Test: Werner's theory and Valence Bond Theory - JEE MCQ
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20 Questions MCQ Test - Test: Werner's theory and Valence Bond Theory
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Test: Werner's theory and Valence Bond Theory - Question 1
is a strong field ligand. This is due to the fact that
Detailed Solution for Test: Werner's theory and Valence Bond Theory - Question 1
bond from pseudohalide to the metal and 
bond (from the metal to pseudohalide).
Test: Werner's theory and Valence Bond Theory - Question 2
Which one of the following complexes is an outer orbital complex
Atomic nos 
Detailed Solution for Test: Werner's theory and Valence Bond Theory - Question 2
(inner)
(inner)
(inner)
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Test: Werner's theory and Valence Bond Theory - Question 3
In the complex [SbF5] 
hybridisation is present Geometry of the complex is
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has 
hybridization and shows square pyramidal geometry
Test: Werner's theory and Valence Bond Theory - Question 4
An anion solution gives a white ppt with 
solution. The ppt. dissolves in dil. ammonia due to the formation of
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Test: Werner's theory and Valence Bond Theory - Question 5
Which of the following is incorrect regarding spectrochemical series?
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Test: Werner's theory and Valence Bond Theory - Question 6
The spin only magnetic moment of [MnBr4]x− is 5.9BM. The geometry of the complex and x respectively are
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B. M.
will have five unpaired electrons so 
will be in +2 state with 
being weak- field ligands.
for 
Test: Werner's theory and Valence Bond Theory - Question 7
Which of the following are inner orbital complex (i.e., involving 
hybridisation) and is paramagnetic in nature?
hybridisation) and is paramagnetic in nature?
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and 
are inner orbital
is diamagnetic in nature.
Test: Werner's theory and Valence Bond Theory - Question 8
Which of the following is organo-metallic compound?
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is an organometallic compound due to Ti directly attached to C- atom
Test: Werner's theory and Valence Bond Theory - Question 9
The geometries of the ammonia complexes of 
and 
, respectively, are
and , respectively, are
Detailed Solution for Test: Werner's theory and Valence Bond Theory - Question 9
octahedral 
square planar 
tetrahedral
Test: Werner's theory and Valence Bond Theory - Question 10
exhibits temperature dependent magnetic behaviour (paramagnetic/diamagnetic). The coordination geometries of 
in the paramagnetic and diamagnetic states are respectively
Detailed Solution for Test: Werner's theory and Valence Bond Theory - Question 10
whose electronic configuration is 
.
giving tetrahedral geometry. The diamagnetic state is achieved by pairing of electrons in 
orbital.
giving square planar geometry.
Test: Werner's theory and Valence Bond Theory - Question 11
Which of the following complex compound(s) is/are paramagnetic and low spin?
(I) 
(II) 
(III) 
(IV) 
Choose the correct code:
Detailed Solution for Test: Werner's theory and Valence Bond Theory - Question 11
in 
low spin complex 
Ni in 
low and high spin complex is applicable for 
to 
configuration
in 
low spin complex 
Test: Werner's theory and Valence Bond Theory - Question 12
An aqueous solution of titanium chloride, when subjected to magnetic measurement, measured zero magnetic moment. Assuming the octahedral complex in aqueous solution, the formulae of the complex is:
Detailed Solution for Test: Werner's theory and Valence Bond Theory - Question 12
octahedral complex Ti is in 
oxidations state 
no unpaired electrons
magnetic moment 
B.M.
Test: Werner's theory and Valence Bond Theory - Question 13
Which of the following statement is not true for the reaction given below?
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Test: Werner's theory and Valence Bond Theory - Question 14
Atomic number of 
and 
are 24, 26 and 27 respectively. Which of the following inner orbital octahedral complexes are paramagnetic?
Detailed Solution for Test: Werner's theory and Valence Bond Theory - Question 14
is
Detailed Solution for Test: Werner's theory and Valence Bond Theory - Question 15
is square planar.
Test: Werner's theory and Valence Bond Theory - Question 16
Which of the following statements is incorrect?
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is diamagnetic as oxalate is a strong ligand causing pairing of 
electrons in 
thereby leading to 
hybridisation.
Test: Werner's theory and Valence Bond Theory - Question 17
An octahedral complex of 
is diamagnetic. The hybridisation involved in the formation of the complex is:
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Test: Werner's theory and Valence Bond Theory - Question 18
The correct statement about the magnetic properties of 
and 
is
and is
Detailed Solution for Test: Werner's theory and Valence Bond Theory - Question 18
is a strong field ligand whereas 
is a weak field ligand.
Test: Werner's theory and Valence Bond Theory - Question 19
Nickel 
combines with a uninegative monodentate ligand to form a diamagnetic complex 
. The hybridization involved and the number of unpaired electrons present in the complex is respectively:
combines with a uninegative monodentate ligand to form a diamagnetic complex . The hybridization involved and the number of unpaired electrons present in the complex is respectively:
Detailed Solution for Test: Werner's theory and Valence Bond Theory - Question 19
is 
.
is 
.
orbital empty and one 
orbital empty.
is 
.
Test: Werner's theory and Valence Bond Theory - Question 20
Prussian blue is a deep blue pigment containing 
and 
ions. It has the formula 
. How many 
and 
ions are there per formula unit?
and ions. It has the formula . How many and ions are there per formula unit?
Detailed Solution for Test: Werner's theory and Valence Bond Theory - Question 20
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