You can prepare effectively for JEE Chemistry for JEE Main & Advanced with this dedicated MCQ Practice Test (available with solutions) on the important topic of "Test: First law, Thermodynamic Equilibrium". These 15 questions have been designed by the experts with the latest curriculum of JEE 2026, to help you master the concept.
Test Highlights:
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A gas expands adiabatically at constant pressure such that
. The value of
of the gas will be :
Detailed Solution: Question 1
What is the value of change in internal energy at 1 atm in the process?

Given : 

at 
Detailed Solution: Question 2
An ideal gas expands against a constant external pressure of 2.0 atmosphere from 20 litre to 40 litre and absorbs 10 kJ of heat from surrounding. What is the change in internal energy of the system? (given : 1 atm-litre = 101.3 J)
Detailed Solution: Question 3
The pressure-volume diagram shows six curved paths that can be followed by the gas (connected by vertical paths). Which two of them should be part of a closed cycle if the net work done by the gas is to be its maximum positive value?

Detailed Solution: Question 4
On P − V coordinates, the slope of an isothermal curve of a gas at a pressure P = 1MPa and volume V = 0.0025 m3 is equal to −400MPa/m3. If Cp/Cv = 1.4, the slope of the adiabatic curve passing through this point is :
Detailed Solution: Question 5
For an ideal gas four processes are marked as 1 2,3 and 4 on
diagram as shown in figure. The amount of heat supplied to the gas in the process
and 4 are
and
respectively, then correct order of heat supplied to the gas is
is process-
is process-
is adiabatic process-3 and
is process-4]

Detailed Solution: Question 6
Detailed Solution: Question 7
A system changes from the state
to
) as shown in the figure. What is the work done by the system?

Detailed Solution: Question 8
If 2.5 moles of an ideal gas at a certain temperature are allowed to expand isothermally and reversibly from an initial volume of
to
, the work done by the gas is −16.5 kJ.
The temperature (in K) of the gas is (Round off to the nearest value)

Detailed Solution: Question 9
An ideal gas is subjected to cyclic process involving four thermodynamic states, the amounts of heat (Q) and work (W) involved in each of these states 



The ratio of the net work done by the gas to the total heat absorbed by the gas is
. The values of
and
respectively are
Detailed Solution: Question 10
For a monoatomic gas, the value of the ratio of
and
is
Detailed Solution: Question 11
If
is the change in enthalpy and
the change in internal energy accompanying a gaseous reaction, then
Detailed Solution: Question 12
An ideal gas expands adiabatically against vaccum. Which of the following is correct for the given process?
Detailed Solution: Question 13
When the state of a gas adiabatically changed from an equilibrium state A to another equilibrium state B an amount of work done on the stystem is
. If the gas is taken from state
to
via process in which the net heat absorbed by the system is
, then the net work done by the system is 
Detailed Solution: Question 14
The ratio γ = Cp, m/CV, m for a diatomic gaseous molecules is
Detailed Solution: Question 15
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