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L37 : Hydrolysis of salt - Equilibrium, Class 11 Video Lecture

FAQs on L37 : Hydrolysis of salt - Equilibrium, Class 11 Video Lecture

1. What is hydrolysis of salt in chemistry?
Ans. Hydrolysis of salt in chemistry refers to the reaction that occurs when a salt compound reacts with water to produce an acidic or basic solution. This reaction involves the breaking of the salt molecule into its constituent ions, which then react with water molecules to form either hydronium ions (H3O+) or hydroxide ions (OH-), resulting in the formation of an acidic or basic solution, respectively.
2. How does the equilibrium of hydrolysis of salt occur?
Ans. The equilibrium of hydrolysis of salt occurs when the rate of the forward reaction, where salt ions react with water to form either hydronium or hydroxide ions, is equal to the rate of the reverse reaction, where the hydronium or hydroxide ions react with the salt ions to regenerate the salt compound. At equilibrium, the concentrations of the reactants and products remain constant, and the pH of the solution may be acidic, basic, or neutral depending on the nature of the salt.
3. What factors affect the equilibrium of hydrolysis of salt?
Ans. Several factors can affect the equilibrium of hydrolysis of salt, including the concentration of the salt and water, temperature, and the nature of the salt compound. Higher concentrations of the salt or water can shift the equilibrium towards the formation of acidic or basic solutions, respectively. Temperature can also influence the equilibrium, as some hydrolysis reactions are exothermic and favor the production of acidic or basic solutions at higher temperatures. Additionally, the nature of the salt compound, such as its acidity or basicity, can influence the equilibrium position.
4. Is hydrolysis of salt a reversible reaction?
Ans. Yes, hydrolysis of salt is a reversible reaction. This means that the reaction can proceed in both the forward and reverse directions. Initially, when a salt compound is dissolved in water, it undergoes hydrolysis to form either hydronium or hydroxide ions, resulting in an acidic or basic solution. However, these ions can also react with the salt ions to regenerate the salt compound, leading to the reverse reaction. At equilibrium, the rates of the forward and reverse reactions are equal, and the concentrations of the reactants and products remain constant.
5. How does the pH of the solution change during hydrolysis of salt?
Ans. The pH of the solution can change during hydrolysis of salt depending on the nature of the salt compound. If the salt is derived from a strong acid and a weak base, the hydrolysis will result in the formation of an acidic solution, leading to a decrease in pH. On the other hand, if the salt is derived from a weak acid and a strong base, the hydrolysis will result in the formation of a basic solution, leading to an increase in pH. If the salt is derived from a strong acid and a strong base, the hydrolysis will not significantly affect the pH, and the solution will remain neutral.
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