In the Figure, isotherms of CO2 at several temperatures near the critical point are shown. At the critical point (critical state), the distinction between the liquid and gaseous states disappear and the density of the gaseous substance is equal to that in the liquid state. For every gas this occurs at specific values of temperature and pressure, called critical temperature and critical pressure respectively. At temperatures and pressures above the critical point value, a gas is said be in a supercritical state. Critical constants are evaluated by solving the Vander W aals equation which is a cubic in volume. The values are Tc 

In the supercritical region the behaviour is studied by plotting Z vs P plots. The variation in this region is studied with respect to boyles temperature a

At temperature 
higher than CB the variation is linear (Plot I) and at temperature lower than CB the variation is non linear (Plot II) With reference to the passage answers the following questions:

Q.

From the given plot between z and P for a real gas the correct is:

Gaseous State MCQ - 2 (Advanced) - Question 6

In the Figure, isotherms of CO2 at several temperatures near the critical point are shown. At the critical point (critical state), the distinction between the liquid and gaseous states disappear and the density of the gaseous substance is equal to that in the liquid state. For every gas this occurs at specific values of temperature and pressure, called critical temperature and critical pressure respectively. At temperatures and pressures above the critical point value, a gas is said be in a supercritical state. Critical constants are evaluated by solving the Vander W aals equation which is a cubic in volume. The values are Tc 

In the supercritical region the behaviour is studied by plotting Z vs P plots. The variation in this region is studied with respect to boyles temperature a

At temperature 
higher than CB the variation is linear (Plot I) and at temperature lower than CB the variation is non linear (Plot II) With reference to the passage answers the following questions:

Q.

A gas can be condensed to liquid through the paths I, II, and Ill, as shown in figure. The path(s) through which the gas changes to liquid abruptly is (are)

Gaseous State MCQ - 2 (Advanced) - Question 7

Sketch shows the plot of Z v/s P for of a hypothetical gas for one mole at three distinct temperature.

Boyle’s temperature is the temperature at which a gas shows ideal behaviour over a pressure range in the low pressure region. Boyle's temperature (Tb) = a/Rb . If a plot is obtained at temperatures well below Boyle's temperature then the curve will show negative deviation, in low pressure region and positive deviation in the high pressure region. Near critical temperature the curve is more likely as CO2 and the temperature well above critical temperature curve is more like H2 at 0°C as shown above. At high pressure suppose all the constant temperature curve varies linearly with pressure according to the following equation:

Q.

Which of the following is correct:

Detailed Solution for Gaseous State MCQ - 2 (Advanced) - Question 7

Gaseous State MCQ - 2 (Advanced) - Question 8

Sketch shows the plot of Z v/s P for of a hypothetical gas for one mole at three distinct temperature.

Boyle’s temperature is the temperature at which a gas shows ideal behaviour over a pressure range in the low pressure region. Boyle's temperature (Tb) = a/Rb . If a plot is obtained at temperatures well below Boyle's temperature then the curve will show negative deviation, in low pressure region and positive deviation in the high pressure region. Near critical temperature the curve is more likely as CO2 and the temperature well above critical temperature curve is more like H2 at 0°C as shown above. At high pressure suppose all the constant temperature curve varies linearly with pressure according to the following equation:

Q.

For 500 K plot value of Z changes from 2 to 2.2 if pressure is varied from 1000 atm to 1200 atm (high pressure) then the value of b/RTwill be

Detailed Solution for Gaseous State MCQ - 2 (Advanced) - Question 8

In the high pressure region

solve for the two points.

Gaseous State MCQ - 2 (Advanced) - Question 9

Sketch shows the plot of Z v/s P for of a hypothetical gas for one mole at three distinct temperature.

Boyle’s temperature is the temperature at which a gas shows ideal behaviour over a pressure range in the low pressure region. Boyle's temperature (Tb) = a/Rb . If a plot is obtained at temperatures well below Boyle's temperature then the curve will show negative deviation, in low pressure region and positive deviation in the high pressure region. Near critical temperature the curve is more likely as CO2 and the temperature well above critical temperature curve is more like H2 at 0°C as shown above. At high pressure suppose all the constant temperature curve varies linearly with pressure according to the following equation:

Q.

As shown in the figure at 200 K and 500 atm value of compressibility factor is 2 (approx). Then volume of the gas at this point will be

Detailed Solution for Gaseous State MCQ - 2 (Advanced) - Question 9

Gaseous State MCQ - 2 (Advanced) - Question 10

Sketch shows the plot of Z v/s P for of a hypothetical gas for one mole at three distinct temperature.

Boyle’s temperature is the temperature at which a gas shows ideal behaviour over a pressure range in the low pressure region. Boyle's temperature (Tb) = a/Rb . If a plot is obtained at temperatures well below Boyle's temperature then the curve will show negative deviation, in low pressure region and positive deviation in the high pressure region. Near critical temperature the curve is more likely as CO2 and the temperature well above critical temperature curve is more like H2 at 0°C as shown above. At high pressure suppose all the constant temperature curve varies linearly with pressure according to the following equation:

Q.

Plot at Boyle's temperature for the gas will be

Detailed Solution for Gaseous State MCQ - 2 (Advanced) - Question 10

At boyles temp, a real gas shows ideal behaviour in the low pressure region.

Gaseous State MCQ - 2 (Advanced) - Question 11

In very high pressure region if Z v/s P is plotted at 1200 K for the above gas then it will have greatest slope.

Detailed Solution for Gaseous State MCQ - 2 (Advanced) - Question 11

and hence is inversely proportional to T.

Gaseous State MCQ - 2 (Advanced) - Question 12

Match the following:

Gaseous State MCQ - 2 (Advanced) - Question 13

For a fixed amount of the gas match the two column:

Column-I       Column II

Gaseous State MCQ - 2 (Advanced) - Question 14

Match the following

Gaseous State MCQ - 2 (Advanced) - Question 15

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