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The major product formed in the thermal reaction given below, is:
In sigmatropic thermal expansion of 1, 1-dicyclopropyl ethene, the final product:
The following transformation proceeds by the sequence indicated. Give the structure of product:
Which of adducts (a)-(d) is the main product of the following Diels-Alder reaction?
Consider the following statements:
(I) Clasisen rearrangement is a [3, 3] sigmatropic rearrangement.
(II) Cope rearrangement proceeds via is chair like transition state.
(III) In the photochemical [2 + 2] cycloaddition of ethylene overlapping of HOMO of one molecule with LUMO of the other molecular takes place.
Select the correct statements.
In which of the following reaction, which sigmatropic reaction will take place:
Among the following dienes, the one that undergoes a degenerate Cope rearrangement is:
Pericyclic reaction involved in one of the steps of the following reaction sequence is:
The product formed and the process involved in the following reaction is:
The two step conversion of 7-dehydrocholesterol to vitamin D3 proceeds through:
With respect to the following biogenetic conversion of chorismic acid (A) to 4-ydroxyphenylpyruvic acid (C), the correct statement is:
Formation of the ketone (II) fro m the diazoketone (I) involves: