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Enthalpy during phase change - Thermodynamics Video Lecture - Class 11

FAQs on Enthalpy during phase change - Thermodynamics Video Lecture - Class 11

1. What is enthalpy during phase change?
Ans. Enthalpy during phase change refers to the heat energy absorbed or released by a substance when it undergoes a change in its physical state, such as from solid to liquid (melting) or from liquid to gas (vaporization). During these phase changes, the temperature of the substance remains constant, and the energy transfer is used to break or form intermolecular bonds.
2. How is enthalpy related to phase change?
Ans. Enthalpy is related to phase change as it represents the heat energy involved in the transition from one phase to another. The enthalpy change during a phase change is given by the equation Q = m * ΔH, where Q is the heat energy transferred, m is the mass of the substance, and ΔH is the enthalpy change per unit mass. This equation allows us to calculate the amount of heat energy required or released during a phase change.
3. Does enthalpy change during phase change depend on the substance?
Ans. Yes, the enthalpy change during a phase change depends on the substance involved. Different substances have different intermolecular forces and require different amounts of energy to break or form bonds during phase changes. For example, the enthalpy of vaporization for water is significantly higher than that of alcohol, indicating that water requires more heat energy to change from liquid to gas compared to alcohol.
4. Is enthalpy change positive or negative during phase change?
Ans. The enthalpy change during a phase change can be either positive or negative, depending on the direction of heat flow. If heat energy is absorbed by the substance during the phase change, the enthalpy change is positive, indicating an endothermic process. On the other hand, if heat energy is released by the substance, the enthalpy change is negative, indicating an exothermic process.
5. Can enthalpy change during phase change be measured experimentally?
Ans. Yes, enthalpy change during phase change can be measured experimentally using calorimetry. Calorimetry involves measuring the heat energy transferred during a phase change by using a calorimeter, which is an insulated container. By carefully measuring the initial and final temperatures of the substance and the surroundings, and considering the mass of the substance, the enthalpy change can be calculated using the equation Q = m * ΔH. This experimental approach allows for accurate determination of enthalpy changes during phase transitions.
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